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A Time Series Short-Term Prediction Method Based on Multi-Granularity Event Matching and Alignment
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作者 haibo li Yongbo Yu +1 位作者 Zhenbo Zhao Xiaokang Tang 《Computers, Materials & Continua》 SCIE EI 2024年第1期653-676,共24页
Accurate forecasting of time series is crucial across various domains.Many prediction tasks rely on effectively segmenting,matching,and time series data alignment.For instance,regardless of time series with the same g... Accurate forecasting of time series is crucial across various domains.Many prediction tasks rely on effectively segmenting,matching,and time series data alignment.For instance,regardless of time series with the same granularity,segmenting them into different granularity events can effectively mitigate the impact of varying time scales on prediction accuracy.However,these events of varying granularity frequently intersect with each other,which may possess unequal durations.Even minor differences can result in significant errors when matching time series with future trends.Besides,directly using matched events but unaligned events as state vectors in machine learning-based prediction models can lead to insufficient prediction accuracy.Therefore,this paper proposes a short-term forecasting method for time series based on a multi-granularity event,MGE-SP(multi-granularity event-based short-termprediction).First,amethodological framework for MGE-SP established guides the implementation steps.The framework consists of three key steps,including multi-granularity event matching based on the LTF(latest time first)strategy,multi-granularity event alignment using a piecewise aggregate approximation based on the compression ratio,and a short-term prediction model based on XGBoost.The data from a nationwide online car-hailing service in China ensures the method’s reliability.The average RMSE(root mean square error)and MAE(mean absolute error)of the proposed method are 3.204 and 2.360,lower than the respective values of 4.056 and 3.101 obtained using theARIMA(autoregressive integratedmoving average)method,as well as the values of 4.278 and 2.994 obtained using k-means-SVR(support vector regression)method.The other experiment is conducted on stock data froma public data set.The proposed method achieved an average RMSE and MAE of 0.836 and 0.696,lower than the respective values of 1.019 and 0.844 obtained using the ARIMA method,as well as the values of 1.350 and 1.172 obtained using the k-means-SVR method. 展开更多
关键词 Time series short-term prediction multi-granularity event ALIGNMENT event matching
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Automatic identification of rock discontinuity and stability analysis of tunnel rock blocks using terrestrial laser scanning 被引量:3
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作者 Meng Wang Jiawen Zhou +3 位作者 Junlin Chen Nan Jiang Puwen Zhang haibo li 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第7期1810-1825,共16页
Local geometric information and discontinuity features are key aspects of the analysis of the evolution and failure mechanisms of unstable rock blocks in rock tunnels.This study demonstrates the integration of terrest... Local geometric information and discontinuity features are key aspects of the analysis of the evolution and failure mechanisms of unstable rock blocks in rock tunnels.This study demonstrates the integration of terrestrial laser scanning(TLS)with distinct element method for rock mass characterization and stability analysis in tunnels.TLS records detailed geometric information of the surrounding rock mass by scanning and collecting the positions of millions of rock surface points without contact.By conducting a fuzzy K-means method,a discontinuity automatic identification algorithm was developed,and a method for obtaining the geometric parameters of discontinuities was proposed.This method permits the user to visually identify each discontinuity and acquire its spatial distribution features(e.g.occurrences,spac-ings,trace lengths)in great detail.Compared with hand mapping in conventional geotechnical surveys,the geometric information of discontinuities obtained by this approach is more accurate and the iden-tification is more efficient.Then,a discrete fracture network with the same statistical characteristics as the actual discontinuities was generated with the distinct element method,and a representative nu-merical model of the jointed surrounding rock mass was established.By means of numerical simulation,potential unstable rock blocks were assessed,and failure mechanisms were analyzed.This method was applied to detection and assessment of unstable rock blocks in the spillway and sand flushing tunnel of the Hongshiyan hydropower project after a collapse.The results show that the noncontact detection of blocks was more labor-saving with lower safety risks compared with manual surveys,and the stability assessment was more reliable since the numerical model built by this method was more consistent with the distribution characteristics of actual joints.This study can provide a reference for geological survey and unstable rock block hazard mitigation in tunnels subjected to complex geology and active rockfalls. 展开更多
关键词 Rock tunnel Terrestrial laser scanning(TLS) Discontinuity automatic identification Distinct element method Rock block stability assessment
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Optimal Scheduling Method of Cogeneration System with Heat Storage Device Based on Memetic Algorithm 被引量:1
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作者 haibo li YibaoWang +2 位作者 Xinfu Pang Wei liu Xu Zhang 《Energy Engineering》 EI 2023年第2期317-343,共27页
Electric-heat coupling characteristics of a cogeneration system and the operating mode of fixing electricity with heat are the main reasons for wind abandonment during the heating season in the Three North area.To imp... Electric-heat coupling characteristics of a cogeneration system and the operating mode of fixing electricity with heat are the main reasons for wind abandonment during the heating season in the Three North area.To improve the wind-power absorption capacity and operating economy of the system,the structure of the system is improved by adding a heat storage device and an electric boiler.First,aiming at the minimum operating cost of the system,the optimal scheduling model of the cogeneration system,including a heat storage device and electric boiler,is constructed.Second,according to the characteristics of the problem,a cultural gene algorithm program is compiled to simulate the calculation example.Finally,through the system improvement,the comparison between the conditions before and after and the simulation solutions of similar algorithms prove the effectiveness of the proposed scheme.The simulation results show that adding the heat storage device and electric boiler to the scheduling optimization process not only improves the wind power consumption capacity of the cogeneration system but also reduces the operating cost of the system by significantly reducing the coal consumption of the unit and improving the economy of the system operation.The cultural gene algorithm framework has both the global evolution process of the population and the local search for the characteristics of the problem,which has a better optimization effect on the solution. 展开更多
关键词 Combined heat and power generation heat storage device memetic algorithm simulated annealing wind abandonment
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Degree of ontogenetic diet shift and trophic niche partitioning of Euphausia superba and Thysanoessa macrura are influenced by food availability
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作者 Zhipeng PANG Xupeng CHI +3 位作者 Zhihui SONG haibo li Yunyan CHEN Guang YANG 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2023年第3期1039-1049,共11页
Euphausia superba and Thysanoessa macrura are dominant krill species in the Southern Ocean and their habitats are often overlapped reportedly.Studies of the feeding strategies of these two krill species will help us b... Euphausia superba and Thysanoessa macrura are dominant krill species in the Southern Ocean and their habitats are often overlapped reportedly.Studies of the feeding strategies of these two krill species will help us better understand the coexistence mechanisms and estimate the roles that krill played in the food web of the Southern Ocean.The trophodynamics of E.superba and T.macrura at different ontogenetic stages(furcilia,juvenile,adult)were studied using fatty acid and stable isotope biomarkers in the samples collected in Amundsen Sea during austral summer of 2017/2018 and 2018/2019.Diatoms like Fragilariopsis spp.was the most abundant phytoplankton species in the summer of 2017/2018,while the abundance of phytoplankton in the summer of 2018/2019 was dominated by Phaeocystis sp.The gradual increase of the carnivorous index 18꞉1n-9/18꞉1n-7 with ontogeny of both species in 2018/2019 indicated more carnivorous feeding of adults compared with juveniles and larvae.Meanwhile,greaterδ15N values of T.macrura than that of E.superba were more significant in the juvenile and adult stages during the summer of 2018/2019.Our results indicate that the trophic niche differentiation between the two krill species appeared in postlarval stage and can be influenced by food availability.Compared with E.superba,T.macrura was more prone to feed omnivorously or carnivorously responding to food availability. 展开更多
关键词 Antarctic krill feeding strategies fatty acids stable isotopes TROPHODYNAMICS Southern Ocean
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Absorptive root-multidimension strategy links air temperature and species distribution in a montane forest
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作者 Zuhua Wang Min liu +5 位作者 Long li Jianwei Hou Xiaodong Zhang haibo li Chuandong Yang lilin Yang 《Forest Ecosystems》 SCIE CSCD 2023年第3期307-315,共9页
Background: Air temperature affects absorptive root traits, which are closely related to species distribution.However, it is still unclear how air temperature regulates species distribution through changes in absorpti... Background: Air temperature affects absorptive root traits, which are closely related to species distribution.However, it is still unclear how air temperature regulates species distribution through changes in absorptive root traits. Seven functional traits of the absorptive roots of 240 individuals of 52 species, soil properties and air temperature were measured along an elevational gradient on Mt. Fanjingshan, Tongren City, Guizhou, and then the direct and indirect effects of these controls on species distribution were detected.Results: Absorptive roots adapted to air temperature with two strategies. The first strategy was positively associated with the specific root area(SRA) and specific root length(SRL) and was negatively associated with the root tissue density(RTD), representing the classic root economics spectrum(RES). The second strategy was represented by the trade-off between root diameter, mycorrhizal fungi colonization(MF) and SRL, representing the collaboration gradient with “do it yourself” resource uptake ranging from “outsourcing” to mycorrhizal resource uptake. Air temperature regulated species distribution in six ways: directly reducing species importance value;indirectly increasing the species importance value by reducing soil nitrogen content or increasing soil pH by reducing soil moisture inducing absorptive roots to change from “do it yourself” resource absorption to “outsourcing” resource absorption;indirectly decreasing the species importance value by decreasing soil moisture to change from“outsourcing”resource absorption to “do it yourself” resource absorption;indirectly increasing the species importance value with increasing soil pH by reducing soil moisture resulting in absorptive root traits turning into nutrient foraging traits;and indirectly decreasing the species importance value by promoting absorptive root traits to nutrient conservation traits.Conclusions: Absorptive root traits play a crucial role in the regulation of species distribution through multiapproaches of air temperature. 展开更多
关键词 Air temperature Absorptive roots Functional traits Structural equation models Mt.Fanjingshan
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Genome-wide analysis of soybean DnaJA-family genes and functional characterization of GmDnaJA6 responses to saline and alkaline stress
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作者 Binshuo Zhang Zhen liu +10 位作者 Runnan Zhou Peng Cheng haibo li Zhiyang Wang Ying liu Mingyang li Zhenqing Zhao Zhenbang Hu Qingshan Chen Xiaoxia Wu Ying Zhao 《The Crop Journal》 SCIE CSCD 2023年第4期1230-1241,共12页
Plant Dna JA proteins act as molecular chaperones in response to environmental stressors.The purpose of this study was to characterize the function and regulatory mechanisms of Dna JA genes in soybean.Gene expression ... Plant Dna JA proteins act as molecular chaperones in response to environmental stressors.The purpose of this study was to characterize the function and regulatory mechanisms of Dna JA genes in soybean.Gene expression profiles in various soybean tissues at various stages of development indicated that Gm Dna JAs function in the coordination of stress and plant hormone responses.Gm Dna JA6 was identified as a candidate regulator of saline and alkaline stress resistance and Gm Dna JA6 overexpression lines showed increased soybean saline and alkaline tolerance.Dna J interacted with Hsp70,and Gm Hsp70 increased the saline and alkaline tolerance of plants with chimeric soybean hairy roots. 展开更多
关键词 SOYBEAN Heat shock proteins DNAJ Salt stress Alkali stress
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有机-无机杂化材料动力学与热力学转化以及荧光信息防伪应用研究——介绍一个综合化学实验
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作者 吴越 李钧 +3 位作者 张波 杨燕 李海波 张宪玺 《大学化学》 CAS 2024年第6期390-399,共10页
有机-无机杂化发光材料易于调控的空间结构和发光性质,在发光防伪领域备受青睐。本实验基于Sb(Ⅲ)掺杂Bi(Ⅲ)基零维有机-无机杂化金属卤化物,利用不同的晶体生长方式实现动力学产物(化合物1)向热力学产物(化合物2)的转变,采用X-射线粉... 有机-无机杂化发光材料易于调控的空间结构和发光性质,在发光防伪领域备受青睐。本实验基于Sb(Ⅲ)掺杂Bi(Ⅲ)基零维有机-无机杂化金属卤化物,利用不同的晶体生长方式实现动力学产物(化合物1)向热力学产物(化合物2)的转变,采用X-射线粉末衍射和荧光光度法分别对其进行了物相表征和光学性能测试,二者表现出截然不同的物相与光物理性质。化合物2在蒸馏水的作用下实现荧光淬灭,而且具有很强的反水性。基于化合物2出色的发光变色性质,制作了简易的可水写荧光信息防伪板/纸。本实验充分体现了“结构决定性质”的专业理论、“学以致用”的教学理念。该实验设计与实践旨在培养学生创新思维,提高其分析和解决实际问题的能力。 展开更多
关键词 Sb(Ⅲ)掺杂Bi(Ⅲ)基杂卤化物 光致发光 动力学与热力学转化 水致变色 可写荧光防伪应用
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P-aminobenzoic acid promotes retinal regeneration through activation of Ascl1a in zebrafish
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作者 Meihui He Mingfang Xia +3 位作者 Qian Yang Xingyi Chen haibo li Xiaobo Xia 《Neural Regeneration Research》 SCIE CAS CSCD 2024年第8期1849-1856,共8页
The retina of zebrafish can regenerate completely after injury.M ultiple studies have demonstrated that metabolic alte rations occur during retinal damage;however to date no study has identified a link between metabol... The retina of zebrafish can regenerate completely after injury.M ultiple studies have demonstrated that metabolic alte rations occur during retinal damage;however to date no study has identified a link between metabolites and retinal regeneration of zebrafish.Here,we performed an unbiased metabolome sequencing in the N-methyl-D-aspartic acid-damaged retinas of zebrafish to demonstrate the metabolomic mechanism of retinal regeneration.Among the differentially-ex pressed metabolites,we found a significant decrease in p-aminobenzoic acid in the N-methyl-D-aspartic acid-damaged retinas of zebrafish.Then,we investigated the role of p-aminobenzoic acid in retinal regeneration in adult zebrafish.Impo rtantly,p-aminobenzoic acid activated Achaetescute complex-like 1a expression,thereby promoting Müller glia reprogramming and division,as well as Müller glia-derived progenitor cell proliferation.Finally,we eliminated folic acid and inflammation as downstream effectors of PABA and demonstrated that PABA had little effect on Müller glia distribution.Taken together,these findings show that PABA contributes to retinal regeneration through activation of Achaetescute complex-like 1a expression in the N-methyl-Daspartic acid-damaged retinas of zebrafish. 展开更多
关键词 Achaetescute complex-like 1a(Ascl1a) metabolomics Müller glia p-aminobenzoic acid(PABA) RETINA REGENERATION ZEBRAFISH
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Analysis of impact pressure,rock-breaking effect,and ground vibration induced by the disposable CO_(2)fracturing tube
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作者 Chong Yu Yongan Ma +3 位作者 haibo li Shouchun Deng Yafei Hao Kuan Zhu 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第8期3099-3121,共23页
The technology of expansion fracturing with liquid CO_(2)(EFLCO_(2))has attracted increasing attention due to reduced vibration and damage.The disposable fracturing tube has been developed and is gradually replacing t... The technology of expansion fracturing with liquid CO_(2)(EFLCO_(2))has attracted increasing attention due to reduced vibration and damage.The disposable fracturing tube has been developed and is gradually replacing the Cardox tube.However,there is a lack of impact pressure testing of disposable tubes under real working conditions,selection of gas explosion design parameters,and systematic analysis of blasting vibration.This limitation has constrained the widespread application of disposable fracturing tubes in engineering.A joint monitoring of the pressure-time curves in the disposable tubes and boreholes was conducted.The rock-breaking effect of varying hole spacing parameters in the EFLCO_(2)design was analyzed,and a systematic study was carried out on the vibration peak value,frequency,and energy characteristics.The results show that(1)the pressure distribution characteristics,stress peak value,and duration in the disposable tubes are different from those of Cardox tubes,which show multi-peak distribution,low-pressure peak value,and short duration.The correlation between the pressure in the disposable tube,filling pressure,and liquid CO_(2)weight is established,and a theoretical calculation method for the borehole wall pressure is proposed;(2)The hole spacing in rocks of different hardness is suggested;and(3)At the same scale distance,the peak particle velocity(PPV)caused by EFLCO_(2)(PPVCO_(2))is significantly smaller than that caused by blasting(PPVexplosive).The ratio of PPVexplosive to PPVCO_(2)is a power function related to scale distance,and a distance-related zonality exist in this relationship.The frequency composition of the vibration signal caused by EFLCO_(2)is relatively simple with a narrow frequency band.Its PPV and energy are mainly concentrated in the low-frequency band.This research contributes to the optimization of disposable fracturing tubes,gas explosion design,and vibration hazard control. 展开更多
关键词 Disposable tube Liquid CO_(2) Impact pressure Hole spacing Vibration effect Cardox tube
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MXene:Promising materials for magnesium-ion batteries
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作者 liuyu Song haibo li +3 位作者 Pengkai Wang Yu Shang Yue Yang Zhaoyu Wu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第5期199-211,共13页
Magnesium-ion batteries(MIBs)have attracted extensive attention due to their high theoretical capacity,superior safety,and low cost.Nonetheless,the development of MIBs is hindered by the lack of cathode materials with... Magnesium-ion batteries(MIBs)have attracted extensive attention due to their high theoretical capacity,superior safety,and low cost.Nonetheless,the development of MIBs is hindered by the lack of cathode materials with long cycle life and rate capability.MXene stands out as a prime choice for MIB cathode or collector for anode-free magnesium batteries(AFMBs)because of its larger surface area,adjustable surface properties,and good electrical conductivity.In this paper,we summarized the preparation and layering methods of MXene and discussed the prospects of MXene as a cathode or collector for MIBs.This review will be immensely beneficial in critically analyzing the synthesis techniques and the applications of MXene material as MIB cathode or AFMB collector.In addition,the challenges of the preparation and layering were concluded,along with raising the research strategies of MXene for storing Mg ions. 展开更多
关键词 MXene NANOMATERIALS ELECTROCHEMISTRY OPTIMIZATION Magnesium-ion batteries(MIBs)
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Effect of intermittent joint distribution on the mechanical and acoustic behavior of rock masses
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作者 Shuaiyang Fu haibo li +2 位作者 liwang liu Di Wu Ben Wang 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第4期1231-1244,共14页
The mechanical characteristics and acoustic behavior of rock masses are greatly influenced by stochastic joints.In this study,numerical models of rock masses incorporating intermittent joints with different numbers an... The mechanical characteristics and acoustic behavior of rock masses are greatly influenced by stochastic joints.In this study,numerical models of rock masses incorporating intermittent joints with different numbers and dip angles were produced using the finite element method(FEM)with the intrinsic cohesive zone model(ICZM).Then,the uniaxial compressive and wave propagation simulations were performed.The results indicate that the joint number and dip angle can affect the mechanical and acoustic properties of the models.The uniaxial compressive strength(UCS)and wave velocity of rock masses decrease monotonically as the joint number increases.However,the wave velocity grows monotonically as the joint dip angle increases.When the joint dip angle is 45°–60°,the UCS of the rock mass is lower than that of other dip angles.The wave velocity parallel to the joints is greater than that perpendicular to the joints.When the dip angle of joints remains unchanged,the UCS and wave velocity are positively related.When the joint dip angle increases,the variation amplitude of the UCS regarding the wave velocity increases.To reveal the effect of the joint distribution on the velocity,a theoretical model was also proposed.According to the theoretical wave velocity,the change in wave velocity of models with various joint numbers and dip angles was consistent with the simulation results.Furthermore,a theoretical indicator(i.e.fabric tensor)was adopted to analyze the variation of the wave velocity and UCS. 展开更多
关键词 Stochastic joints Intrinsic cohesive zone model Uniaxial compressive strength(UCS) Wave propagation Fabric tensor
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Analysis of optical axis deviation caused by structural stiffness in equatorial telescopes
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作者 haibo li Runfu Peng +2 位作者 Chenggang Shu Yong Bi Shaoming Hu 《Astronomical Techniques and Instruments》 CSCD 2024年第4期203-210,共8页
The impact of structural stiffness on optical axis deviation poses a significant challenge in the design of equatorial telescope structures.A comprehensive analysis during the design process can reduce the reliance of... The impact of structural stiffness on optical axis deviation poses a significant challenge in the design of equatorial telescope structures.A comprehensive analysis during the design process can reduce the reliance of a telescope on advanced control technologies,thereby improving its economic feasibility.Although full-system finite element analyses are reliable,they are encumbered by significant time requirements and limitations in covering all possible telescope orientations.Therefore,we propose an efficient and comprehensive analytical method to evaluate the optical axis deviation of equatorial telescopes across a full range of angles.To address the challenge of ensuring that the analysis covers all possible positions of an equatorial telescope,based on a model from SiTian project,we analyze the optical axis deviations caused by the fork arm at 25 different angles and then use fitting methods to obtain results for all angles.Based on the analysis results of the optical axis deviation caused by the stiffness of the optical tube in the horizontal position,we derive the results for the tube at any position using geometric relationships.Finally,we calculate the coupling factors and combine these impacts.Furthermore,we identify six discrete feature points to reflect possible telescope orientations and conduct comprehensive finite element analyses.The results are in alignment with those acquired through a comprehensive computational approach. 展开更多
关键词 Astronomical instrumentation Telescopes Equatorial mounts Multivariate analysis
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中医药调控线粒体损伤干预呼吸系统疾病的研究进展
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作者 李海博 杨静帆 +1 位作者 秦燕勤 刘田田 《Chinese Medicine and Natural Products》 CAS 2024年第2期49-55,共7页
Mitochondria are important organelles in cells for energy production,and mitochon-drial damage caused by various reasons is an important factor promoting disease progression.Mitochondrial damage involves structural da... Mitochondria are important organelles in cells for energy production,and mitochon-drial damage caused by various reasons is an important factor promoting disease progression.Mitochondrial damage involves structural damage and mitochondrial DNA damage,which are closely related to the occurrence and development of respiratory system diseases.In recent years,a large number of studies have confirmed the significant role of mitochondrial damage in the progression of respiratory system diseases,which may be an important target for the treatment of respiratory system diseases with traditional Chinese medicine(TCM).This article reviews the role of TCM in regulating mitochondrial damage for intervention in respiratory system diseases such as chronic obstructive pulmonary disease,lung cancer,pulmonary fibrosis,acute lung injury,asthma,and pneumonia,aiming to provide a basis for the study of the pathogenesis and drug action targets of respiratory system diseases. 展开更多
关键词 mitochondrial damage respiratory system diseases TCM
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Biomass-derived nitrogen-doped hierarchical porous carbon as efficient sulfur host for lithium–sulfur batteries 被引量:15
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作者 Qinghuiqiang Xiao Gaoran li +6 位作者 Minjie li Ruiping liu haibo li Pengfei Ren Yue Dong Ming Feng Zhongwei Chen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第5期61-67,共7页
Lithium-sulfur(Li-S) battery is a potential energy storage technology with high energy density and low cost. However, the gap between theoretical expectation and practical performance limits its wide implementation. H... Lithium-sulfur(Li-S) battery is a potential energy storage technology with high energy density and low cost. However, the gap between theoretical expectation and practical performance limits its wide implementation. Herein, we report a nitrogen-doped porous carbon derived from biomass pomelo peel as sulfur host material for Li-S batteries. The hierarchical porous architecture and the polar surface introduced by N-doping render a favorable combination of physical and chemical sulfur confinements as well as an expedite electron/ion transfer, thus contributing to a facilitated and stabilized sulfur electrochemistry. As a result, the corresponding sulfur composite electrodes exhibit an ultrahigh initial capacity of 1534.6 mAh g^-1, high coulombic efficiency over 98% upon 300 cycles, and decent rate capability up to 2 C. This work provides an economical and effective strategy for the fabrication of advanced carbonaceous sulfur host material as well as the significant improvement of Li-S battery performance. 展开更多
关键词 Biomass-derived material Porous carbon LITHIUM SULFUR BATTERIES Electrochemical performance
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2D titanium carbide(MXene) electrodes with lower-F surface for high performance lithium-ion batteries 被引量:11
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作者 Ming Lu Haojie li +9 位作者 Wenjuan Han Junnan Chen Wen Shi Jiaheng Wang Xiang-Min Meng Jingang Qi haibo li Bingsen Zhang Wei Zhang Weitao Zheng 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2019年第4期148-153,共6页
MXene has shown distinctive advantages as anode materials of lithium-ion batteries. However, local surface chemistry, which was confirmed that can block ion transfer and limit redox reaction, has a significant effect ... MXene has shown distinctive advantages as anode materials of lithium-ion batteries. However, local surface chemistry, which was confirmed that can block ion transfer and limit redox reaction, has a significant effect on electrochemical performance. Herein, annealing MXene under hydrogen was employed for removing-F and turning-OH to-O terminations. We demonstrate that it improves the kinetics of Li-ion transport between the electrolyte and electrode. As a result, a lower interfacial charge transfer impedance was obtained. The electrochemical measurement exhibited that a nearly 2-fold increase of specific capacity was achieved for the annealed MXene. 展开更多
关键词 Ti3C2 MXene LI-ION Hydrogen -F CONTENT
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Reinforced polysulfide barrier by g-C_(3)N_(4)/CNT composite towards superior lithium-sulfur batteries 被引量:7
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作者 Xiangliang Wang Gaoran li +7 位作者 Minjie li Ruiping liu haibo li Tengyu li Mingzhu Sun Yirui Deng Ming Feng Zhongwei Chen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2021年第2期234-240,I0008,共8页
The notorious shuttle effect has long been obstructing lithium-sulfur(Li-S) batteries from yielding the expected high energy density and long lifespan.Herein,we develop a multifunctional polysulfide barrier reinforced... The notorious shuttle effect has long been obstructing lithium-sulfur(Li-S) batteries from yielding the expected high energy density and long lifespan.Herein,we develop a multifunctional polysulfide barrier reinforced by the graphitic carbon nitride/carbon nanotube(g-C_3 N_4/CNT) composite toward inhibited shuttling behavior and improved battery performance.The obtained g-C_3 N_4 delivers a unique spongelike architecture with massive ion transfer pathways and fully exposed active interfaces,while the abundant C-N heteroatomic structures impose strong chemical immobilization toward lithium polysulfides.Combined with the highly conductive agent,the g-C_3 N_4/CNT reinforced separator is endowed with great capability of confining and reutilizing the active sulfur within the cathode,thus contributing to an efficient and stable sulfur electrochemistry.Benefiting from these synergistic attributes,Li-S cells based on g-C_3 N_4/CNT separator exhibit an excellent cyclability with a minimum decay rate of 0.03% per cycle over 500 cycles and decent rate capability up to 2 C.Moreover,a high areal capacity of 7.69 mAh cm^(-2)can be achieved under a raised sulfur loading up to 10.1 mg cm^(-2).demonstrating a facile and efficient pathway toward superior Li-S batteries. 展开更多
关键词 Graphitic carbon nitride Reinforced separator Lithium sulfur battery Chemical interaction Synergistic effect
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K+alkalization promoted Ca2+intercalation in V2CTx MXene for enhanced Li storage 被引量:5
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作者 Ming Lu Yaopeng Zhang +5 位作者 Junnan Chen Wenjuan Han Wei Zhang haibo li Xia Zhang Bingsen Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第10期358-364,共7页
Although MXenes is highly attractive as anode materials of lithium ion batteries,it sets a bottleneck for higher capacity of the V2CTxMXene due to the limited interlayer space and the derived surface terminations.Here... Although MXenes is highly attractive as anode materials of lithium ion batteries,it sets a bottleneck for higher capacity of the V2CTxMXene due to the limited interlayer space and the derived surface terminations.Herein,the cation intercalation and ion-exchange were well employed to achieve a K+and Ca2+intercalated V2CTxMXene.A larger interlayer distance and low F surface terminations were thereof obtained,which accelerates the ion transport and promotes the delicate surface of V2CTx MXene.As a result,a package of enhanced capacity,rate performance and cyclability can be achieved.Furthermore,the ion exchange approach can be extended to other 2 D layered materials,and both the interlayer control and the surface modification will be achieved. 展开更多
关键词 V2CTx MXenes Calcium ion Interlayer distance INTERCALATION Lithium storage
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Difference of planktonic ciliate communities of the tropical West Pacific, the Bering Sea and the Arctic Ocean 被引量:4
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作者 Chaofeng Wang haibo li +8 位作者 Zhiqiang Xu Shan Zheng Qiang Hao Yi Dong li Zhao Wuchang Zhang Yuan Zhao Gérald Grégori Tian Xiao 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2020年第4期9-17,共9页
Ciliates are important components in planktonic food webs,but our understanding of their community structures in different oceanic water masses is limited.We report pelagic ciliate community characteristics in three s... Ciliates are important components in planktonic food webs,but our understanding of their community structures in different oceanic water masses is limited.We report pelagic ciliate community characteristics in three seas:the tropical West Pacific,the Bering Sea and the Arctic Ocean.Planktonic ciliate abundance had"bimodal-peak","surface-peak"and"DCM(deep chlorophyll a maximum layer)-peak"vertical distribution patterns in the tropical West Pacific,the Bering Sea and the Arctic Ocean,respectively.The abundance proportion of tintinnid to total ciliate in the Bering Sea(42.6%)was higher than both the tropical West Pacific(7.8%)and the Arctic Ocean(2.0%).The abundance proportion of small aloricate ciliates(10–20μm size-fraction)in the tropical West Pacific was highest in these three seas.The Arctic Ocean had higher abundance proportion of tintinnids in larger LOD(lorica oral diameter)size-class.Proportion of redundant species increased from the Arctic Ocean to the tropical West Pacific.Our result provided useful data to further understand ecology roles of planktonic ciliates in different marine habitats. 展开更多
关键词 planktonic ciliates vertical distribution community structure tropical West Pacific Bering Sea Arctic Ocean
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There is plenty of space in the MXene layers: The confinement and fillings 被引量:4
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作者 Ming Lu Wenjuan Han +2 位作者 haibo li Wei Zhang Bingsen Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第9期344-363,I0011,共21页
MXenes have emerged as a new kind of 2D transition metal carbides,nitrides and carbonitrides.Origined from the unique 2D structure with a luxuriant combination of elements,MXenes drive a series of the investigations r... MXenes have emerged as a new kind of 2D transition metal carbides,nitrides and carbonitrides.Origined from the unique 2D structure with a luxuriant combination of elements,MXenes drive a series of the investigations related to energy storage and conversion,biometrics and sensing,lighting,purification and separation.For 2D layered MXene materials,the interspacing confined by the independent MXenes layers affords a distinct confinement space,which is similar to a nanoreactor that can be utilized for the storage of ions,nanoparticles,nanowires,and the materials with 2D or 3D structure.These fillings confined by MXene layers afford new opptunities for achieving improved properties and performance via complementary natural features,further the synergistic effect.Herein,we summarize the recent reports concerning with the confinded MXenes spacing and the fillings.The modification of interlayer distance lead by the intercalants were explored.We expect that our review may offer the route for a series of ongoing studies to address the MXenes. 展开更多
关键词 MXenes Interlayer distance INTERCALATION STRUCTURE Fillings
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Characterization of 3D pore nanostructure and stress-dependent permeability of organic-rich shales in northern Guizhou Depression,China 被引量:4
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作者 Xiaofang Jiang Shouchun Deng +1 位作者 haibo li Hong Zuo 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2022年第2期407-422,共16页
The three-dimensional(3D)pore structures and permeability of shale are critical for forecasting gas production capacity and guiding pressure differential control in practical reservoir extraction.However,few investiga... The three-dimensional(3D)pore structures and permeability of shale are critical for forecasting gas production capacity and guiding pressure differential control in practical reservoir extraction.However,few investigations have analyzed the effects of microscopic organic matter(OM)morphology and 3D pore nanostructures on the stress sensitivity,which are precisely the most unique and controlling factors of reservoir quality in shales.In this study,ultra-high nanoscale-resolution imaging experiments,i.e.focused ion beam-scanning electron microscopy(FIB-SEMs),were conducted on two organic-rich shale samples from Longmaxi and Wufeng Formations in northern Guizhou Depression,China.Pore morphology,porosity of 3D pore nanostructures,pore size distribution,and connectivity of the six selected regions of interest(including clump-shaped OMs,interstitial OMs,framboidal pyrite,and microfractures)were qualitatively and quantitatively characterized.Pulse decay permeability(PDP)measurement was used to investigate the variation patterns of stress-dependent permeability and stress sensitivity of shales under different confining pressures and pore pressures,and the results were then used to calculate the Biot coefficients for the two shale formations.The results showed that the samples have high OM porosity and 85%of the OM pores have the radius of less than 40 nm.The OM morphology and pore structure characteristics of the Longmaxi and Wufeng Formations were distinctly different.In particular,the OM in the Wufeng Formation samples developed some OM pores with radius larger than500 nm,which significantly improved the connectivity.The macroscopic permeability strongly depends on the permeability of OM pores.The stress sensitivity of permeability of Wufeng Formation was significantly lower than that of Longmaxi Formation,due to the differences in OM morphology and pore structures.The Biot coefficients of 0.729 and 0.697 were obtained for the Longmaxi and Wufeng Formations,respectively. 展开更多
关键词 Focused ion beam scanning electron microscopy(FIB-SEM) Three-dimensional(3D)reconstruction Pulse decay permeability(PDP) Stress sensitivity Wufeng-Longmaxi formation
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