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二维Mo_(2)TiC_(2)MXene材料对调节MgH_(2)储氢性能的催化作用
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作者 章浩宇 田贵宾 +3 位作者 吴富英 姚振东 郑家广 张刘挺 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2023年第11期3465-3475,共11页
通过刻蚀Mo_(2)TiAlC_(2)合成二维Mo_(2)TiC_(2) MXene材料,并将其与MgH_(2)复合以调节MgH_(2)的储氢性能。Mo_(2)TiC_(2)的掺杂使MgH_(2)的初始放氢温度从330℃显著降低至187℃。等温放氢性能测试表明,MgH_(2)+9%Mo_(2)TiC_(2)(质量分... 通过刻蚀Mo_(2)TiAlC_(2)合成二维Mo_(2)TiC_(2) MXene材料,并将其与MgH_(2)复合以调节MgH_(2)的储氢性能。Mo_(2)TiC_(2)的掺杂使MgH_(2)的初始放氢温度从330℃显著降低至187℃。等温放氢性能测试表明,MgH_(2)+9%Mo_(2)TiC_(2)(质量分数)复合材料在300℃时4min内可快速释放6.4%(质量分数)的氢气。对于吸氢反应,完全脱氢的MgH_(2)+9%Mo_(2)TiC_(2)在175℃时5 min内吸收了6.5%(质量分数)的氢气。经过计算,MgH_(2)+9%Mo_(2)TiC_(2)的放氢反应活化能为(135.6±1.9)kJ/mol,吸氢反应活化能为(46.1±0.2)kJ/mol。20次循环后,MgH_(2)+9%Mo_(2)TiC_(2)复合材料的储氢容量损失1.0%(质量分数)。显微组织分析表明,Mo_(2)TiC_(2)中的Mo使MXene的稳定性增强、循环过程中活性Ti的生成量减少,从而导致催化剂的催化效果不如Ti_(3)C_(2)。 展开更多
关键词 储氢性能 氢化镁 Mo_(2)TiC_(2)MXene 催化机理
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Mn纳米颗粒增强MgH_(2)的吸放氢动力学 被引量:2
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作者 陈艳 章浩宇 +4 位作者 吴富英 孙泽 郑家广 张刘挺 陈立新 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第11期3469-3477,共9页
合成锰纳米颗粒并掺杂到MgH_(2)中以改善其吸放氢性能。与MgH_(2)相比,含10%(质量分数)锰纳米颗粒的MgH_(2)其初始放氢温度下降到175℃。在300、275和250℃下,该复合体系能在5、10和25 min之内分别释放出6.7%、6.5%和6.1%(质量分数)的... 合成锰纳米颗粒并掺杂到MgH_(2)中以改善其吸放氢性能。与MgH_(2)相比,含10%(质量分数)锰纳米颗粒的MgH_(2)其初始放氢温度下降到175℃。在300、275和250℃下,该复合体系能在5、10和25 min之内分别释放出6.7%、6.5%和6.1%(质量分数)的氢气。此外,该复合体系在室温下即可吸氢,并能在50℃、30 min之内吸收2.0%(质量分数)的氢气。在掺杂10%(质量分数)锰纳米颗粒后,MgH_(2)吸氢反应的活化能从(72.5±2.7) kJ/mol降低到(18.8±0.2) kJ/mol,该复合体系表现出优异的循环性能,在20次循环后保持着92%的初始容量。 展开更多
关键词 储氢材料 氢化镁 锰纳米颗粒 催化机理 可逆性
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Effect of Xingnao-Jianshen granules in treating AIS patients:study protocol for a non-randomized controlled intervention trial
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作者 Chun-Yu Ma Miao Liu +3 位作者 hao-yu zhang Min Yang Xin-Na Wang De-Xi Zhao 《Clinical Research Communications》 2022年第4期17-22,共6页
Objective:Acute ischemic stroke(AIS)is characterized by high morbidity and high mortality.In recent years,complementary and alternative medicine has gradually been widely accepted and applied.At present,traditional Ch... Objective:Acute ischemic stroke(AIS)is characterized by high morbidity and high mortality.In recent years,complementary and alternative medicine has gradually been widely accepted and applied.At present,traditional Chinese medicine therapy and standard treatments are used for the treatment of AIS.Xingnao-Jianshen prescriptions(XNJS)is an effective prescription for the clinical treatment of AIS,but there is a lack of large-scale clinical evidence to confirm its clinical efficacy.Therefore,our team designed this protocol to evaluate the initial therapeutic effect of XNJS.Methods:The protocol for a non-randomized controlled trial is designed in which 72 eligible patients will be allocated to one of two groups.The control group(n=36)will receive standard treatment for AIS,the test group(n=36)will receive XNJS and standard treatment.Patients will be recruited after stroke onset and will receive the intervention continuously over 10±1 days,with a follow-up period of 90 days.The primary outcome will be the change in the NIHSS,BI,mRS scores.All outcome measures will be assessed at inception,after the intervention(10±1 days),and at the follow-up(90 days).The results will be disseminated to the public through peerreviewed journals and academic conferences.Discussion:The study will provide evidence of the preliminary effects. 展开更多
关键词 Xingnao-Jianshen prescriptions AIS non-randomized controlled intervention trials study protocol
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Modeling and Analysis of Interstand Tension Control in 6-high Tandem Cold Rolling Mill 被引量:3
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作者 Xin zhang Shu-zong CHEN +3 位作者 hao-yu zhang Xi-wen zhang Dian-hua zhang Jie SUN 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2014年第9期830-836,共7页
The interstand tension control is one of the most important ways to meet tight tolerances for strip product quality during tandem cold rolling process. Using coordinate analysis and parabolic approximation for the mas... The interstand tension control is one of the most important ways to meet tight tolerances for strip product quality during tandem cold rolling process. Using coordinate analysis and parabolic approximation for the mass flow balance principle, the strip velocities eliminating the use of forward slips and backward slips were calculated. In order to reduce the effect of roll eccentricity on the tension measurement, a filter based on bilinear transformation was de- signed. Applying a first-order Taylor series approximation, the transfer function matrix model of interstand tension stress was derived. The actual measurements on-site and the final calculation results showed that the established model had high calculation accuracy and was beneficial for interstand tension control of random cold rolling process. 展开更多
关键词 tension control tandem cold rolling mill bilinear transformation transfer function matrix model
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Hydrogenation of Alkenes Catalyzed by Rare-Earth Metal Phosphinophosphinidene Complexes:1,2-Addition/Elimination Versusσ-Bond Metathesis Mechanism
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作者 Bin Feng hao-yu zhang +3 位作者 Hongling Qin Qian Peng Xuebing Leng Yaofeng Chen 《CCS Chemistry》 CAS 2022年第10期3309-3318,共10页
Rare-earth metal complexes have been used as catalysts for many types of reactions.However,the mechanistic studies showed that basically,these various reactions proceeded withσ-bond metathesis of RE–E bond(RE:rare-e... Rare-earth metal complexes have been used as catalysts for many types of reactions.However,the mechanistic studies showed that basically,these various reactions proceeded withσ-bond metathesis of RE–E bond(RE:rare-earth metals;E:main group elements)or RE ions acting as Lewis acid centers to activate the polar functional groups of the substrates.In this article,a lutetium phosphinophosphinidene complex,with Lu=P double-bond character,was synthesized and structurally characterized. 展开更多
关键词 rare-earthmetal PHOSPHINIDENE ALKENE HYDROGENATION reaction mechanism density functional theory calculations
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