Erosion can influence cathode life,and is thus considered to be one of the main factors limiting the application of applied-field magnetoplasmadynamic thrusters.In this paper,erosion sites on graphite cathodes are stu...Erosion can influence cathode life,and is thus considered to be one of the main factors limiting the application of applied-field magnetoplasmadynamic thrusters.In this paper,erosion sites on graphite cathodes are studied so as to identify the influence of applied magnetic field and the ratio of propellant mass flow rate supplied from cathode and anode.The experiment results show that the application of applied magnetic field can significantly reduce the erosion rate of the cathode compared to that without magnetic field.The erosion sites on the cathode vary with the relative position of the convergent-divergent magnetic field,and are mainly distributed in the divergent part of the field.The erosion sites on the cathodes are found to be related to the propellant supply.The decreasing anode mass flow rate enlarges the range of erosion.These results are much helpful for the analysis of cathode erosion site location since they provide evidences of erosion mechanisms and point out the directions for further research.展开更多
The characteristics of electrons play a dominant role in determining the ionization and acceleration processes of plasmas.Compared with electrostatic diagnostics,the optical method is independent of the radio frequenc...The characteristics of electrons play a dominant role in determining the ionization and acceleration processes of plasmas.Compared with electrostatic diagnostics,the optical method is independent of the radio frequency(RF)noise,magnetic field,and electric field.In this paper,an optical emission spectroscope was used to determine the plasma emission spectra,electron excitation energy population distributions(EEEPDs),growth rates of low-energy and highenergy electrons,and their intensity jumps with input powers.The 56 emission lines with the highest signal-to-noise ratio and their corresponding electron excitation energy were used for the translation of the spectrum into EEEPD.One discrete EEEPD has two clear different regions,namely the low-energy electron excitation region(neutral lines with threshold energy of13–15 eV)and the high-energy electron excitation region(ionic lines with threshold energy?19 e V).The EEEPD variations with different diameters of discharge tubes(20 mm,40 mm,and 60 mm)and different input RF powers(200–1800 W)were investigated.By normalized intensity comparison of the ionic and neutral lines,the growth rate of the ionic population was higher than the neutral one,especially when the tube diameter was less than 40 mm and the input power was higher than 1000 W.Moreover,we found that the intensities of low-energy electrons and high-energy electrons jump at different input powers from inductively coupled(H)mode to helicon(W)mode;therefore,the determination of W mode needs to be carefully considered.展开更多
The development of electric propulsion has taken decades and in fact, began flight testing as early as the 1960s. However, it was initially slow to develop as an alternative to chemical propulsion systems due to the l...The development of electric propulsion has taken decades and in fact, began flight testing as early as the 1960s. However, it was initially slow to develop as an alternative to chemical propulsion systems due to the lack of available on-board electrical power for space vehicles. Since the turn of this century, the booming satellite market, and in particular for small satellites, has driven the demand for propulsion systems with high specific impulse, precisely adjustable thrust, long lifetime, and adaptable for different kinds of small vehicles.展开更多
The surface topography of noble metal particles is a significant factor in tailoring surface-enhanced Raman scattering (SERS) properties. Here, we present a simple fabrication route to hexagonally arranged arrays of...The surface topography of noble metal particles is a significant factor in tailoring surface-enhanced Raman scattering (SERS) properties. Here, we present a simple fabrication route to hexagonally arranged arrays of surface-roughened urchin- like Ag hemispheres (Ag-HSs) decorated with Ag nanoparticles (Ag-NPs) for highly active and reproducible SERS substrates. The urchin-like Ag-HS arrays are achieved by sputtering Ag onto the top surface of a highly ordered porous anodic aluminum oxide (AAO) template to form ordered arrays of smooth Ag-HSs and then by electrodepositing Ag-NPs onto the surface of each Ag-HS. Owing to the ordered arrangement of the Ag-HSs and the improved surface roughness, the urchin-like hierarchical Ag-HS arrays can provide sufficient and uniform "hot spots" for reproducible and highly active SERS effects. Using the urchin-like Ag-HS arrays as SERS substrates, 10-7 M dibutyl phthalate (a member of plasticizers family) and 1.5 × 10-5 M PCB-77 (one congener of polychlorinated biphenyl, a notorious class of pollutants) are identified, showing promising potential for these substrates in the rapid recognition of organic pollutants.展开更多
Additively manufactured high-entropy alloys generally suffer from low strength and/or poor ductility.In this work,by leveraging the good castability of eutectic high entropy alloys and high cooling rate of selective l...Additively manufactured high-entropy alloys generally suffer from low strength and/or poor ductility.In this work,by leveraging the good castability of eutectic high entropy alloys and high cooling rate of selective laser melting(SLM),we report a nearly fully dense and crack-free as-SLM AlCoCrFeNi_(2.1) eutectic high entropy alloy with an exceptional strength-ductility synergy,showing an ultrahigh yield strength of 982.1±35.2 MPa and an ultimate tensile strength of 1322.8±54.9 MPa together with an elongation to fracture of 12.3±0.5%.Such strength-ductility enhancement is owing to the heterogeneous eutectic microstructure consisting of the columnar,equiaxed,and“L-shape”cells with much refined sizes down to nanoscales.The morphology of cells in the transition zone is related to the misorientation between the growth direction of adjacent layers.This heterogeneous eutectic microstructure is the result of the graingrowth behavior dominated by the mechanisms of the epitaxial growth and growth of heterogeneous nuclei in SLM.Our current results provide a new methodology for the future design of ultrahigh-strength and ductile SLM-fabricated metallic materials including HEAs,and other printable alloys for various structural applications.展开更多
Inexpe nsive copper nano particles are generally thought to possess weak and broad localized surface plasm on resonance(LSPR).The,present experimental and theoretical studies show that tailoring the Cu nanoparticle to...Inexpe nsive copper nano particles are generally thought to possess weak and broad localized surface plasm on resonance(LSPR).The,present experimental and theoretical studies show that tailoring the Cu nanoparticle to a cubic shape results in a single intense,narrow,and asymmetric LSPR line shape,which is even superior to round-shaped gold nanoparticles.In this study,the dielectric function of copper is decomposed into an interband transition component and a free-electron component.This allows interband transition-induced plasmon damping to be visualized both spectrally and by surface polarization charges.The results reveal that the LSPR of Cu nanocubes originates from the comer mode as it is spectrally separated from the interb and transitions.In additi on,the interband tran sitions lead to severe damping of the local electromagnetic field but the cubic corner LSPR mode survives.Cu nanocubes display an extinction coefficient comparable to the dipole mode of a gold nanosphere with the same volume and show a larger local electromagnetic field enhancement These results will guider-development of in expensive plasmonic copper-based nano materials.展开更多
The coupling region of a Hall thruster with a hollow cathode is the region between the cathode and the thruster plume.The characteristics of plasma in that region are complicated and strongly associated with the thrus...The coupling region of a Hall thruster with a hollow cathode is the region between the cathode and the thruster plume.The characteristics of plasma in that region are complicated and strongly associated with the thruster working conditions and the cathode position.In this paper,a laboratory 100 W class magnetically shielded Hall thruster was coupled with a hollow cathode.Optical imaging and electrostatic probe were employed to monitor and scan the plasma plume.Plume characteristics in the coupling region in non-self-sustained mode and self-sustained mode were compared.Evolution of the coupling plume with the cathode position was studied.Experiments show that,when turning the thruster into self-sustained mode or moving the cathode further away axially,the discharge current can be reduced by 6.4–10.6%restraining the electron current and improving ionization.In particular,when the cathode is moved further,the electron conduction near the channel walls is suppressed.The electron current is reduced by 27.4%and the ion beam current is increased by 7%.Overall,this work shows that the working mode of the thruster and the position of the cathode greatly affect the coupling plasma plume.Both play an important role in improving the utilizations of propellant and current.展开更多
Ion-driven magnetic nozzles(Ti>Te)are designed as intrinsic parts of cutting-edge propulsive technologies such as variable specific impulse magnetoplasma rockets(VASIMRs)and applied-field magnetoplasmadynamic thrus...Ion-driven magnetic nozzles(Ti>Te)are designed as intrinsic parts of cutting-edge propulsive technologies such as variable specific impulse magnetoplasma rockets(VASIMRs)and applied-field magnetoplasmadynamic thrusters.Employing a two-dimensional axisymmetric particle-in-cell(PIC)code,in the ion-driven magnetic nozzle,the compositions and distributions of azimuthal currents in different axial regions are investigated under various inlet ion temperatures Ti0 and found to differ dramatically from that in the electron-driven magnetic nozzles.Previously reported to be all paramagnetic and vanishing under a high magnetic field,the azimuthal currents resulting from the E 3 B drift are shown to turn diamagnetic and sustain a considerable magnitude when Ti0 is considered.The previously reported profile of diamagnetic drift current is altered by the introduction of inlet ion temperature,and the paramagnetic part is significantly suppressed.Moreover,a wide range of paramagnetic currents appear downstream due to the inward detachment of ions,which can also be reduced by increasing inlet ion temperature.Albeit considered in this paper,the azimuthal currents resulting from grad-B and curvature drift are still negligible in all cases of interest.The magnitude of diamagnetic azimuthal currents increases with amplifying Ti0,indicating a clear physical image of energy transformation from ion thermal energy to the directed kinetic energy through electromagnetic processes in the magnetic nozzle.Additionally,the magnetic inductive strength also has noticeable impacts on the azimuthal currents,the current magnitude tends to decrease as the magnetic field increases,and over-increment of it may result in larger divergence angles and lower nozzle efficiency.展开更多
基金supported by the Fundamental Research Program(No.11872093)。
文摘Erosion can influence cathode life,and is thus considered to be one of the main factors limiting the application of applied-field magnetoplasmadynamic thrusters.In this paper,erosion sites on graphite cathodes are studied so as to identify the influence of applied magnetic field and the ratio of propellant mass flow rate supplied from cathode and anode.The experiment results show that the application of applied magnetic field can significantly reduce the erosion rate of the cathode compared to that without magnetic field.The erosion sites on the cathode vary with the relative position of the convergent-divergent magnetic field,and are mainly distributed in the divergent part of the field.The erosion sites on the cathodes are found to be related to the propellant supply.The decreasing anode mass flow rate enlarges the range of erosion.These results are much helpful for the analysis of cathode erosion site location since they provide evidences of erosion mechanisms and point out the directions for further research.
基金supported by National Natural Science Foundation of China(Nos.11805011 and 11872093)supported by the Shanghai Engineering Research Center of Space Engine(No.17DZ2280800)
文摘The characteristics of electrons play a dominant role in determining the ionization and acceleration processes of plasmas.Compared with electrostatic diagnostics,the optical method is independent of the radio frequency(RF)noise,magnetic field,and electric field.In this paper,an optical emission spectroscope was used to determine the plasma emission spectra,electron excitation energy population distributions(EEEPDs),growth rates of low-energy and highenergy electrons,and their intensity jumps with input powers.The 56 emission lines with the highest signal-to-noise ratio and their corresponding electron excitation energy were used for the translation of the spectrum into EEEPD.One discrete EEEPD has two clear different regions,namely the low-energy electron excitation region(neutral lines with threshold energy of13–15 eV)and the high-energy electron excitation region(ionic lines with threshold energy?19 e V).The EEEPD variations with different diameters of discharge tubes(20 mm,40 mm,and 60 mm)and different input RF powers(200–1800 W)were investigated.By normalized intensity comparison of the ionic and neutral lines,the growth rate of the ionic population was higher than the neutral one,especially when the tube diameter was less than 40 mm and the input power was higher than 1000 W.Moreover,we found that the intensities of low-energy electrons and high-energy electrons jump at different input powers from inductively coupled(H)mode to helicon(W)mode;therefore,the determination of W mode needs to be carefully considered.
文摘The development of electric propulsion has taken decades and in fact, began flight testing as early as the 1960s. However, it was initially slow to develop as an alternative to chemical propulsion systems due to the lack of available on-board electrical power for space vehicles. Since the turn of this century, the booming satellite market, and in particular for small satellites, has driven the demand for propulsion systems with high specific impulse, precisely adjustable thrust, long lifetime, and adaptable for different kinds of small vehicles.
基金This work was financially supported by the National Basic Research Program of China (No. 2013CB934304), the CAS/SAFEA International Partnership Program for Creative Research Teams, the National NaturalScience Foundation of China (Nos. 21303211, 11274312 and 51472245).
文摘The surface topography of noble metal particles is a significant factor in tailoring surface-enhanced Raman scattering (SERS) properties. Here, we present a simple fabrication route to hexagonally arranged arrays of surface-roughened urchin- like Ag hemispheres (Ag-HSs) decorated with Ag nanoparticles (Ag-NPs) for highly active and reproducible SERS substrates. The urchin-like Ag-HS arrays are achieved by sputtering Ag onto the top surface of a highly ordered porous anodic aluminum oxide (AAO) template to form ordered arrays of smooth Ag-HSs and then by electrodepositing Ag-NPs onto the surface of each Ag-HS. Owing to the ordered arrangement of the Ag-HSs and the improved surface roughness, the urchin-like hierarchical Ag-HS arrays can provide sufficient and uniform "hot spots" for reproducible and highly active SERS effects. Using the urchin-like Ag-HS arrays as SERS substrates, 10-7 M dibutyl phthalate (a member of plasticizers family) and 1.5 × 10-5 M PCB-77 (one congener of polychlorinated biphenyl, a notorious class of pollutants) are identified, showing promising potential for these substrates in the rapid recognition of organic pollutants.
基金Wentao Yan acknowledges the support of A∗STAR AME IRG Grant(No.A20E5c0091)Anping Dong acknowledges the support of the fellowship of China National Postdoctoral Program for Innovative Talents(No.BX20200203)+2 种基金the National Science and Technology Major Project of China(No.J2019-VI-0004-0117)the National Natural Science Foundation of China(No.52071205)Haibin Tang would like to acknowledge startup funds from Nanjing University of Science and Technology(No.JAB25802007/002).
文摘Additively manufactured high-entropy alloys generally suffer from low strength and/or poor ductility.In this work,by leveraging the good castability of eutectic high entropy alloys and high cooling rate of selective laser melting(SLM),we report a nearly fully dense and crack-free as-SLM AlCoCrFeNi_(2.1) eutectic high entropy alloy with an exceptional strength-ductility synergy,showing an ultrahigh yield strength of 982.1±35.2 MPa and an ultimate tensile strength of 1322.8±54.9 MPa together with an elongation to fracture of 12.3±0.5%.Such strength-ductility enhancement is owing to the heterogeneous eutectic microstructure consisting of the columnar,equiaxed,and“L-shape”cells with much refined sizes down to nanoscales.The morphology of cells in the transition zone is related to the misorientation between the growth direction of adjacent layers.This heterogeneous eutectic microstructure is the result of the graingrowth behavior dominated by the mechanisms of the epitaxial growth and growth of heterogeneous nuclei in SLM.Our current results provide a new methodology for the future design of ultrahigh-strength and ductile SLM-fabricated metallic materials including HEAs,and other printable alloys for various structural applications.
文摘Inexpe nsive copper nano particles are generally thought to possess weak and broad localized surface plasm on resonance(LSPR).The,present experimental and theoretical studies show that tailoring the Cu nanoparticle to a cubic shape results in a single intense,narrow,and asymmetric LSPR line shape,which is even superior to round-shaped gold nanoparticles.In this study,the dielectric function of copper is decomposed into an interband transition component and a free-electron component.This allows interband transition-induced plasmon damping to be visualized both spectrally and by surface polarization charges.The results reveal that the LSPR of Cu nanocubes originates from the comer mode as it is spectrally separated from the interb and transitions.In additi on,the interband tran sitions lead to severe damping of the local electromagnetic field but the cubic corner LSPR mode survives.Cu nanocubes display an extinction coefficient comparable to the dipole mode of a gold nanosphere with the same volume and show a larger local electromagnetic field enhancement These results will guider-development of in expensive plasmonic copper-based nano materials.
基金supported by the National Natural Science Foundation of China(No.11872093)。
文摘The coupling region of a Hall thruster with a hollow cathode is the region between the cathode and the thruster plume.The characteristics of plasma in that region are complicated and strongly associated with the thruster working conditions and the cathode position.In this paper,a laboratory 100 W class magnetically shielded Hall thruster was coupled with a hollow cathode.Optical imaging and electrostatic probe were employed to monitor and scan the plasma plume.Plume characteristics in the coupling region in non-self-sustained mode and self-sustained mode were compared.Evolution of the coupling plume with the cathode position was studied.Experiments show that,when turning the thruster into self-sustained mode or moving the cathode further away axially,the discharge current can be reduced by 6.4–10.6%restraining the electron current and improving ionization.In particular,when the cathode is moved further,the electron conduction near the channel walls is suppressed.The electron current is reduced by 27.4%and the ion beam current is increased by 7%.Overall,this work shows that the working mode of the thruster and the position of the cathode greatly affect the coupling plasma plume.Both play an important role in improving the utilizations of propellant and current.
基金supported by the National Natural Science Foundation of China(Grant No.11872093)and the High Performance Computing(HPC)resources at Beihang University.
文摘Ion-driven magnetic nozzles(Ti>Te)are designed as intrinsic parts of cutting-edge propulsive technologies such as variable specific impulse magnetoplasma rockets(VASIMRs)and applied-field magnetoplasmadynamic thrusters.Employing a two-dimensional axisymmetric particle-in-cell(PIC)code,in the ion-driven magnetic nozzle,the compositions and distributions of azimuthal currents in different axial regions are investigated under various inlet ion temperatures Ti0 and found to differ dramatically from that in the electron-driven magnetic nozzles.Previously reported to be all paramagnetic and vanishing under a high magnetic field,the azimuthal currents resulting from the E 3 B drift are shown to turn diamagnetic and sustain a considerable magnitude when Ti0 is considered.The previously reported profile of diamagnetic drift current is altered by the introduction of inlet ion temperature,and the paramagnetic part is significantly suppressed.Moreover,a wide range of paramagnetic currents appear downstream due to the inward detachment of ions,which can also be reduced by increasing inlet ion temperature.Albeit considered in this paper,the azimuthal currents resulting from grad-B and curvature drift are still negligible in all cases of interest.The magnitude of diamagnetic azimuthal currents increases with amplifying Ti0,indicating a clear physical image of energy transformation from ion thermal energy to the directed kinetic energy through electromagnetic processes in the magnetic nozzle.Additionally,the magnetic inductive strength also has noticeable impacts on the azimuthal currents,the current magnitude tends to decrease as the magnetic field increases,and over-increment of it may result in larger divergence angles and lower nozzle efficiency.