Structural Health Monitoring(SHM)systems have become a crucial tool for the operational management of long tunnels.For immersed tunnels exposed to both traffic loads and the effects of the marine environment,efficient...Structural Health Monitoring(SHM)systems have become a crucial tool for the operational management of long tunnels.For immersed tunnels exposed to both traffic loads and the effects of the marine environment,efficiently identifying abnormal conditions from the extensive unannotated SHM data presents a significant challenge.This study proposed amodel-based approach for anomaly detection and conducted validation and comparative analysis of two distinct temporal predictive models using SHM data from a real immersed tunnel.Firstly,a dynamic predictive model-based anomaly detectionmethod is proposed,which utilizes a rolling time window for modeling to achieve dynamic prediction.Leveraging the assumption of temporal data similarity,an interval prediction value deviation was employed to determine the abnormality of the data.Subsequently,dynamic predictive models were constructed based on the Autoregressive Integrated Moving Average(ARIMA)and Long Short-Term Memory(LSTM)models.The hyperparameters of these models were optimized and selected using monitoring data from the immersed tunnel,yielding viable static and dynamic predictive models.Finally,the models were applied within the same segment of SHM data,to validate the effectiveness of the anomaly detection approach based on dynamic predictive modeling.A detailed comparative analysis discusses the discrepancies in temporal anomaly detection between the ARIMA-and LSTM-based models.The results demonstrated that the dynamic predictive modelbased anomaly detection approach was effective for dealing with unannotated SHM data.In a comparison between ARIMA and LSTM,it was found that ARIMA demonstrated higher modeling efficiency,rendering it suitable for short-term predictions.In contrast,the LSTM model exhibited greater capacity to capture long-term performance trends and enhanced early warning capabilities,thereby resulting in superior overall performance.展开更多
During the long term evolution of globular clusters(GCs), some member stars are lost to the field. The recently found nitrogen-rich(N-rich) metal-poor field stars are promising candidates of these GC escapees, since N...During the long term evolution of globular clusters(GCs), some member stars are lost to the field. The recently found nitrogen-rich(N-rich) metal-poor field stars are promising candidates of these GC escapees, since N enhancement is the fingerprint of chemically enhanced populations in GCs. In this work, we discuss the possibility of identifying N-rich metal-poor field stars with the upcoming Chinese Space Station Telescope(CSST). We focus on the main survey camera with NUV, u, g, r, i, z, y filters and slitless spectrograph with a resolution about 200.The combination of UV sensitive equipment and prominent N-related molecular lines in the UV band bodes well for the identification: the color–color diagram of(u-g) versus(g-r) is capable of separating N-rich field stars from normal halo stars, if metallicity can be estimated without using the information on u-band photometry.Besides, the synthetic spectra show that a signal-to-noise ratio of 10 is sufficient to identify N-rich field stars. In the near future, a large sample of N-rich field stars found by CSST, combined with state-of-the-art N-body simulations will be crucial to deciphering GC-Galaxy co-evolution.展开更多
The electrochemical CO_(2)reduction reaction to produce multi-carbon(C_(2+)) hydrocarbons or oxygenate compounds is a promising route to obtain a renewable fuel of high energy density.However,producing C_(2+)at high c...The electrochemical CO_(2)reduction reaction to produce multi-carbon(C_(2+)) hydrocarbons or oxygenate compounds is a promising route to obtain a renewable fuel of high energy density.However,producing C_(2+)at high current densities is still a challenge.Herein,we develop a Cu-Zn alloy/Cu-Zn aluminate oxide composite electrocatalytic system for enhanced conversion of CO_(2)to C_(2+)products.The Cu-Zn-Al-Layered Double Hydroxide(LDH) is used as a precursor to decompose into uniform Cu-Zn oxide/Cu-Zn aluminate pre-catalyst.Under electrochemical reduction,Cu-Zn oxide generates Cu-Zn alloy while Cu-Zn aluminate oxide remains unchanged.The alloy and oxide are closely stacked and arranged alternately,and the aluminate oxide induces the strong electron interaction of Cu,Zn and Al,creating a large number of highly active reaction interfaces composed of 0 to+3 valence metal sites.With the help of the interface effect,the optimized Cu_(9)Zn_(1)/Cu_(0.8)Zn_(0.2)Al_(2)O_(4)catalyst achieves a Faradaic efficiency of 88.5% for C_(2+)products at a current density of 400 mA cm^(-2)at-1.15 V versus reversible hydrogen electrode.The in-situ Raman and attenuate total reflectance-infrared absorption spectroscopy(ATR-IRAS) spectra show that the aluminate oxide at the interface significantly enhances the adsorption and activation of CO_(2)and the dissociation of H2O and strengthens the adsorption of CO intermediates,and the alloy promotes the C-C coupling to produce C_(2+)products.This work provides an efficient strategy to construct highly active reaction interfaces for industrial-scale electrochemical CO_(2)RR.展开更多
The electrochemical oxygen reduction reaction(ORR) and oxygen evolution reaction(OER) are fundamental processes in a range of energy conversion devices such as fuel cells and metal–air batteries. ORR and OER both hav...The electrochemical oxygen reduction reaction(ORR) and oxygen evolution reaction(OER) are fundamental processes in a range of energy conversion devices such as fuel cells and metal–air batteries. ORR and OER both have significant activation barriers, which severely limit the overall performance of energy conversion devices that utilize ORR/OER. Meanwhile, ORR is another very important electrochemical reaction involving oxygen that has been widely investigated. ORR occurs in aqueous solutions via two pathways: the direct 4-electron reduction or 2-electron reduction pathways from O_(2) to water(H_2O) or from O_(2) to hydrogen peroxide(H_2O_(2)). Noble metal electrocatalysts are often used to catalyze OER and ORR, despite the fact that noble metal electrocatalysts have certain intrinsic limitations, such as low storage. Thus, it is urgent to develop more active and stable low-cost electrocatalysts, especially for severe environments(e.g., acidic media). Theoretically, an ideal oxygen electrocatalyst should provide adequate binding to oxygen species. Transition metals not belonging to the platinum group metal-based oxides are a low-cost substance that could give a d orbital for oxygen species binding. As a result, transition metal oxides are regarded as a substitute for typical precious metal oxygen electrocatalysts. However, the development of oxide catalysts for oxygen reduction and oxygen evolution reactions still faces significant challenges, e.g., catalytic activity, stability, cost, and reaction mechanism. We discuss the fundamental principles underlying the design of oxide catalysts, including the influence of crystal structure, and electronic structure on their performance. We also discuss the challenges associated with developing oxide catalysts and the potential strategies to overcome these challenges.展开更多
电催化二氧化碳还原反应(CO_(2)RR)可以将二氧化碳转化为具有高经济价值的碳氢化合物,被认为是实现碳中和并缓解能源危机的一种有潜力的技术.铜(Cu)作为一种最有应用前景的非贵金属催化剂之一,表现出较高的催化CO_(2)RR转化为多碳产物(C...电催化二氧化碳还原反应(CO_(2)RR)可以将二氧化碳转化为具有高经济价值的碳氢化合物,被认为是实现碳中和并缓解能源危机的一种有潜力的技术.铜(Cu)作为一种最有应用前景的非贵金属催化剂之一,表现出较高的催化CO_(2)RR转化为多碳产物(C_(2+))的活性.然而,电催化CO_(2)还原成C_(2+)产物涉及一个动力学过程缓慢的C-C偶联反应,这导致C_(2+)产物的选择性较低,电流密度低,阻碍了其在工业电解槽中的实际应用.同时,CO_(2)RR产物的选择性不仅取决于热力学速率决定步骤,还取决于传质控制动力学.CO_(2)RR发生在固-气-液三相反应界面,气-液的平衡扩散可以有效抑制析氢竞争反应,进而提高CO_(2)RR的反应效率.本文设计合成了一种富晶界的Cu纳米带催化剂,并构建了气-液平衡扩散的电极结构,用于高效电催化二氧化碳还原制备乙烯(C_(2)H_(4)).以一种碱式碳酸铜(Cu_(2)CO_(3)(OH)_(2))纳米带为前驱体,在原位电化学还原条件下,前驱体中的Cu2+离子获得电子被还原为金属Cu,而释放的CO_(3)2-和OH-混合阴离子调节金属Cu的生长.生成的Cu纳米带由细小的纳米颗粒堆积而成,并暴露出大量的由Cu(111),Cu(200)和Cu(220)晶面形成的富晶界结构(GBs).同时,在CO_(2)RR测试中发现催化剂层的厚度是影响CO_(2)和电解质传质的关键因素.通过调整催化层厚度,CO_(2)和电解质可以同时到达催化剂表面,参与到CO_(2)RR中,实现了气-液平衡扩散,有效抑制了氢析出副反应.在晶界效应和气-液平衡扩散的协同作用下,优化后的电极在电流密度为700 mA cm^(-2)时,对C_(2)H_(4)和C_(2+).产物的法拉第效率分别高达67.2%和82.1%.此外,C_(2)H_(4)的部分电流密度可高达505 mA cm^(-2),高于大多数文献报道的结果.原位拉曼光谱和衰减全内反射表面增强红外吸收光谱结果表明,丰富的晶;界结构增强了CO_(2)在催化剂表面的活化,显著促进了*CO中间体的形成和吸附,加速了C-C偶联过程形成*OCCO和*OCCOH中间体,提高了C_(2)H_(4)和其他C_(2+)产物的产率.综上,本文设计了一种高活性Cu催化剂和电极结构,为高效电催化CO_(2)还原为C_(2)H_(4)等C_(2+)产物提供参考.展开更多
A catalog of more than 43,000 M giant stars has been selected by Li et al.from the ninth data release of LAMOST.Using the data-driven method SLAM,we obtain the stellar parameters(T_(eff),logg,[M/H],[α/M])for all the ...A catalog of more than 43,000 M giant stars has been selected by Li et al.from the ninth data release of LAMOST.Using the data-driven method SLAM,we obtain the stellar parameters(T_(eff),logg,[M/H],[α/M])for all the M giant stars with uncertainties of 57 K,0.25 dex,0.16 dex and 0.06 dex at SNR>100,respectively.With those stellar parameters,we constrain the absolute magnitude in the K-band,which brings distance with relative uncertainties around 25%statistically.Radial velocities are also calculated by applying cross correlation on the spectra between 8000 and 8950?with synthetic spectra from ATLAS9,which covers the CaⅡtriplet.Comparison between our radial velocities and those from APOGEE DR17 and Gaia DR3 shows that our radial velocities have a system offset and dispersion around 1 and 4.6 km s^(-1),respectively.With the distances and radial velocities combining with the astrometric data from Gaia DR3,we calculate the full 6D position and velocity information,which are able to be used for further chemo-dynamic studies on the disk and substructures in the halo,especially the Sagittarius Stream.展开更多
LAMOST-MRS-B is one of the sub-surveys of LAMOST medium-resolution(R~7500)spectroscopic survey.It aims at studying the statistical properties(e.g.,binary fraction,orbital period distribution,mass ratio distribution)of...LAMOST-MRS-B is one of the sub-surveys of LAMOST medium-resolution(R~7500)spectroscopic survey.It aims at studying the statistical properties(e.g.,binary fraction,orbital period distribution,mass ratio distribution)of binary stars and exotic stars.We intend to observe about 30000 stars(10 mag≤G<14.5 mag)with at least 10 visits in five years.We first planned to observe 25 plates around the galactic plane in 2018.Then the plates were reduced to 12 in 2019 because of the limitation of observation.At the same time,two new plates located at the high galactic latitude were added to explore binary properties influenced by the different environments.In this survey project,we set the identified exotic and low-metallicity stars with the highest observation priorities.For the rest of the selected stars,we gave the higher priority to the relatively brighter stars in order to obtain high quality spectra as many as possible.Spectra of49129 stars have been obtained in LAMOST-MRS-B field and released in DR8,of which 28828 and 3375 stars have been visited more than twice and ten times with SNR≥10,respectively.Most of the sources are B-,A-,and F-type stars with-0.6<[Fe/H]<0.4 dex.We also obtain 347 identified variable and exotic stars and about 250 stars with[Fe/H]<-1 dex.We measure radial velocities(RVs)by using 892233 spectra of the stars.The uncertainties of RV achieve about 1 km·s^(-1)and 10 km·s^(-1)for 95%of late-and early-type stars,respectively.The datasets presented in this paper are available at http://www.doi.org/10.57760/sciencedb.j00113.00035.展开更多
Background:Hippocampal damage caused by status epilepticus(SE)can bring about cognitive decline and emotional disorders,which are common clinical comorbidities in patients with epilepsy.It is therefore imperative to d...Background:Hippocampal damage caused by status epilepticus(SE)can bring about cognitive decline and emotional disorders,which are common clinical comorbidities in patients with epilepsy.It is therefore imperative to develop a novel therapeutic strat-egy for protecting hippocampal damage after SE.Mitochondrial dysfunction is one of contributing factors in epilepsy.Given the therapeutic benefits of mitochondrial replenishment by exogenous mitochondria,we hypothesized that transplantation of mitochondria would be capable of ameliorating hippocampal damage following SE.Methods:Pilocarpine was used to induced SE in mice.SE-generated cognitive de-cline and emotional disorders were determined using novel object recognition,the tail suspension test,and the open field test.SE-induced hippocampal pathology was assessed by quantifying loss of neurons and activation of microglia and astrocytes.The metabolites underlying mitochondrial transplantation were determined using metabonomics.Results:The results showed that peripheral administration of isolated mitochon-dria could improve cognitive deficits and depressive and anxiety-like behaviors.Exogenous mitochondria blunted the production of reactive oxygen species,pro-liferation of microglia and astrocytes,and loss of neurons in the hippocampus.The metabonomic profiles showed that mitochondrial transplantation altered multiple metabolic pathways such as sphingolipid signaling pathway and carbon metabolism.Among potential affected metabolites,mitochondrial transplantation decreased levels of sphingolipid(d18:1/18:0)and methylmalonic acid,and elevated levels of D-fructose-1,6-bisphosphate.Conclusion:To the best of our knowledge,these findings provide the first direct ex-perimental evidence that artificial mitochondrial transplantation is capable of amelio-rating hippocampal damage following SE.These new findings support mitochondrial transplantation as a promising therapeutic strategy for epilepsy-associated psychiat-ric and cognitive disorders.展开更多
Motivated by recent studies of the perturbation of the Magellanic Clouds(MCs)on the Milky Way(MW)and the planned multi-band wide-field deep survey named Chinese Space Station Telescope(CSST),we explore the detection l...Motivated by recent studies of the perturbation of the Magellanic Clouds(MCs)on the Milky Way(MW)and the planned multi-band wide-field deep survey named Chinese Space Station Telescope(CSST),we explore the detection limit of the MW reflex motion due to the MCs infall in different observation precision using an MW-MCs-mass galaxy from MAGPIE simulation to provide a reference for the CSST survey.By involving different errors of distance,proper motion,and radial velocity,we investigate the reflex motion characterized by the velocity shift in each velocity component.We find the strongest shifts in the tangential velocities,which align with the motion direction of the MCs.In the ideal case that distance errors dominate,we find a relative distance error of 10%can allow the reliable detection of velocity shifts in tangential velocities within 100 kpc,and a relative distance error of 30%is the minimum requirement to detect the reliable tangential velocity shifts of about 40kms^(-1)within 50 kpc.Different errors of proper motions in combination with a relative distance error of 10%or 20%show an error of 0.1 mas yr^(-1)in proper motions can guarantee the reliable detection of velocity shifts in V_(l)and V_(b)up to 80-100 kpc and an error of 0.15 mas yr^(-1)is the minimum requirement.In the other ideal case that radial velocity errors dominate,we find a radial velocity error of 20kms^(-1)can present reliable reflex motion in line-of-sight velocity up to 70 kpc,while the detection volume will be reduced to 50 kpc as the radial velocity error increases to 40kms^(-1).When the radial velocity error is larger than 60kms^(-1),the velocity shifts cannot be detected anymore.In addition,we find that reliable detection of reflex motion requires at least 20%of the whole sample.展开更多
In this paper,some typical methods to promote mixing in supersonic combustion are reviewed,and the fluid-dynamic mechanism underpinning the development of the supersonic shear layer in the presence of a streamwise vor...In this paper,some typical methods to promote mixing in supersonic combustion are reviewed,and the fluid-dynamic mechanism underpinning the development of the supersonic shear layer in the presence of a streamwise vortex is analyzed through computational fluid dynamics.It is proven that the streamwise vortex-couple method is an excellent approach to enhance mixing.A specific combustor design is proposed accordingly.展开更多
基金supported by the Research and Development Center of Transport Industry of New Generation of Artificial Intelligence Technology(Grant No.202202H)the National Key R&D Program of China(Grant No.2019YFB1600702)the National Natural Science Foundation of China(Grant Nos.51978600&51808336).
文摘Structural Health Monitoring(SHM)systems have become a crucial tool for the operational management of long tunnels.For immersed tunnels exposed to both traffic loads and the effects of the marine environment,efficiently identifying abnormal conditions from the extensive unannotated SHM data presents a significant challenge.This study proposed amodel-based approach for anomaly detection and conducted validation and comparative analysis of two distinct temporal predictive models using SHM data from a real immersed tunnel.Firstly,a dynamic predictive model-based anomaly detectionmethod is proposed,which utilizes a rolling time window for modeling to achieve dynamic prediction.Leveraging the assumption of temporal data similarity,an interval prediction value deviation was employed to determine the abnormality of the data.Subsequently,dynamic predictive models were constructed based on the Autoregressive Integrated Moving Average(ARIMA)and Long Short-Term Memory(LSTM)models.The hyperparameters of these models were optimized and selected using monitoring data from the immersed tunnel,yielding viable static and dynamic predictive models.Finally,the models were applied within the same segment of SHM data,to validate the effectiveness of the anomaly detection approach based on dynamic predictive modeling.A detailed comparative analysis discusses the discrepancies in temporal anomaly detection between the ARIMA-and LSTM-based models.The results demonstrated that the dynamic predictive modelbased anomaly detection approach was effective for dealing with unannotated SHM data.In a comparison between ARIMA and LSTM,it was found that ARIMA demonstrated higher modeling efficiency,rendering it suitable for short-term predictions.In contrast,the LSTM model exhibited greater capacity to capture long-term performance trends and enhanced early warning capabilities,thereby resulting in superior overall performance.
基金support from the China Manned Space Project Nos. CMS-CSST-2021-B03,CMS-CSST-2021-A08, and________the National Natural Science Foundation of China under grant No. 12233013,12073090+8 种基金the Natural Science Foundation of Guangdong Province under grant No. 2022A1515010732grant support provided by Proyecto Fondecyt Iniciación No. 11220340ANID Concurso de Fomento a la Vinculación Internacional para Instituciones de Investigación Regionales (Modalidad corta duración) Proyecto No. FOVI210020Joint Committee ESO-Government of Chile 2021 (ORP 023/2021)Becas Santander Movilidad Internacional Profesores 2022, Banco Santander Chilesupport from the National Natural Science Foundation of China through grant 21BAA00619the one-hundred-talent project of Sun Yat-sen Universitythe Fundamental Research Funds for the Central UniversitiesSun Yat-sen University (22hytd09)。
文摘During the long term evolution of globular clusters(GCs), some member stars are lost to the field. The recently found nitrogen-rich(N-rich) metal-poor field stars are promising candidates of these GC escapees, since N enhancement is the fingerprint of chemically enhanced populations in GCs. In this work, we discuss the possibility of identifying N-rich metal-poor field stars with the upcoming Chinese Space Station Telescope(CSST). We focus on the main survey camera with NUV, u, g, r, i, z, y filters and slitless spectrograph with a resolution about 200.The combination of UV sensitive equipment and prominent N-related molecular lines in the UV band bodes well for the identification: the color–color diagram of(u-g) versus(g-r) is capable of separating N-rich field stars from normal halo stars, if metallicity can be estimated without using the information on u-band photometry.Besides, the synthetic spectra show that a signal-to-noise ratio of 10 is sufficient to identify N-rich field stars. In the near future, a large sample of N-rich field stars found by CSST, combined with state-of-the-art N-body simulations will be crucial to deciphering GC-Galaxy co-evolution.
基金supported by the National Natural Science Foundation of China (NSFC)(22075201)the National Key Research and Development Program of China (2022YFB4101800)。
文摘The electrochemical CO_(2)reduction reaction to produce multi-carbon(C_(2+)) hydrocarbons or oxygenate compounds is a promising route to obtain a renewable fuel of high energy density.However,producing C_(2+)at high current densities is still a challenge.Herein,we develop a Cu-Zn alloy/Cu-Zn aluminate oxide composite electrocatalytic system for enhanced conversion of CO_(2)to C_(2+)products.The Cu-Zn-Al-Layered Double Hydroxide(LDH) is used as a precursor to decompose into uniform Cu-Zn oxide/Cu-Zn aluminate pre-catalyst.Under electrochemical reduction,Cu-Zn oxide generates Cu-Zn alloy while Cu-Zn aluminate oxide remains unchanged.The alloy and oxide are closely stacked and arranged alternately,and the aluminate oxide induces the strong electron interaction of Cu,Zn and Al,creating a large number of highly active reaction interfaces composed of 0 to+3 valence metal sites.With the help of the interface effect,the optimized Cu_(9)Zn_(1)/Cu_(0.8)Zn_(0.2)Al_(2)O_(4)catalyst achieves a Faradaic efficiency of 88.5% for C_(2+)products at a current density of 400 mA cm^(-2)at-1.15 V versus reversible hydrogen electrode.The in-situ Raman and attenuate total reflectance-infrared absorption spectroscopy(ATR-IRAS) spectra show that the aluminate oxide at the interface significantly enhances the adsorption and activation of CO_(2)and the dissociation of H2O and strengthens the adsorption of CO intermediates,and the alloy promotes the C-C coupling to produce C_(2+)products.This work provides an efficient strategy to construct highly active reaction interfaces for industrial-scale electrochemical CO_(2)RR.
基金the Natural Science Foundation of China (22005250)National Key R D Program of China (2022YFB2502000)FWO (12ZV320N)。
文摘The electrochemical oxygen reduction reaction(ORR) and oxygen evolution reaction(OER) are fundamental processes in a range of energy conversion devices such as fuel cells and metal–air batteries. ORR and OER both have significant activation barriers, which severely limit the overall performance of energy conversion devices that utilize ORR/OER. Meanwhile, ORR is another very important electrochemical reaction involving oxygen that has been widely investigated. ORR occurs in aqueous solutions via two pathways: the direct 4-electron reduction or 2-electron reduction pathways from O_(2) to water(H_2O) or from O_(2) to hydrogen peroxide(H_2O_(2)). Noble metal electrocatalysts are often used to catalyze OER and ORR, despite the fact that noble metal electrocatalysts have certain intrinsic limitations, such as low storage. Thus, it is urgent to develop more active and stable low-cost electrocatalysts, especially for severe environments(e.g., acidic media). Theoretically, an ideal oxygen electrocatalyst should provide adequate binding to oxygen species. Transition metals not belonging to the platinum group metal-based oxides are a low-cost substance that could give a d orbital for oxygen species binding. As a result, transition metal oxides are regarded as a substitute for typical precious metal oxygen electrocatalysts. However, the development of oxide catalysts for oxygen reduction and oxygen evolution reactions still faces significant challenges, e.g., catalytic activity, stability, cost, and reaction mechanism. We discuss the fundamental principles underlying the design of oxide catalysts, including the influence of crystal structure, and electronic structure on their performance. We also discuss the challenges associated with developing oxide catalysts and the potential strategies to overcome these challenges.
文摘电催化二氧化碳还原反应(CO_(2)RR)可以将二氧化碳转化为具有高经济价值的碳氢化合物,被认为是实现碳中和并缓解能源危机的一种有潜力的技术.铜(Cu)作为一种最有应用前景的非贵金属催化剂之一,表现出较高的催化CO_(2)RR转化为多碳产物(C_(2+))的活性.然而,电催化CO_(2)还原成C_(2+)产物涉及一个动力学过程缓慢的C-C偶联反应,这导致C_(2+)产物的选择性较低,电流密度低,阻碍了其在工业电解槽中的实际应用.同时,CO_(2)RR产物的选择性不仅取决于热力学速率决定步骤,还取决于传质控制动力学.CO_(2)RR发生在固-气-液三相反应界面,气-液的平衡扩散可以有效抑制析氢竞争反应,进而提高CO_(2)RR的反应效率.本文设计合成了一种富晶界的Cu纳米带催化剂,并构建了气-液平衡扩散的电极结构,用于高效电催化二氧化碳还原制备乙烯(C_(2)H_(4)).以一种碱式碳酸铜(Cu_(2)CO_(3)(OH)_(2))纳米带为前驱体,在原位电化学还原条件下,前驱体中的Cu2+离子获得电子被还原为金属Cu,而释放的CO_(3)2-和OH-混合阴离子调节金属Cu的生长.生成的Cu纳米带由细小的纳米颗粒堆积而成,并暴露出大量的由Cu(111),Cu(200)和Cu(220)晶面形成的富晶界结构(GBs).同时,在CO_(2)RR测试中发现催化剂层的厚度是影响CO_(2)和电解质传质的关键因素.通过调整催化层厚度,CO_(2)和电解质可以同时到达催化剂表面,参与到CO_(2)RR中,实现了气-液平衡扩散,有效抑制了氢析出副反应.在晶界效应和气-液平衡扩散的协同作用下,优化后的电极在电流密度为700 mA cm^(-2)时,对C_(2)H_(4)和C_(2+).产物的法拉第效率分别高达67.2%和82.1%.此外,C_(2)H_(4)的部分电流密度可高达505 mA cm^(-2),高于大多数文献报道的结果.原位拉曼光谱和衰减全内反射表面增强红外吸收光谱结果表明,丰富的晶;界结构增强了CO_(2)在催化剂表面的活化,显著促进了*CO中间体的形成和吸附,加速了C-C偶联过程形成*OCCO和*OCCOH中间体,提高了C_(2)H_(4)和其他C_(2+)产物的产率.综上,本文设计了一种高活性Cu催化剂和电极结构,为高效电催化CO_(2)还原为C_(2)H_(4)等C_(2+)产物提供参考.
基金supported by Beijing Natural Science Foundation with Grant No.1214028the National Natural Science Foundation of China(NSFC)under grant 12103062+7 种基金the NSFC under grant 12273027the NSFC under Grant Nos.12090040,12090044,and 11833006the NSFC with grant No.11835057support from the NSFC(Grant No.12133002)China West Normal University grant 17YC507.the National Key R&D Program of China No.2019YFA0405501supported by the National Key R&D Program of China No.2019YFA0405502Guo Shou Jing Telescope(the Large sky Area Multi-Object fiber Spectroscopic Telescope LAMOST)is a National Major Scientific Project built by the Chinese Academy of Sciences.Funding for the project has been provided by the National Development and Reform Commission。
文摘A catalog of more than 43,000 M giant stars has been selected by Li et al.from the ninth data release of LAMOST.Using the data-driven method SLAM,we obtain the stellar parameters(T_(eff),logg,[M/H],[α/M])for all the M giant stars with uncertainties of 57 K,0.25 dex,0.16 dex and 0.06 dex at SNR>100,respectively.With those stellar parameters,we constrain the absolute magnitude in the K-band,which brings distance with relative uncertainties around 25%statistically.Radial velocities are also calculated by applying cross correlation on the spectra between 8000 and 8950?with synthetic spectra from ATLAS9,which covers the CaⅡtriplet.Comparison between our radial velocities and those from APOGEE DR17 and Gaia DR3 shows that our radial velocities have a system offset and dispersion around 1 and 4.6 km s^(-1),respectively.With the distances and radial velocities combining with the astrometric data from Gaia DR3,we calculate the full 6D position and velocity information,which are able to be used for further chemo-dynamic studies on the disk and substructures in the halo,especially the Sagittarius Stream.
基金supported by the National Natural Science Foundation of China(Grant Nos.12073070,12173081,12090043,11873016,and 12173013)Yunnan Fundamental Research Project(Grant No.202101AV070001)+5 种基金the Science Research Grants from The China Manned Space Project(Grant Nos.CMS-CSST2021-A08,CMS-CSST-2021-A10,and CMS-CSST-2021-B05)CAS‘Light of West China’ProgramGuoshoujing Telescope(the Large Sky Area MultiObject Fiber Spectroscopic Telescope LAMOST)is a National Major Scientific Project built by the Chinese Academy of Sciences.Funding for the project has been provided by the National Development and Reform Commission of ChinaFunding for the DPAC has been provided by national institutions,in particular the institutions participating in the Gaia Multilateral AgreementThe LAMOST fellowship is supported by Special Funding for Advanced Users,budgeted and administrated by Center for Astronomical Mega-Science,Chinese Academy of Sciences(CAMS)supported by Cultivation Project for LAMOST Scientific Payoff and Research Achievement of CAMS-CAS and Special Research Assistant Program of Chinese Academy of Sciences。
文摘LAMOST-MRS-B is one of the sub-surveys of LAMOST medium-resolution(R~7500)spectroscopic survey.It aims at studying the statistical properties(e.g.,binary fraction,orbital period distribution,mass ratio distribution)of binary stars and exotic stars.We intend to observe about 30000 stars(10 mag≤G<14.5 mag)with at least 10 visits in five years.We first planned to observe 25 plates around the galactic plane in 2018.Then the plates were reduced to 12 in 2019 because of the limitation of observation.At the same time,two new plates located at the high galactic latitude were added to explore binary properties influenced by the different environments.In this survey project,we set the identified exotic and low-metallicity stars with the highest observation priorities.For the rest of the selected stars,we gave the higher priority to the relatively brighter stars in order to obtain high quality spectra as many as possible.Spectra of49129 stars have been obtained in LAMOST-MRS-B field and released in DR8,of which 28828 and 3375 stars have been visited more than twice and ten times with SNR≥10,respectively.Most of the sources are B-,A-,and F-type stars with-0.6<[Fe/H]<0.4 dex.We also obtain 347 identified variable and exotic stars and about 250 stars with[Fe/H]<-1 dex.We measure radial velocities(RVs)by using 892233 spectra of the stars.The uncertainties of RV achieve about 1 km·s^(-1)and 10 km·s^(-1)for 95%of late-and early-type stars,respectively.The datasets presented in this paper are available at http://www.doi.org/10.57760/sciencedb.j00113.00035.
基金the National Natural Science Foundation of China(Grant No.82173803,81872847).
文摘Background:Hippocampal damage caused by status epilepticus(SE)can bring about cognitive decline and emotional disorders,which are common clinical comorbidities in patients with epilepsy.It is therefore imperative to develop a novel therapeutic strat-egy for protecting hippocampal damage after SE.Mitochondrial dysfunction is one of contributing factors in epilepsy.Given the therapeutic benefits of mitochondrial replenishment by exogenous mitochondria,we hypothesized that transplantation of mitochondria would be capable of ameliorating hippocampal damage following SE.Methods:Pilocarpine was used to induced SE in mice.SE-generated cognitive de-cline and emotional disorders were determined using novel object recognition,the tail suspension test,and the open field test.SE-induced hippocampal pathology was assessed by quantifying loss of neurons and activation of microglia and astrocytes.The metabolites underlying mitochondrial transplantation were determined using metabonomics.Results:The results showed that peripheral administration of isolated mitochon-dria could improve cognitive deficits and depressive and anxiety-like behaviors.Exogenous mitochondria blunted the production of reactive oxygen species,pro-liferation of microglia and astrocytes,and loss of neurons in the hippocampus.The metabonomic profiles showed that mitochondrial transplantation altered multiple metabolic pathways such as sphingolipid signaling pathway and carbon metabolism.Among potential affected metabolites,mitochondrial transplantation decreased levels of sphingolipid(d18:1/18:0)and methylmalonic acid,and elevated levels of D-fructose-1,6-bisphosphate.Conclusion:To the best of our knowledge,these findings provide the first direct ex-perimental evidence that artificial mitochondrial transplantation is capable of amelio-rating hippocampal damage following SE.These new findings support mitochondrial transplantation as a promising therapeutic strategy for epilepsy-associated psychiat-ric and cognitive disorders.
基金supported by the National Key Research and Development Program of China No.2019YFA0405504the science research grants from the China Manned Space Project with NO.CMS-CSST-2021-B03+4 种基金the National Natural Science Foundation of China(NSFC)grant Nos.11988101,11890694,12103062,12273027,12273053 and 12173046CAS Project for Young Scientists in Basic Research grant No.YSBR-062support from the K.C.Wong Foundationthe Sichuan Youth Science and Technology Innovation Research Team(grant No.21CXTD0038)the Innovation Team Funds of China West Normal University(grant No.KCXTD2022-6)。
文摘Motivated by recent studies of the perturbation of the Magellanic Clouds(MCs)on the Milky Way(MW)and the planned multi-band wide-field deep survey named Chinese Space Station Telescope(CSST),we explore the detection limit of the MW reflex motion due to the MCs infall in different observation precision using an MW-MCs-mass galaxy from MAGPIE simulation to provide a reference for the CSST survey.By involving different errors of distance,proper motion,and radial velocity,we investigate the reflex motion characterized by the velocity shift in each velocity component.We find the strongest shifts in the tangential velocities,which align with the motion direction of the MCs.In the ideal case that distance errors dominate,we find a relative distance error of 10%can allow the reliable detection of velocity shifts in tangential velocities within 100 kpc,and a relative distance error of 30%is the minimum requirement to detect the reliable tangential velocity shifts of about 40kms^(-1)within 50 kpc.Different errors of proper motions in combination with a relative distance error of 10%or 20%show an error of 0.1 mas yr^(-1)in proper motions can guarantee the reliable detection of velocity shifts in V_(l)and V_(b)up to 80-100 kpc and an error of 0.15 mas yr^(-1)is the minimum requirement.In the other ideal case that radial velocity errors dominate,we find a radial velocity error of 20kms^(-1)can present reliable reflex motion in line-of-sight velocity up to 70 kpc,while the detection volume will be reduced to 50 kpc as the radial velocity error increases to 40kms^(-1).When the radial velocity error is larger than 60kms^(-1),the velocity shifts cannot be detected anymore.In addition,we find that reliable detection of reflex motion requires at least 20%of the whole sample.
基金supported by the National Natural Science Foundation of China(No.12002193)the Shandong Provincial Natural Science Foundation,China(No.ZR2019QA018).
文摘In this paper,some typical methods to promote mixing in supersonic combustion are reviewed,and the fluid-dynamic mechanism underpinning the development of the supersonic shear layer in the presence of a streamwise vortex is analyzed through computational fluid dynamics.It is proven that the streamwise vortex-couple method is an excellent approach to enhance mixing.A specific combustor design is proposed accordingly.
