Electromagnetic interference shielding and thermal management by wearable devices show great po-tential in emerging digital healthcare.Conventional metal films implementing the functions must sacri-fice either flexibi...Electromagnetic interference shielding and thermal management by wearable devices show great po-tential in emerging digital healthcare.Conventional metal films implementing the functions must sacri-fice either flexibility or permeability,which is far from optimal in practical applications.In this work,an ultra-thin(15μm),flexible,and porous Cu/PLLA fibrous membrane is developed by depositing cop-per particles on the polymer substrate.With novel acetone&heat treatment procedure,the mem-brane is considerably stronger while maintaining the porous fibre structure.Its fantastic breathabil-ity and super high electrical conductivity(9471.8130 S/cm)enable the composites to have fast electri-cal heating characteristics and excellent thermal conductivity for effective thermal management.Mean-while,the porous polymer substrate structure greatly enhances the diffusion of conductive substances and increases the electromagnetic interference shielding effectiveness of the membranes(7797.98 dB cm^(2)/g at the H band and 8072.73 dB cm^(2)/g at the Ku band respectively).The composites present high flexibility,breathability,and strength with the functions of thermal management and electromag-netic shielding,showing great potential for future portable electronic devices and wearable integrated garments.展开更多
基金We acknowledge the support of the Electron Microscopy Centre at The University of Manchester.
文摘Electromagnetic interference shielding and thermal management by wearable devices show great po-tential in emerging digital healthcare.Conventional metal films implementing the functions must sacri-fice either flexibility or permeability,which is far from optimal in practical applications.In this work,an ultra-thin(15μm),flexible,and porous Cu/PLLA fibrous membrane is developed by depositing cop-per particles on the polymer substrate.With novel acetone&heat treatment procedure,the mem-brane is considerably stronger while maintaining the porous fibre structure.Its fantastic breathabil-ity and super high electrical conductivity(9471.8130 S/cm)enable the composites to have fast electri-cal heating characteristics and excellent thermal conductivity for effective thermal management.Mean-while,the porous polymer substrate structure greatly enhances the diffusion of conductive substances and increases the electromagnetic interference shielding effectiveness of the membranes(7797.98 dB cm^(2)/g at the H band and 8072.73 dB cm^(2)/g at the Ku band respectively).The composites present high flexibility,breathability,and strength with the functions of thermal management and electromag-netic shielding,showing great potential for future portable electronic devices and wearable integrated garments.
