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Preparation and characterization of a novel antibacterial acrylate polymer composite modified with capsaicin 被引量:1
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作者 Jianhui Zhou Xiaotong Zhang +4 位作者 Ying Yan Jianfeng Hu hangwang Yan Cai Jinqing Qu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第12期3043-3052,共10页
A novel antibacterial acrylate polymer composite modified with capsaicin was successfully synthesized by a two-step reaction.Capsaicin and acryloyl chloride were firstly esterified,and then applied to solution polymer... A novel antibacterial acrylate polymer composite modified with capsaicin was successfully synthesized by a two-step reaction.Capsaicin and acryloyl chloride were firstly esterified,and then applied to solution polymerization with acrylate monomers and styrene.The yield of the esterified products was about 85.3%.The polymer was characterized by Fourier transform infrared spectroscopy(FTIR),gel permeation chromatography(GPC),thermogravimetric analysis(TGA),contact angle(CA)and antibacterial ring tests.The number-average molecular weight(M_n)of the polymer was 27214,based on the capsaicin-acrylate dosage of 6.5 wt%.The TGA revealed a stable thermal property.The contact angles of the polymers films on tinplate increased from 77.5°to 86.2°with the increasing amount of capsaicin-acrylate.The antibacterial tests demonstrated excellent antimicrobial capability of the polymers. 展开更多
关键词 CAPSAICIN ACRYLATE POLYMER Solution POLYMERIZATION ANTIBACTERIAL
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含功能化咪唑鎓离聚物增韧改性聚乳酸的研究 被引量:2
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作者 王行 胡浩东 +3 位作者 陈相见 潘莉 张坤玉 李悦生 《高分子学报》 SCIE CAS CSCD 北大核心 2021年第10期1323-1333,共11页
以生物质来源的氯醚弹性体和羟乙基咪唑、PEG端咪唑单体为原料,通过简单的季胺化和离子交换反应,成功制备了2种新型功能化的生物基离聚物(ECO-OH-PF_(6),ECO-EG-PF_(6)),并将其应用于聚乳酸的共混增韧改性.离聚物ECO-EG-PF_(6)呈现典型... 以生物质来源的氯醚弹性体和羟乙基咪唑、PEG端咪唑单体为原料,通过简单的季胺化和离子交换反应,成功制备了2种新型功能化的生物基离聚物(ECO-OH-PF_(6),ECO-EG-PF_(6)),并将其应用于聚乳酸的共混增韧改性.离聚物ECO-EG-PF_(6)呈现典型的弹性体特征,而ECO-OH-PF_(6)表现为塑料性能.在聚乳酸(PLA)与离聚物共混体系中,ECO-OH-PF_(6)表现出对PLA更优的增韧效果.PLA/ECO-OH-PF_(6)(80/20)共混物断裂伸长率可提高至241%,而拉伸强度可保持在47.8 MPa.动态机械分析和扫描电子显微镜的结果表明离子-偶极相互作用和氢键相互作用使得ECO-OH-PF_(6)与PLA组分之间具有良好的相容性,形成了较强的界面粘附.而且由于折光指数相匹配,PLA/ECO-OH-PF_(6)共混物表现出良好的透明性,可见光范围内的透过率可达77%~87%.因而ECO-OH-PF_(6)可成为PLA良好的增韧改性剂,促进PLA基材料在透明包装等领域获得广阔的应用. 展开更多
关键词 聚乳酸 离聚物 非价键相互作用 增韧 透明性
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