Electron-deficient Cu site catalyzed acetylene hydrochlorination

Rational design of catalytic sites to activate the C≡C bond is of paramount importance to advance acetylene hydrochlorination. Herein, Cu sites with electron-rich and electron-deficient states were constructed by controlling the impregnation solutions. The π electrons flowing from acetylene to Cu site are facilitated over the electron-deficient Cu sites, achieving high activation of C≡C bond. The contradiction between the increased activation of acetylene required for enhanced catalytic activity and the resistance of Cu site to reduction by acetylene required for maintaining catalytic stability can be balanced by establishing strong interactions of Cu site with pyrrolic-N species. The catalytic activity displays a volcano shape scaling relationship as a function of Cu particle size. Tribasic copper chloride is concomitantly generated with the construction of electron-deficient Cu sites. The H–Cl bond of HCl can be activated over the tribasic copper chloride, accelerating the surface reaction of vinyl chloride production. This strategy of inducing electron deficiency provides new insight into the rational design of catalysts for the synthesis of vinyl chloride with a high catalytic performance.

Design and analysis of the Macao Science Satellite-1's laser retro-reflector array

The origin and spatial-temporal variation of the Earth’s magnetic field(EMF)is one of the important scientific problems that has long been unsolved.The Macao Science Satellite-1(MSS-1)under construction is China’s first high-precision EMF measurement satellite.To satisfy the highly precise requirements of the MSS-1 orbit measurement,a light,high-precision,four-prism laser retroreflector array was designed.It weighs approximately 285 g,its effective reflection area is greater than 1.77 cm^(2),and its size is 100×100×41 mm.The laser retro-reflector array has excellent performance,and it can achieve a ranging precision at the subcentimeter level for satellite laser ranging.It will be developed and installed on the MSS-1 as a power-free load for high-precision orbit measurement and accurate orbit calibration.The MSS-1 is planned to be brought into the International Laser Ranging Service observations.More than 31satellite laser ranging stations in the International Laser Ranging Service around the world will be able to measure the MSS-1 with long arcs,which will support the scientific mission of high-precision EMF exploration.

Static strength and crashworthiness analysis of a train cowcatcher at a running speed of 160 km/h

The cowcatcher is one of the unique devices at the front end of the train, which can remove obstacles on the track by crashing before the vehicle body to ensure the safety of the train. When a collision accident happens, the cowcatcher serves as the first energy-absorbing structure to dissipate and guide the collision energy. The design of the existing cowcatcher of multiple units generally focuses on the good ability to remove obstacles, while the secondary function, the crashworthiness of orderly deformation under collision, still needs further research. In this study, a finite element model of structural static load and collision analysis was established under standard EN 15227, with the cowcatcher for 160 km/h train as the prototype. Then the solution and simulation process was accomplished under the environment of ANSYS and LS-DYNA. The analysis results showed that the structural static strength of the current cowcatcher met the requirements of the standard EN 15227, and the longitudinal stiffness was evenly distributed. When removing the obstacles with low mass, the impact force was small and the structure would not produce obvious deformation;when removing the obstacles with large mass, the impact force was large and the shear fracture might occur at the connection of the cowcatcher.

直观想象素养下的函数导数试题的命题手法

以2015年高考数学压轴题为例,探讨在直观想象素养指导下,通过研究函数的伸缩变换来创设试题情境的函数导数试题命题手法.旨在为高中数学教师提供有效的教学策略和命题思路.

种猪育种关键技术研究进展

在生猪养殖过程当中,种猪育种是一个非常重要的环节。提高种猪育种水平,可以有效提高生猪养殖的经济效益。因此文章基于育种目标选定,从常规育种技术、分子育种技术、人工授精技术三大方面分析种猪育种的关键技术研究进展。

生长育肥猪常见疾病的临床表现及防控

随着养殖水平不断提高以及居民对猪肉制品消费和需求的不断增加,我国生猪养殖规模的不断扩大,目前生猪存栏量、出栏量均较前期有所提高。我国养猪业在不断发展的同时,也在面临着前所未有的困难和挑战,其中对养猪业和养殖者来说最大的难题,就是猪病的种类不断增加,以及随之不断提升的预防和治疗的难度与成本。特别是对于生长育肥猪来说,一旦患病,便会给养殖者带来巨大的经济损失。文章对目前生猪养殖业中生长育肥猪常见且危害较大的几种疾病的临床表现和防控进行了简要综述。

Assessing the impacts of ecological-living-productive land changes on eco-environmental quality in Xining City on Qinghai-Tibet Plateau, China

The Ecological-living-productive land(ELPL)classification system was proposed in an effort to steer China's land pattern to an ecological-centered path,with the development model shifting from a single function into more integrated multifunction land use.The focus is coordinating the man-land contradictions and developing an intensive,efficient and sustainable land use policy in an increasingly tense relationship between humans and nature.Driven by socioeconomic change and rapid population growth,many cities are undergoing urban sprawl,which involves the consumption of cropland and ecological land and threatens the ecological balance.This paper aims to quantitatively analyze the critical effects of ELPL changes on eco-environmental quality according to land use classification based on leading function of ecology,living and production from 1990 to 2015 with a case study of Xining City.Also,four future land use scenarios were simulated for 2030 using the Future Land Use Simulation(FLUS)model that couples human and natural effects.Our results show a decrease in productive land(PL)and an increase in ecological land(EL)and living land(LL)in Xining City.Forestry ecological land(FEL)covered the top largest proportion;agriculture productive land(APL)showed the greatest reduction and urban and rural living land(U-RLL)presented a dramatic increase.The eco-environmental quality improved in 1990-2010,mainly affected by the conversion of APL to FEL and GEL.However,the encroachment of U-RLL into APL,other ecological land(OEL)and FEL was the main contributor to the decline in eco-environmental quality in 2010-2015 as well as the primary reason for the increase area of lower-quality.The Harmonious Development(HD)-Scenario,characterized by a rational allocation of LL and PL and a better eco-environment,would have implications for planning and monitoring future management of ELPL,and may represent a valuable reference for local policy-makers.

Crystallization Behaviour and Mechanical Properties of Zr65Cu18Ni9A18 Bulk Metallic Glass

Designing and synthesis of cost effective bulk metallic glasses （BMGs） has been of considerable interest during the last decade so that they can be made commercially viable. Among these, Zr-based BMGs have been reported extensively due to their attractive properties, An alloy having composition Zr65Cu18Ni9A18 was designed and synthesized using 2-3 N pure materials by Cu mould casting. The alloy was characterized by X- ray diffraction （XRD）, scanning electron microscopy （SEM）, energy dispersive X-ray spectroscopy （EDS） and high temperature differential scanning calorimetry （DSC）. Thermal parameters like supercooled liquid region △Tx, reduced glass transition temperature Trg, γ and δ parameters were evaluated. Mechanical properties like microhardness, nanohardness, elastic modulus and fracture strength were measured. The alloy showed wide supercooled liquid region of 129＋1 K with improved thermal stability. The alloy has considerable fracture strength along with fair amount of ductility.

Fatigue Characterization on a Cast Aluminum Beam of a High-Speed Train Through Numerical Simulation and Experiments

The cast aluminum beam is a key structure for carrying the body-hung traction motor of a high-speed train;its fatigue property is fundamental for predicting the residual life and service mileage of the structure.To characterize the structural fatigue property,a finite element-based method is developed to compute the stress concentration factor,which is used to obtain the structural fatigue strength reduction factors.A full-scale fatigue test on the cast aluminum beam is designed and implemented for up to ten million cycles,and the corresponding finite element model of the beam is validated using the measured data of the gauges.The results show that the maximum stress concentration occurs at the fillet of the supporting seat,where the structural fatigue strength reduction factor is 2.45 and the calculated fatigue limit is 35.4 MPa.Moreover,no surface cracks are detected using the liquid penetrant test.Both the experimental and simulation results indicate that the cast aluminum beam can satisfy the service life requirements under the designed loading conditions.

The progress of laser ranging technology at Shanghai Astronomical Observatory

As an important station of International Laser Ranging Service(ILRS),Shanghai Astronomical Observatory(SHAO)has upgraded Satellite Laser Ranging(SLR)system with high repetition rate and achieved some technological progress,There are a lot of improvements for overall system performance,such as annual observation passes,measurement precision and quality of observation data.SLR technology with repetition rate of 10 kHz is accomplished firstly in China,and space debris laser ranging technology with200 Hz laser is promoted and proved to be more detective for weak echo,which lead to successful measurement for 40,000 km satellites and space debris within 3000 km.At the same time,SLR based on multi-telescopes and 1064 nm wavelength are planned to make a breakthrough of detection capabilities,and also to expand its application fields.These progresses will be introduced in this paper in detail.

Hybrid Recommendation Based on Graph Embedding

In recent years,online reservation systems of country hotel have become increasingly popular in rural areas.How to accurately recommend the houses of country hotel to the users is an urgent problem to be solved.Aiming at the problem of cold start and data sparseness in recommendation,a Hybrid Recommendation method based on Graph Embedding(HRGE)is proposed.First,three types of network are built,including user-user network based on user tag,househouse network based on house tag,and user-user network based on user behavior.Then,by using the method of graph embedding,three types of network are respectively embedded into low-dimensional vectors to obtain the characterization vectors of nodes.Finally,these characterization vectors are used to make a hybrid recommendation.The datasets in this paper are derived from the Country Hotel Reservation System in Guizhou Province.The experimental results show that,compared with traditional recommendation algorithms,the comprehensive evaluation index(F1)of the HRGE is improved by 20% and the Mean Average Precision(MAP)is increased by 11%.

SnS_2 nanosheets arrays sandwiched by N-doped carbon and TiO_2 for high-performance Na-ion storage

In this paper, SnS_2 nanosheets arrays sandwiched by porous N-doped carbon and TiO_2(TiO_2@SnS_2@N-C) on flexible carbon cloth are prepared and tested as a free-standing anode for high-performance sodium ion batteries. The as-obtained TiO_2@SnS_2@N-C composite delivers a remarkable capacity performance(840 mA h g^(-1) at a current density of 200 mA g^(-1)), excellent rate capability and long-cycling life stability(293 mA h g^(-1) at 1 A g^(-1) after 600 cycles). The excellent electrochemical performance can be attributed to the synergistic effect of each component of the unique hybrid structure, in which the SnS_2 nanosheets with open framworks offer high capacity, while the porous N-doped carbon nanoplates arrays on flexible carbon cloth are able to improve the conductivity and the TiO_2 passivation layer can keep the structure integrity of SnS_2 nanosheets.

Relationship between brachial-ankle pulse wave velocity and metabolic syndrome components in a Chinese population

The purpose of this study was to assess the relationship between arterial stiffness, as measured by brachial-ankle pulse wave velocity （baPWV）, and the presence of the metabolic syndrome （MS） in a Chinese population. A total of 4,445 subjects were enrolled. The prevalence of MS in for the general population, males and females, respectively. our study population was 21.7%, 17.2% and 25.6% With adjustments for age, gender, cigarette smoking, heart rate, total cholesterol, low-density lipoprotein （LDL） cholesterol, and the use of anti-hypertensive drug, the stepwise regression analysis showed that baPWV had a significant relationship with components of MS, including systolic blood pressure （P 〈 0.001）, diastolic blood pressure （P 〈 0.001）, glucose （P 〈 0.001）, highdensity lipoprotein （HDL） cholesterol （P = 0.04）, and triglycerides （P 〈 0.001）, but no relationship with waist circumference （P = 0.25）. With an increase in the number of the MS components, baPWV increased significantly both in women and men. This study indicated that the MS is indeed a risk factor for arterial stiffness. Monitoring of baPWV in patients with MS may help in identifying persons at high risk for cardiovascular disease.

CBL Significance in Pathophysiology Teaching

Objective: To explore the importance of CBL in pathophysiology teaching. Methods: 218 undergraduate clinical medicine students in 2015 grade were divided into CBL group and control group, and each group had 109 students. The CBL group was taught by CBL, while the control group was taught by routine teaching mode. The teaching effects was evaluated by questionnaire survey and stage test. Results: The CBL group was superior to the control group in learning interest, logical thinking, knowledge system construction, comprehensive use of knowledge to solve problems. Conclusion: CBL teaching enhanced students’ understanding of knowledge significantly, and also enhanced their clinical thinking and problem analysis ability.

2020年世界生猪产业发展情况及2021年趋势

2020年世界猪肉总产量有较大幅度下降,为9788万吨,比2019年下降了4.02%,世界猪肉产量下降的主要原因是中国的生猪产能下滑。中国是世界上最大的猪肉生产国与进口国,2020年中国猪肉进口量为480万吨,比2019年上升了95.84%;占全球进口总量的46.31%,比2019年占比上升近17.30个百分点。预计2021年下半年中国生猪出栏量将呈持续增加的态势,年底生猪产能将达到非洲猪瘟疫情之前的水平。中国生猪产能的恢复将带动2021年世界猪肉产量的上升。

基于云服务的棚室蔬菜智能终端系统设计与实现——以黑龙江省为研究案例

棚室蔬菜产业在黑龙江省农业转方式、调结构和供给侧改革中占有重要的战略地位。黑龙江省棚室蔬菜生产规模近年来发展较快,技术支撑需求也与日俱增。本研究针对黑龙江省棚室蔬菜发展规模与技术服务支撑能力不匹配的现状,提出了基于云服务的棚室蔬菜智能终端系统及关键技术的实现方法。本研究以专家服务为主、数据挖掘技术为辅,以物联网设备为感知手段、以智能手机为用户终端,利用云服务对知识、资源、物联网数据的整合配置能力,提供蔬菜专家及棚室蔬菜用户对信息获取、存储、分析和决策的高效解决方案。本研究的部分内容已在黑龙江省农业科研部门、企业、蔬菜合作社、农户等不同用户群体中实验应用,能够为专家提供棚室蔬菜生产环境的远程问诊手段,适用于各类棚室蔬菜应用场景。本研究还提出了对大规模应用场景下的技术解决方案建议,可在全国的棚室蔬菜生产中推广应用,实现更广泛高效的专家技术服务支撑。

Nonreciprocal properties of 1D magnetized plasma photonic crystals with the Fibonacci sequence

In this paper, the nonreciprocal properties of a novel kind of 1D magnetized plasma photonic crystals(MPPCs) with the Fibonacci sequence are investigated. The isolation of the proposed 1D MPPCs is also used to analyze the nonreciprocal properties. Compared to the conventional 1D MPPCs with periodic structure, the nonreciprocal performance can be significantly improved.The effects of several parameters of the proposed 1D MPPCs on the nonreciprocal properties are studied by the transfer matrix method, which includes the incident angle, order of the Fibonacci sequence, plasma frequency, plasma cyclotron frequency and plasma filling factor. The obtained results show that the nonreciprocal propagation properties can be improved by increasing the values of the plasma cyclotron frequency and incident angle, but they will worsen by blindly increasing the order of the Fibonacci sequence, plasma frequency and filling factor of plasma.The peaks of transmittance also are obviously reduced. In addition, the value of isolation will increase with increasing the incident angle, order of Fibonacci sequence, plasma frequency and plasma filling factor. However, when the plasma cyclotron frequency is increased, the value of isolation will be increased at lower frequencies, but is almost unchanged at higher frequencies.

Environmental drivers of phytoplankton crops and taxonomic composition in northeastern Antarctic Peninsula adjacent sea area

The ecosystem of the sea region adjacent to the Antarctic Peninsula is undergoing remarkable physical and biological changes, in the context of global warming. However, understanding of the dynamics of phytoplankton taxonomic composition in this marginal ice zone remains unclear. In this study, seawater samples collected from 36 stations in the northeastern Antarctic Peninsula were analyzed for nutrients and phytoplankton pigments.Combining with CHEMTAX analysis, remote sensing data, and physicochemical measurements, we investigated the relationships between phytoplankton crops, taxonomic composition, and marine environmental drivers.Integrated chlorophyll a(Chl a) concentrations(200 m) varied from 8.9 mg/m^(2)to 64.2 mg/m^(2), with an average of(23.2±12.0) mg/m^(2)and higher phytoplankton biomass concentrated in the coastal region of South Orkney Island and South Shetland Island. Diatoms were the dominant functional group(63%±21%). Higher proportions of diatoms were associated with higher Chl a(r=0.40, p<0.01), stable water columns(r=0.20, p<0.01), higher Si/P ratios(r=0.34, p<0.01), higher photosynthetically active radiation intensity(r=0.64, p<0.01), and higher sea ice melt water contributions(MWC, r=0.20, p<0.01). Conversely, Phaeocystis antarctica contributed a smaller overall proportion(31%±18%) and was more concentrated in the offshore water masses(e.g., Philip Ridge and South Scotia Ridge) with lower light levels(r=-0.58, p<0.01), deeper mixed layer depths(r=0.17, p<0.05), higher nutrient concentrations(e.g., N, P, and Si, r>0.35, p<0.01), and lower MWC(r=-0.20, p<0.01). In comparison, the total contribution from green flagellates(4%±5%), cryptophyta(1%±3%), dinoflagellates(1%±4%), and cyanobacteria(1% ± 5%) was only 6%. In offshore regions with well-mixed water, less varied taxonomic composition and lower crops with a higher proportion of nanophytoplankton were observed. In contrast, significantly decreasing crops below the mixed layer depth was observed in water columns with strong stratification, where the dominant phytoplankter changed from diatoms to P. antarctica. These findings have important implications for better understanding the future dynamics of marine ecosystems in the sea area adjacent to the Antarctic Peninsula.

To Construct High Level Secure Communication System： CTMI Is Not Enough

Public key cryptographic(PKC) algorithms, such as the RSA, elliptic curve digital signature algorithm(ECDSA) etc., are widely used in the secure communication systems, such as OpenSSL, and a variety of information security systems. If designer do not securely implement them, the secret key will be easily extracted by side-channel attacks(SCAs) or combinational SCA thus mitigating the security of the entire communication system. Previous countermeasures of PKC implementations focused on the core part of the algorithms and ignored the modular inversion which is widely used in various PKC schemes. Many researchers believe that instead of straightforward implementation, constant time modular inversion(CTMI) is enough to resist the attack of simple power analysis combined with lattice analysis. However, we find that the CTMI security can be reduced to a hidden t-bit multiplier problem. Based on this feature, we firstly obtain Hamming weight of intermediate data through side-channel leakage. Then, we propose a heuristic algorithm to solve the problem by revealing the secret(partial and full) base of CTMI. Comparing previous nec-essary input message for masking filtering, our procedure need not any information about the secret base of the inversion. To our knowledge, this is the first time for evaluating the practical security of CTMI and experimental results show the fact that CTMI is not enough for high-level secure communication systems.

Extended Bell inequality and maximum violation

The original formula of Bell inequality（BI） in terms of two-spin singlet has to be modified for the entangled-state with parallel spin polarization. Based on classical statistics of the particle-number correlation, we prove in this paper an extended BI, which is valid for two-spin entangled states with both parallel and antiparallel polarizations. The BI and its violation can be formulated in a unified formalism based on the spin coherent-state quantum probability statistics with the statedensity operator, which is separated to the local and non-local parts. The local part gives rise to the BI, while the violation is a direct result of the non-local quantum interference between two components of entangled state. The Bell measuring outcome correlation denoted by PB is always less than or at most equal to one for the local realistic model（PB^lc≤ 1）regardless of the specific superposition coefficients of entangled state. Including the non-local quantum interference the maximum violation of BI is found as PB^max =2, which, however depends on state parameters and three measuring directions as well. Our result is suitable for entangled photon pairs.