CTF增效剂提升混凝土抗冻性能研究

本工作以3%质量浓度的NaCl溶液为介质,进行混凝土抗冻性试验,通过超声波波速损失率(C_(n))、质量剥蚀量(M_(B))和溶液吸入率(W_(S))三种指标研究了CTF(Coal tar fuel)增效剂对混凝土抗冻性能的影响。同时,深入剖析了CTF增效剂对混凝土内部气孔结构的影响,并基于气孔分形模型,建立了分形维数(D)与超声波波速损失率(C_(n))的关系。结果表明:CTF增效剂能有效提升混凝土的抗冻性能,且当掺量为0.7%时提升效果最为显著。与普通混凝土相比,降低10%的水泥用量并掺加0.7%的CTF增效剂时,冻融循环100次后,混凝土超声波波速损失率(C_(n))较小,且质量剥蚀量(M_(B))降低了12.51%。此外,NaCl溶液吸入率(W_(S))降低了0.83%,内部直径规格小于100μm的气孔个数增加了180%,大于100μm的气孔个数减少了18.18%。

Reliability Analysis of Reinforcement Based on GM(1,1)-Markov Semi-immersion Test

To investigate the corrosion degradation law and service life of reinforced concrete in various salt solution environments,reinforced concrete specimens were semi-immersed in 3%Na_(2)CO_(3)(N3-0-0),3%Na_(2)CO_(3)+3%NaCl(N3-Cl3-0)and 3%Na_(2)CO_(3)+3%NaCl+3%Na_(2)SO_(4)(N3-Cl3-S3)salt solutions.The electrochemical workstation was used for regular non-destructive testing,and the polarization curve and related electrochemical parameters were used as the macroscopic durability evaluation indicators,while microscopic analysis of steel bar corrosion products was performed in combination with SEM and EDS.In addition,the corrosion current density degradation model of GM(1,1)was established and compared with the modified GM(1,1)-Markov degradation model.The results showed that the prediction error of the GM(1,1)-Markov model was smaller and more accurate than that of GM(1,1).The reinforced concrete specimens in the N3-0-0,N3-Cl3-0 and N3-Cl3-S3 solutions reached the failure state in 3.08,1.67,and 2.30 years,respectively,as predicted by the GM(1,1)-Markov model.According to ESM and EDS microscopic analysis of reinforcement,carbonate had no significant effect on reinforcement corrosion,chloride ions played a dominant role in reinforcement corrosion,and sulfate ion improved concrete's resistance to chloride ion corrosion.Based on GM(1,1)-Markov model,the failure and damage of reinforced concrete in saline soil areas can be quantitatively evaluated in the whole life cycle,which provides a theoretical basis for the early maintenance or reinforcing of reinforced concrete.

Accelerated Deterioration Mechanism and Reliability Evaluation of Concrete in Saline Soil Area

To reveal the deterioration mechanism and service life of concrete durability in the western saline soil area,the indoor accelerated test of the concrete specimen was simulated in the coupled environment of salt erosion and dry-wet cycles in the west saline soil area of China.The deterioration mechanism of concrete durability was revealed through the relative dynamic elastic modulus,relative quality evaluation parameters,SEM,and XRD evaluation indexes.Random Wiener distribution function was used for modeling life prediction.The results show that the relative dynamic elastic modulus evaluation parameter as an evaluation index of concrete durability under various environmental coupling effects is more reliable than the relative quality,there were holes and cracks in the concrete,and needle-like and layered crystals grow from the internal cracks.The corrosion products include ettringite,gypsum and other expansive crystals and non-gelling Mg(OH)_(2);the expansion stress caused by physical,chemical reaction,and temperature change under the action of drywet cycle aggravates the formation and development of cracks.The random Wiener distribution function can describe the degradation process of concrete specimen durability,and the established concrete reliability function can intuitively reflect the service life of concrete specimens.