Cerium Methacrylate Assisted Preparation of Highly Thermally Conductive and Anticorrosive Multifunctional Coatings for Heat Conduction Metals Protection

Preparing polymeric coatings with well corrosion resistance and high thermal conductivity(TC)to prolong operational life and ensure service reliability of heat conductive metallic materials has long been a substantive and urgent need while a difficult task.Here we report a multifunctional epoxy composite coating(F-CB/CEP)by synthesizing cerium methacrylate and ingeniously using it as a novel curing agent with corrosion inhibit for epoxy resin and modifier for boron nitride through"cation-π"interaction.The prepared F-CB/CEP coating presents a high TC of 4.29 W m^(−1)K^(−1),which is much higher than other reported anti-corrosion polymer coatings and thereby endowing metal materials coated by this coating with outstanding thermal management performance compared with those coated by pure epoxy coating.Meanwhile,the low-frequency impedance remains at 5.1×10^(11)Ωcm^(2)even after 181 days of immersion in 3.5 wt%NaCl solution.Besides,the coating also exhibits well hydrophobicity,self-cleaning properties,temperature resistance and adhesion.This work provides valuable insights for the preparation of high-performance composite coatings with potential to be used as advanced multifunctional thermal management materials,especially for heat conduction metals protection.

Construction of 3D interconnected boron nitride/carbon nanofiber hybrid network within polymer composite for thermal conductivity improvement

With the increasing power density and integration of electronic devices,polymeric composites with high thermal conductivity(TC)are in urgent demand for solving heat accumulation issues.However,the direct introduction of inorganic fillers into a polymer matrix at low filler content usually leads to low TC enhancement.In this work,an interconnected three-dimensional(3D)polysulfone/hexagonal boron nitride-carbon nanofiber(PSF/BN-CNF)skeleton was prepared via the salt templated method to address this issue.After embedding into the epoxy(EP),the EP/PSF/BN-CNF composite presents a high TC of 2.18 W m^(−1) K^(−1) at a low filler loading of 28.61 wt%,corresponding to a TC enhancement of 990%compared to the neat epoxy.The enhanced TC is mainly attributed to the fabricated 3D interconnected structure and the efficient synergistic effect of BN and CNF.In addition,the TC of the epoxy composites can be further increased to 2.85 W m^(−1) K^(−1) at the same filler loading through a post-heat treatment of the PSF/BN-CNF skeletons.After carbonization at 1500°C,the adhesive PSF was converted into carbonaceous layers,which could serve as a thermally conductive glue to connect the filler network,further decreasing the interfacial thermal resistance and promoting phonon transport.Besides,the good heat dissipation performance of the EP/C/BN-CNF composites was directly confirmed by thermal infrared imaging,indicating a bright and broad application in the thermal management of modern electronics and energy fields.