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具有甲基丙烯酸甲酯-45S5生物活性玻璃复合涂层的镁在模拟体液中的生物降解行为
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作者 Zanko ROUEIN hassan jafari +2 位作者 Fatemehsadat PISHBIN Rahim MOHAMMADI Abdolreza SIMCHI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第7期2216-2228,共13页
研究甲基丙烯酸甲酯(PMMA)和甲基丙烯酸甲酯-生物活性玻璃(BG)复合材料对镁生物降解行为的影响。通过电泳沉积和浸涂技术,利用含有不同比例两种涂层材料的悬浮液制备复合涂层。用SEM、EDS、FTIR和水接触角测量对涂层进行表征。通过线偏... 研究甲基丙烯酸甲酯(PMMA)和甲基丙烯酸甲酯-生物活性玻璃(BG)复合材料对镁生物降解行为的影响。通过电泳沉积和浸涂技术,利用含有不同比例两种涂层材料的悬浮液制备复合涂层。用SEM、EDS、FTIR和水接触角测量对涂层进行表征。通过线偏振、阻抗谱和模拟体液浸泡实验研究镁的生物降解行为。电镜结果表明,复合涂层致密且均匀。水接触角测量显示,与没有复合涂层的镁相比,具有复合涂层的镁接触角增加44°。复合涂层在模拟体液中浸泡336 h后其表面被类骨羟基磷灰石层覆盖,表明涂层具有良好的体外生物活性。电化学测试结果证实,与未涂覆复合材料涂层的镁相比,涂覆了由45 g/LPMMA和3.5 g/L45S5 BG组成的悬浮液所制复合涂层的镁,其生物降解率显著降低了96.9%。因此,具有复合涂层的镁可作为一种有前景的生物降解植入材料。 展开更多
关键词 镁合金 聚甲基丙烯酸甲酯 生物活性玻璃 复合涂层 电泳沉积 生物降解
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挤压参数对生物植入应用镁合金降解性能的影响:综述
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作者 Mahdi SHIRI hassan jafari Raman SINGH 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第9期2787-2813,共27页
作为新一代临时生物材料,镁合金具有良好的生物相容性和生物可降解性,也有助于损伤骨组织的修复。但是,其在人体体液中不具备所要求的耐腐蚀性能。挤压等热机械加工对镁合金的力学性能和生物腐蚀行为均有影响。本文综述挤压参数(挤压比... 作为新一代临时生物材料,镁合金具有良好的生物相容性和生物可降解性,也有助于损伤骨组织的修复。但是,其在人体体液中不具备所要求的耐腐蚀性能。挤压等热机械加工对镁合金的力学性能和生物腐蚀行为均有影响。本文综述挤压参数(挤压比和温度)对镁合金生物腐蚀性能的影响。它们的影响主要归因于挤压合金显微组织的改变,包括最终的晶粒尺寸和均匀度、织构以及第二相的尺寸、分布和体积分数。挤压过程中的动态再结晶和晶粒细化使组织更均匀,并导致基面织构的形成,从而提高镁合金的强度和耐腐蚀性能。挤压温度和挤压比是影响降解的重要因素。随着挤压比的增加和/或挤压温度的降低,镁合金的晶粒尺寸减小,与挤压方向平行的样品两侧的基面织构增强,析出相体积分数降低,晶粒尺寸减小,这些都有助于提高镁合金植入物的耐腐蚀性能。 展开更多
关键词 镁合金 挤压温度 挤压比 生物降解 显微组织
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涂层厚度对消失模铸Al-Si-Cu合金铸件的影响(英文) 被引量:5
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作者 Majid KARIMIAN Ali OURDJINI +1 位作者 Mohd HASBULLAH IDRIS hassan jafari 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第9期2092-2097,共6页
对Al-Si-Cu合金进行消失模铸造,研究涂层厚度对Al-Si-Cu合金铸件缺陷、孔隙率和共晶硅间距的影响。结果表明,提高涂层浆料黏度和延长浸渍时间对铸件的完整性和显微组织有影响。薄的涂层有利于模腔充填性能的改善、显微组织的细化和低孔... 对Al-Si-Cu合金进行消失模铸造,研究涂层厚度对Al-Si-Cu合金铸件缺陷、孔隙率和共晶硅间距的影响。结果表明,提高涂层浆料黏度和延长浸渍时间对铸件的完整性和显微组织有影响。薄的涂层有利于模腔充填性能的改善、显微组织的细化和低孔隙度高质量铸件的获得。 展开更多
关键词 铝合金 消失模铸造 涂层厚度 浆料黏度 浸渍时间 孔隙度
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影响消失模铸造Al-Si-Cu合金薄壁铸件质量的显著性工艺参数(英文) 被引量:4
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作者 hassan jafari Mohd Hsbullah IDRIS Amirreza SHAYGANPOUR 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第10期2843-2851,共9页
通过控制消失模铸造工艺参数可以制备出无缺陷的形状复杂的铸件产品。对Al-Si-Cu合金消失模铸造进行研究,考察浇注温度、涂料黏度、振动时间、型砂粒径以及它们之间的交互作用对铸件表面质量、孔隙率和共晶硅间距的影响。采用两水平全... 通过控制消失模铸造工艺参数可以制备出无缺陷的形状复杂的铸件产品。对Al-Si-Cu合金消失模铸造进行研究,考察浇注温度、涂料黏度、振动时间、型砂粒径以及它们之间的交互作用对铸件表面质量、孔隙率和共晶硅间距的影响。采用两水平全因子实验设计方法考察影响铸件性能的显著性影响工艺参数。结果表明,浇注温度和振动时间对铸件共晶硅间距和孔隙率的影响最明显。在细型砂模和较高的浇注温度下,铸件的表面质量几乎保持稳定不变,而在粗型砂模下铸件的表面质量较低。涂料黏度对铸件性能没有显著影响。 展开更多
关键词 AL-SI-CU合金 消失模铸造 全因子实验设计 表面处理 孔隙率 硅间距
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固溶处理对可生物降解Mg-6Zn合金腐蚀性能的影响(英文) 被引量:3
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作者 Seyed Morteza Ghaffari SHAHRI Mohd Hasbullah IDRIS +2 位作者 hassan jafari Babak GHOLAMPOUR Mahtab ASSADIAN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第5期1490-1499,共10页
对可生物降解二元Mg-6Zn合金进行固溶处理,来评价获得的显微组织变化对合金降解速率的影响及其相关机理。在350°C条件下固溶处理6-48 h。采用光学显微镜、扫描电镜、能量色散X射线光谱仪和X射线衍射仪分析铸态和固溶处理后试样。在... 对可生物降解二元Mg-6Zn合金进行固溶处理,来评价获得的显微组织变化对合金降解速率的影响及其相关机理。在350°C条件下固溶处理6-48 h。采用光学显微镜、扫描电镜、能量色散X射线光谱仪和X射线衍射仪分析铸态和固溶处理后试样。在37°C的模拟体液中进行浸泡和电化学测试,评价其抗腐蚀性。为保证腐蚀测试的结果,对p H值进行测试。结果发现,大于24 h的固溶处理,金属间化合物相溶解于基体中,并产生了近单晶相组织。金属间化合物相的减少导致阴极区/阳极区比减小且腐蚀率降低。电化学和失重测试结果表明,延长固溶处理时间可提高合金的抗腐蚀性。经350°C固溶处理24 h后,铸态合金的抗腐蚀性提高了60%以上。另外,逐渐减少的金属间化合物相和伴随的低p H值上升,降低了腐蚀速率。对于Mg-Zn合金作为生物可降解移植材料的应用,固溶处理是一种可以提高腐蚀性的工艺。 展开更多
关键词 镁合金 固溶处理 生物降解 浸泡 极化 矫形外科植入
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Assessment of dairy products consumed on the Arakmarket as determined by heavy metal residues 被引量:2
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作者 Mohammad Rezaei Hajar Akbari Dastjerdi +6 位作者 hassan jafari Ali Farahi Arman Shahabi Hossein Javdani Hossein Teimoory Mohammad Yahyaei Ali Akbar Malekirad 《Health》 2014年第5期323-327,共5页
Dairy products are nutritious drink and can play a significant part in a healthy diet. The safety of dairy products decreases with increasing concentration of toxic compounds and environmental pollutants (especially h... Dairy products are nutritious drink and can play a significant part in a healthy diet. The safety of dairy products decreases with increasing concentration of toxic compounds and environmental pollutants (especially heavy metals). In the present study, the contamination of Al, Sn, As, Cd, Hg and Pb in dairy products (pasteurized milk, yogurt, yogurt drink, cheese) consumed in Arak, Iran, 2013 was evaluated using inductively coupled plasma mass spectrometry (ICP-SFMS) method. To meet the aim, 60 samples of 5 different brands, consisting of pasteurized milk, yogurt, yogurt drink, cheese (n = 15) were selected and analyzed for heavy metals content. 100% of the samples were positive regarding the total average and range concentration of Al, Sn, As, Cd, Hg and Pb in dairy products was 168.25 ± 92.2 (30.6 - 356.5), 5.9 ± 4 (1.1 - 16), 3.2 ± 1.95 (0.4 - 8.1), 4.55 ± 2.6 (0.6 - 10.6), 23.15 ± 10.4 (6.8 - 50.2) and 15.4 ± 8.53 (3.1 - 40.2) μg/kg, respectively. 28.3% (17 of 60 samples) of dairy products samples had lead (Pb) greater than EU limit and national Iranian standard (20 μg/kg). Statistical analysis indicated except about As in pasteurized milk and cheese there was no significant difference between products in terms of heavy metals content. 展开更多
关键词 HEAVY METALS MILK CHEESE YOGURT FOOD Safety ICP
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Effect of extrusion process on microstructure and mechanical and corrosion properties of biodegradable Mg-5Zn-1.5Y magnesium alloy 被引量:1
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作者 hassan jafari Amir Houshang Mojiri Tehrani +1 位作者 Mojiri Tehrani Mahsa Heydari 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2022年第3期490-502,共13页
The effect of extrusion temperature and ratio on the microstructure, hardness, compression, and corrosion behavior of Mg-5Zn-1.5Y alloy were analyzed in this study. The microstructural observations revealed that the c... The effect of extrusion temperature and ratio on the microstructure, hardness, compression, and corrosion behavior of Mg-5Zn-1.5Y alloy were analyzed in this study. The microstructural observations revealed that the cast alloy consists of α-Mg grains, and Mg3Zn6Y and Mg3Zn3Y2 intermetallic compounds, mostly located on the α-Mg grain boundaries. Extruded alloy at higher temperatures showed coarser grain microstructures, whereas those extruded at higher ratios contained finer ones, although more dynamic recrystalized grains with lower intermetallics were measured at both conditions. Combined conditions of the lower temperature (340°C) and higher ratio (1:11.5) provided higher compressive strengths. However, no significant hardness improvement was achieved. The extrusion process could decrease the corrosion rate of the cast alloy in simulated body fluid for over 80% due to primarily the refined microstructure. The extrusion temperature showed a more pronounced effect on corrosion resistance compared to the extrusion ratio, and the higher the extrusion temperature, the higher the corrosion resistance. 展开更多
关键词 magnesium alloy BIODEGRADABLE EXTRUSION MICROSTRUCTURE mechanical properties CORROSION
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超临界二氧化碳热动力技术应用于地热发电的研究及展望 被引量:3
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作者 周康 赵国斌 +1 位作者 hassan jafari 吴俊翔 《上海节能》 2018年第2期109-113,共5页
本文论述了将美国宇航局(NASA)开发的温控及供能系统与汽轮机及喷射泵组合,形成喷气式发动机的热动力系统,应用于超临界CO_2地热流体发电。该系统有别于现有的高温CO_2跨临界布雷顿循环或已经成熟运用于地热发电的有机朗肯循环,显著提... 本文论述了将美国宇航局(NASA)开发的温控及供能系统与汽轮机及喷射泵组合,形成喷气式发动机的热动力系统,应用于超临界CO_2地热流体发电。该系统有别于现有的高温CO_2跨临界布雷顿循环或已经成熟运用于地热发电的有机朗肯循环,显著提高了热动力转化效率,降低了系统对热源品位的要求。该项技术关键是通过轴流式汽轮机与凯瑟琳轮结合,利用超临界CO_2传热流体与另一种有机工质完成热动力转化。其热动力设计流程旨在找到一种能够利用温度更低、深度更浅的热储进行高效发电的一般性方法,从而降低地热钻井的深度和成井难度,降低地热发电单位成本,提升地热发电的可行性与设计弹性,同时节约地热电站冷却水的用量,合理利用地热资源,兼顾地下水的保护和地表生态环境的修复与改善。并最终在杭州湾大开发等区域规划实现并普及EGS地热发电及地热能利用。 展开更多
关键词 超临界CO2 动力技术 地热发电
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Influence of Gating System,Sand Grain Size,and Mould Coating on Microstructure and Mechanical Properties of Thin-Wall Ductile Iron 被引量:2
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作者 hassan jafari Mohd Hasbullah Idris +2 位作者 Ali Ourdjini Majid Karimian Gholamhassan Payganeh 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2010年第12期38-45,共8页
Two gating systems namely stepped and tapered runners were used to cast strip samples with different thicknesses by CO2/silicate process using sand grain sizes of AFS 151 and 171. To assess the effect of mould coating... Two gating systems namely stepped and tapered runners were used to cast strip samples with different thicknesses by CO2/silicate process using sand grain sizes of AFS 151 and 171. To assess the effect of mould coating on the properties of thin wall ductile iron, half of the moulds were coated whilst the rest were not coated. Molten metal with the carbon equivalent of 4.29% was prepared and poured at 1 450 ℃. Microstructure of the specimens was analyzed by optical and scanning electron microscopes. Count, area fraction, roundness and diameter of the graphite nodules of the samples were measured by image analyzer. Brinell hardness and tensile tests of all the samples were also conducted. The results show that by using stepped runner gating system with uncoated and coarse sand mould, roundness and count of the graphite nodules decrease whereas diameter and area fraction increase. Although fine sand and coated mould cause longer distance of molten metal travel, hardness and strength of the samples decrease. 展开更多
关键词 thin-wail ductile iron gating system sand grain size mould coating mechanical property mierostructure
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Effect of Multi-Step Tempering on Retained Austenite and Mechanical Properties of Low Alloy Steel 被引量:2
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作者 Hamid Reza Bakhsheshi-Rad Ahmad Monshi +3 位作者 Hossain Monajatizadeh Mohd Hasbullah Idris Mohammed Rafiq Abdul Kadir hassan jafari 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2011年第12期49-56,共8页
The effect of multi-step tempering on retained austenite content and mechanical properties of low alloy steel used in the forged cold back-up roll was investigated.Microstructural evolutions were characterized by opti... The effect of multi-step tempering on retained austenite content and mechanical properties of low alloy steel used in the forged cold back-up roll was investigated.Microstructural evolutions were characterized by optical microscope,X-ray diffraction,scanning electron microscope and Feritscope,while the mechanical properties were determined by hardness and tensile tests.The results revealed that the content of retained austenite decreased by about 2% after multi-step tempering.However,the content of retained austenite increased from 3.6% to 5.1% by increasing multi-step tempering temperature.The hardness and tensile strength increased as the austenitization temperature changed from 800 to 920 ℃,while above 920 ℃,hardness and tensile strength decreased.In addition,the maximum values of hardness,ultimate and yield strength were obtained via triple tempering at 520 ℃,while beyond 520 ℃,the hardness,ultimate and yield strength decreased sharply. 展开更多
关键词 cold back-up roll retained austenite mechanical property austenite grain size
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