We consider a bistable mesoscopic chemical reaction system and calculate entropy produc- tion along the dominant pathway during nonequilibrium phase transition. Using probability generating function method and eikonal...We consider a bistable mesoscopic chemical reaction system and calculate entropy produc- tion along the dominant pathway during nonequilibrium phase transition. Using probability generating function method and eikonal approximation, we first convert the chemical master equation into the classical Hamilton-Jacobi equation, and then find the dominant pathways between two steady states in the phase space by calculating zero-energy trajectories. We find that entropy productions are related to the actions of the forward and backward dominant pathways. At the coexistence point where the stabilities of the two steady states are equiv alent, both the system entropy change and the medium entropy change are zero; whereas at non-coexistence point both of them are nonzero.展开更多
Heterogeneous mean-field theory is commonly used methodology to study dynamical processes on complex networks,such as epidemic spreading and phase transitions in spin models.In this paper,we propose an improved hetero...Heterogeneous mean-field theory is commonly used methodology to study dynamical processes on complex networks,such as epidemic spreading and phase transitions in spin models.In this paper,we propose an improved heterogeneous mean-field theory for studying the Ising model on complex networks.Our method shows a more accurate prediction in the critical temperature of the Ising model than the previous heterogeneous mean-field theory.The theoretical results are validated by extensive Monte Carlo simulations in various types of networks.展开更多
文摘We consider a bistable mesoscopic chemical reaction system and calculate entropy produc- tion along the dominant pathway during nonequilibrium phase transition. Using probability generating function method and eikonal approximation, we first convert the chemical master equation into the classical Hamilton-Jacobi equation, and then find the dominant pathways between two steady states in the phase space by calculating zero-energy trajectories. We find that entropy productions are related to the actions of the forward and backward dominant pathways. At the coexistence point where the stabilities of the two steady states are equiv alent, both the system entropy change and the medium entropy change are zero; whereas at non-coexistence point both of them are nonzero.
基金Supported by the National Natural Science Foundation of China under Grant Nos.11875069,11405001the Key Scientific Research Fund of Anhui Provincial Education Department under Grant No.KJ2019A0781
文摘Heterogeneous mean-field theory is commonly used methodology to study dynamical processes on complex networks,such as epidemic spreading and phase transitions in spin models.In this paper,we propose an improved heterogeneous mean-field theory for studying the Ising model on complex networks.Our method shows a more accurate prediction in the critical temperature of the Ising model than the previous heterogeneous mean-field theory.The theoretical results are validated by extensive Monte Carlo simulations in various types of networks.