The Fe-B alloy containing chromium and nickel was prepared, and the microstructure and erosioncorrosion behavior of the alloy were investigated by means of scanning electron microscopy, energy dispersive X-ray spectro...The Fe-B alloy containing chromium and nickel was prepared, and the microstructure and erosioncorrosion behavior of the alloy were investigated by means of scanning electron microscopy, energy dispersive X-ray spectrometry, X-ray diffraction analysis, Leica digital image analysis, a hardness tester and an erosioncorrosion tester. Cr28 white cast iron was used for comparison. Results show that the microstructures of both as-cast and heat-treated Fe-B alloys consist of austenite and borocarbide. The nickel and chromium elements are mainly distributed over the matrix and borocarbide, respectively. The hardness of the austenite matrix and the Rockwell hardness of heat-treated Fe-B alloy are higher than those of as-cast Fe-B alloy. In the erosioncorrosion test of the slurry, the erosion-corrosion weight loss of Fe-B alloy is lower than that of Cr28 white cast iron, indicating the Fe-B alloy displays higher erosion-corrosion resistance.展开更多
The microstructures and abrasion wear resistance of directional solidification Fe-B alloy have been investigated using optical microscopy, X-ray diffraction, scanning electron microscopy and laser scanning microscopy....The microstructures and abrasion wear resistance of directional solidification Fe-B alloy have been investigated using optical microscopy, X-ray diffraction, scanning electron microscopy and laser scanning microscopy. The results show that the microstructure of as-cast Fe-B alloy consists of ferrite, pearlite and eutectic boride. After heat treatment, the microstructure is composed of boride and martensite. The plane which is perpendicular to the boride growth direction possesses the highest hardness. In two-body abrasive wear tests, the silicon carbide abrasive can cut the boride and martensite matrix synchronously, and the wear mechanism is micro cutting mechanism. The worn surface roughness and the wear weight loss both increase with the increasing contact load. Moreover, when the boride growth direction is perpendicular to the worn surface, the highest hardness plane of the boride can effectively oppose abrasion, and the martensite matrix can surround and support borides perfectly.展开更多
The microstructure, mechanical properties and wear resistance of high chromium cast steel containing boron after different heat treatments were studied by means of the optical microscopy (OM), the scanning electron ...The microstructure, mechanical properties and wear resistance of high chromium cast steel containing boron after different heat treatments were studied by means of the optical microscopy (OM), the scanning electron microscopy (SEM), X-ray diffraction (XRD), hardness, impact toughness, tensile and pin-on-disc abrasion tests. The results show that as cast microstructures of boron-free high chromium steel consist of martensite and a few (Cr, Fe)_7C_3 carbide, and the macro-hardness of boron-free high chromium steel is 55-57 HRC. After 0.5 mass% B was added into high chromium cast steel, as-cast structure transforms into eutectic (Fe, Cr)2B, (Cr, Fe)7 (C, B)a and martensite, and the macro-hardness reaches 58-60 HRC. High temperature quenching leads to the disconnection and isolated distribution of boride, and there are many (Cr,Fe)_23 (C,B)_6 precipitated phases in the quenching structure. Quenching from 1050 ℃, high chromium steel obtained the highest hardness, and the hardness of high chromium cast steel containing boron is higher than that of boron-free high chromium steel. The change of quenching temperature has no obvious effect on impact toughness of high chromium steel, and the increase of quenching temperature leads to tensile strength having an increasing tendency. At the same quenching temperature, the wear resistance of high chromium cast steel containing boron is more excellent than that of boron-free high chromium steel. High chromium cast steel guide containing boron has good performance while using in steel bar mill.展开更多
In this paper, in situ (Ti, Nb)C particle ((Ti, Nb)Cp) reinforced Fe-based composite coatings were produced by laser cladding on the surface of the high carbon steel. The effects of heat input on the microstruct...In this paper, in situ (Ti, Nb)C particle ((Ti, Nb)Cp) reinforced Fe-based composite coatings were produced by laser cladding on the surface of the high carbon steel. The effects of heat input on the microstructure, distribution characteristics of particle, and mechanical properties of the coating were investigated. The results show that (Ti, Nb)C multiple carbide particle is synthesized during solidification of molten pool. The size of particle coarsens gradually, the area ratio of particle increases, and the amount of particles presents a non-monotonous variation with the increase in energy density. The mechanical properties of the coating are improved dramatically compared with those of the substrate, benefiting from its higher hardness and dispersed in situ (Ti, Nb)Cp in it. With the change in heat input, the mechanical performances of the coating vary except the hardness. When energy density is 1 × 10^5 J.mm-2, tensile strength and wear resistance of the coating achieve optimal value due to moderate content and size of the particle in the coating.展开更多
(Ti, Nb)C reinforced Fe based laser coatings were prepared with normal and high scanning velocities of the laser beam. The distribution characteristics of reinforced particles in the coatings were investigated. The ...(Ti, Nb)C reinforced Fe based laser coatings were prepared with normal and high scanning velocities of the laser beam. The distribution characteristics of reinforced particles in the coatings were investigated. The mechanical properties of coatings were tested. The results showed that the morphologies of the microstructure and the reinforced particle changed dramatically at high solidification rate due to rapid laser processing compared with that prepared by normal processing. Two kinds of particles were observed in the coating. One was (Ti, Nb)C multiple carbide particle with the size of micron and sub micron scales, in which a mass of dislocations were found. Another was nano sized particle including a Fe and (Ti, Nb)C obtained by rapid solidification. The microstructure of the coatings was highly refined and a large number of twin crystals were found in matrix. The resuhs of mechanical properties test revealed that the wear resistance of the coaling was improved by rapid laser processing, compared with that of the coating prepared with normal speeds. The ahove-mentioned conclusion indicated that rapid laser cladding can promote not on ly the processing efficiency but also lhe mechanical properties of the coating.展开更多
基金financially supported by the National Natural Science Foundation of China under Grant No.51705414the Huozhou Coal Electricity Group Co.,Ltd.of China under Grant No.HZMDJSHT20007
文摘The Fe-B alloy containing chromium and nickel was prepared, and the microstructure and erosioncorrosion behavior of the alloy were investigated by means of scanning electron microscopy, energy dispersive X-ray spectrometry, X-ray diffraction analysis, Leica digital image analysis, a hardness tester and an erosioncorrosion tester. Cr28 white cast iron was used for comparison. Results show that the microstructures of both as-cast and heat-treated Fe-B alloys consist of austenite and borocarbide. The nickel and chromium elements are mainly distributed over the matrix and borocarbide, respectively. The hardness of the austenite matrix and the Rockwell hardness of heat-treated Fe-B alloy are higher than those of as-cast Fe-B alloy. In the erosioncorrosion test of the slurry, the erosion-corrosion weight loss of Fe-B alloy is lower than that of Cr28 white cast iron, indicating the Fe-B alloy displays higher erosion-corrosion resistance.
基金financially supported by the National Natural Science Foundation of China(51641105)the Natural Science Basic Research Plan in Shaanxi Province of China(2014JQ2-5028)+4 种基金the Scientific Research Program Funded by Shaanxi Provincial Education Department(15JK1486)the Open Research Subject of Key Laboratory of Special Materials and Manufacturing Technology in Sichuan Provincial Universities(szjj2016-089)the Huozhou Coal Electricity Group Co.,Ltd.of China(HZMDJSHT20007)the International S&T Cooperation Projects of China(2015DFR50990)the International S&T Cooperation Projects of Qinghai Province(2014HZ819 and 2015HZ811)
文摘The microstructures and abrasion wear resistance of directional solidification Fe-B alloy have been investigated using optical microscopy, X-ray diffraction, scanning electron microscopy and laser scanning microscopy. The results show that the microstructure of as-cast Fe-B alloy consists of ferrite, pearlite and eutectic boride. After heat treatment, the microstructure is composed of boride and martensite. The plane which is perpendicular to the boride growth direction possesses the highest hardness. In two-body abrasive wear tests, the silicon carbide abrasive can cut the boride and martensite matrix synchronously, and the wear mechanism is micro cutting mechanism. The worn surface roughness and the wear weight loss both increase with the increasing contact load. Moreover, when the boride growth direction is perpendicular to the worn surface, the highest hardness plane of the boride can effectively oppose abrasion, and the martensite matrix can surround and support borides perfectly.
基金Item Sponsored by National Natural Science Foundation of China(51274016)Natural Science Foundation of Beijing of China(2142009)Plan Item of Beijing Education Committee of China(KM201310005003)
文摘The microstructure, mechanical properties and wear resistance of high chromium cast steel containing boron after different heat treatments were studied by means of the optical microscopy (OM), the scanning electron microscopy (SEM), X-ray diffraction (XRD), hardness, impact toughness, tensile and pin-on-disc abrasion tests. The results show that as cast microstructures of boron-free high chromium steel consist of martensite and a few (Cr, Fe)_7C_3 carbide, and the macro-hardness of boron-free high chromium steel is 55-57 HRC. After 0.5 mass% B was added into high chromium cast steel, as-cast structure transforms into eutectic (Fe, Cr)2B, (Cr, Fe)7 (C, B)a and martensite, and the macro-hardness reaches 58-60 HRC. High temperature quenching leads to the disconnection and isolated distribution of boride, and there are many (Cr,Fe)_23 (C,B)_6 precipitated phases in the quenching structure. Quenching from 1050 ℃, high chromium steel obtained the highest hardness, and the hardness of high chromium cast steel containing boron is higher than that of boron-free high chromium steel. The change of quenching temperature has no obvious effect on impact toughness of high chromium steel, and the increase of quenching temperature leads to tensile strength having an increasing tendency. At the same quenching temperature, the wear resistance of high chromium cast steel containing boron is more excellent than that of boron-free high chromium steel. High chromium cast steel guide containing boron has good performance while using in steel bar mill.
基金financially supported by the National Natural Science Foundation of China(No.51275006)
文摘In this paper, in situ (Ti, Nb)C particle ((Ti, Nb)Cp) reinforced Fe-based composite coatings were produced by laser cladding on the surface of the high carbon steel. The effects of heat input on the microstructure, distribution characteristics of particle, and mechanical properties of the coating were investigated. The results show that (Ti, Nb)C multiple carbide particle is synthesized during solidification of molten pool. The size of particle coarsens gradually, the area ratio of particle increases, and the amount of particles presents a non-monotonous variation with the increase in energy density. The mechanical properties of the coating are improved dramatically compared with those of the substrate, benefiting from its higher hardness and dispersed in situ (Ti, Nb)Cp in it. With the change in heat input, the mechanical performances of the coating vary except the hardness. When energy density is 1 × 10^5 J.mm-2, tensile strength and wear resistance of the coating achieve optimal value due to moderate content and size of the particle in the coating.
基金Item Sponsored by National Natural Science Foundation of China(51275006,51274016)Natural Science Foundation of Beijing of China(2142009)Scientific Plan Item of Beijing Education Committee of China(PXM2015-014204-500170)
文摘(Ti, Nb)C reinforced Fe based laser coatings were prepared with normal and high scanning velocities of the laser beam. The distribution characteristics of reinforced particles in the coatings were investigated. The mechanical properties of coatings were tested. The results showed that the morphologies of the microstructure and the reinforced particle changed dramatically at high solidification rate due to rapid laser processing compared with that prepared by normal processing. Two kinds of particles were observed in the coating. One was (Ti, Nb)C multiple carbide particle with the size of micron and sub micron scales, in which a mass of dislocations were found. Another was nano sized particle including a Fe and (Ti, Nb)C obtained by rapid solidification. The microstructure of the coatings was highly refined and a large number of twin crystals were found in matrix. The resuhs of mechanical properties test revealed that the wear resistance of the coaling was improved by rapid laser processing, compared with that of the coating prepared with normal speeds. The ahove-mentioned conclusion indicated that rapid laser cladding can promote not on ly the processing efficiency but also lhe mechanical properties of the coating.