We present a novel scheme for dense electron acceleration driven by the laser irradiation of a near-critical-density plasma.The electron reflux effect in a transversely tailored plasma is particularly enhanced in the ...We present a novel scheme for dense electron acceleration driven by the laser irradiation of a near-critical-density plasma.The electron reflux effect in a transversely tailored plasma is particularly enhanced in the area of peak density.We observe a bubble-like distribution of re-injected electrons,which forms a strong quasistatic electromagnetic field that can accelerate electrons longitudinally while also preserving the electron transverse emittance.Simulation results demonstrate that over-dense electrons could be trapped in such an artificial bubble and accelerated to an energy of ~500 MeV.The obtained relativistic electron beam can reach a total charge of up to 0.26 nC and is well collimated with a small divergence of 17 mrad.Moreover,the wavelength of electron oscillation is noticeably reduced due to the shaking of the bubble structure in the laser field.As a result,the energy of the produced photons is substantially increased to the range.This new regime provides a path to generating high-charge electron beams and high-energy-ray sources.展开更多
The theoretical and technological achievements in the damage mechanism and evaluation model obtained through the national basic research program“Key Fundamental Scientific Problems on Mechanical Equipment Remanufactu...The theoretical and technological achievements in the damage mechanism and evaluation model obtained through the national basic research program“Key Fundamental Scientific Problems on Mechanical Equipment Remanufacturing”are reviewed in this work.Large centrifugal compressor impeller blanks were used as the study object.The materials of the blanks were FV520B and KMN.The mechanism and evaluation model of ultra-high cycle fatigue,erosion wear,and corrosion damage were studied via theoretical calculation,finite element simulation,and experimentation.For ultra-high cycle fatigue damage,the characteristics of ultra-high cycle fatigue of the impeller material were clarified,and prediction models of ultra-high cycle fatigue strength were established.A residual life evaluation technique based on the“b-HV-N”(where b was the nonlinear parameter,HV was the Vickers hardness,and N was the fatigue life)double criterion method was proposed.For erosion wear,the flow field of gas-solid two-phase flow inside the impeller was simulated,and the erosion wear law was clarified.Two models for erosion rate and erosion depth calculation were established.For corrosion damage,the electrochemical and stress corrosion behaviors of the impeller material and welded joints in H2S/CO2 environment were investigated.KISCC(critical stress intensity factor)and da/dt(crack growth rate,where a is the total crack length and t is time)varied with H2S concentration and temperature,and their variation laws were revealed.Through this research,the key scientific problems of the damage behavior and mechanism of remanufacturing objects in the multi-strength field and cross-scale were solved.The findings provide theoretical and evaluation model support for the analysis and evaluation of large centrifugal compressor impellers before remanufacturing.展开更多
Electrocatalytic hydrogenation(ECH)enables the sustainable production of chemicals under ambient condition;however,suffers from serious competition with hydrogen(H2)evolution and the use of precious metals as electroc...Electrocatalytic hydrogenation(ECH)enables the sustainable production of chemicals under ambient condition;however,suffers from serious competition with hydrogen(H2)evolution and the use of precious metals as electrocatalysts.Herein,molybdenum disulfide is for the first time developed as an efficient and noble-metal-free catalyst for ECH via in situ intercalation of ammonia or alkyl-amine cations.This interlayer engineering regulates phase transition(2H→1 T),and effectively ameliorates electronic configurations and surface hydrophobicity to promote the ECH of biomass-derived oxygenates,while prohibiting H2 evolution.The optimal one intercalated by dimethylamine(MoS_(2)-DMA)is capable of hydrogenating furfural(FAL)to furfuryl alcohol with high Faradaic efficiency of 86.3%–73.3%and outstanding selectivity of>95.0%at−0.25 to−0.65 V(vs.RHE),outperforming MoS_(2) and other conventional metals.Such prominent performance stems from the enhanced chemisorption and surface hydrophobicity.The chemisorption of H intermediate and FAL,synchronously strengthened on the edge-sites of MoS_(2)-DMA,accelerates the surface elementary step following Langmuir-Hinshelwood mechanism.Moreover,the improved hydrophobicity benefits FAL affinity to overcome diffusion limitation.Discovering the effective modulation of MoS_(2) from a typical H2 evolution electrocatalyst to a promising candidate for ECH,this study broadens the scope to exploit catalysts used for electrochemical synthesis.展开更多
基金supported by the China Postdoctoral Science Foundation(Grant No.2021M692204)the National Natural Science Foundation of China(Grant No.11805278)+3 种基金the Fundamental Research Program of Shenzhen(Grant No.SZWD2021007)the Science and Technology on Plasma Physics Laboratorythe Guangdong Basic and Applied Basic Research Foundation(Grant No.2022A1515010326)the Shenzhen Technology University.
文摘We present a novel scheme for dense electron acceleration driven by the laser irradiation of a near-critical-density plasma.The electron reflux effect in a transversely tailored plasma is particularly enhanced in the area of peak density.We observe a bubble-like distribution of re-injected electrons,which forms a strong quasistatic electromagnetic field that can accelerate electrons longitudinally while also preserving the electron transverse emittance.Simulation results demonstrate that over-dense electrons could be trapped in such an artificial bubble and accelerated to an energy of ~500 MeV.The obtained relativistic electron beam can reach a total charge of up to 0.26 nC and is well collimated with a small divergence of 17 mrad.Moreover,the wavelength of electron oscillation is noticeably reduced due to the shaking of the bubble structure in the laser field.As a result,the energy of the produced photons is substantially increased to the range.This new regime provides a path to generating high-charge electron beams and high-energy-ray sources.
文摘The theoretical and technological achievements in the damage mechanism and evaluation model obtained through the national basic research program“Key Fundamental Scientific Problems on Mechanical Equipment Remanufacturing”are reviewed in this work.Large centrifugal compressor impeller blanks were used as the study object.The materials of the blanks were FV520B and KMN.The mechanism and evaluation model of ultra-high cycle fatigue,erosion wear,and corrosion damage were studied via theoretical calculation,finite element simulation,and experimentation.For ultra-high cycle fatigue damage,the characteristics of ultra-high cycle fatigue of the impeller material were clarified,and prediction models of ultra-high cycle fatigue strength were established.A residual life evaluation technique based on the“b-HV-N”(where b was the nonlinear parameter,HV was the Vickers hardness,and N was the fatigue life)double criterion method was proposed.For erosion wear,the flow field of gas-solid two-phase flow inside the impeller was simulated,and the erosion wear law was clarified.Two models for erosion rate and erosion depth calculation were established.For corrosion damage,the electrochemical and stress corrosion behaviors of the impeller material and welded joints in H2S/CO2 environment were investigated.KISCC(critical stress intensity factor)and da/dt(crack growth rate,where a is the total crack length and t is time)varied with H2S concentration and temperature,and their variation laws were revealed.Through this research,the key scientific problems of the damage behavior and mechanism of remanufacturing objects in the multi-strength field and cross-scale were solved.The findings provide theoretical and evaluation model support for the analysis and evaluation of large centrifugal compressor impellers before remanufacturing.
基金supported by the National Key Research and Development Program of China (2018YFA0209402)the National Natural Science Foundation of China (21773093)
文摘Electrocatalytic hydrogenation(ECH)enables the sustainable production of chemicals under ambient condition;however,suffers from serious competition with hydrogen(H2)evolution and the use of precious metals as electrocatalysts.Herein,molybdenum disulfide is for the first time developed as an efficient and noble-metal-free catalyst for ECH via in situ intercalation of ammonia or alkyl-amine cations.This interlayer engineering regulates phase transition(2H→1 T),and effectively ameliorates electronic configurations and surface hydrophobicity to promote the ECH of biomass-derived oxygenates,while prohibiting H2 evolution.The optimal one intercalated by dimethylamine(MoS_(2)-DMA)is capable of hydrogenating furfural(FAL)to furfuryl alcohol with high Faradaic efficiency of 86.3%–73.3%and outstanding selectivity of>95.0%at−0.25 to−0.65 V(vs.RHE),outperforming MoS_(2) and other conventional metals.Such prominent performance stems from the enhanced chemisorption and surface hydrophobicity.The chemisorption of H intermediate and FAL,synchronously strengthened on the edge-sites of MoS_(2)-DMA,accelerates the surface elementary step following Langmuir-Hinshelwood mechanism.Moreover,the improved hydrophobicity benefits FAL affinity to overcome diffusion limitation.Discovering the effective modulation of MoS_(2) from a typical H2 evolution electrocatalyst to a promising candidate for ECH,this study broadens the scope to exploit catalysts used for electrochemical synthesis.