Both macroscopic composition and microstructure should be considered for reasonable microwave ab-sorbent designing.In this study,Co_(3)O_(4)@reduced graphene oxide(rGO)/Celery stalks derived carbon(CDC)was prepared by...Both macroscopic composition and microstructure should be considered for reasonable microwave ab-sorbent designing.In this study,Co_(3)O_(4)@reduced graphene oxide(rGO)/Celery stalks derived carbon(CDC)was prepared by loading Co_(3)O_(4) particles into rGO and biomass-derived carbon mixture through oxidation precipitation.By changing the mass ratio of rGO to CDC,the dielectric and impedance matching proper-ties of the composites can be easily regulated.The RL min value of Co_(3)O_(4)@rGO/CDC_(13) composite(weight ratio for rGO:CDC is 1:3)reaches-84.3 dB with a thickness of 4.6 mm,and the widest effective band-width can be obtained at 4.5 GHz with a matching thickness of 2.8 mm.The Co_(3)O_(4)@rGO/CDC_(13) compos-ite with multiple components(Co_(3)O_(4),CDC,rGO)and 3D net structure produces magnetic/dielectric loss combinations,interfacial polarization,and multiple reflections and scattering,and the CDC with half tube and half sheet structure is conducive to the optimization of impedance matching.The strategy of co-regulating dielectric properties of materials with double carbon provides a novel pathway for the prepa-ration of lightweight,low-cost,and high-performance absorbers.展开更多
基金supported by the National Natural Science Foundation of China(No.52101274)the Natural Science Foundation of Shandong Province(No.ZR2020QE011)the Youth Top Talent Foundation of Yantai University(No.2219008).
文摘Both macroscopic composition and microstructure should be considered for reasonable microwave ab-sorbent designing.In this study,Co_(3)O_(4)@reduced graphene oxide(rGO)/Celery stalks derived carbon(CDC)was prepared by loading Co_(3)O_(4) particles into rGO and biomass-derived carbon mixture through oxidation precipitation.By changing the mass ratio of rGO to CDC,the dielectric and impedance matching proper-ties of the composites can be easily regulated.The RL min value of Co_(3)O_(4)@rGO/CDC_(13) composite(weight ratio for rGO:CDC is 1:3)reaches-84.3 dB with a thickness of 4.6 mm,and the widest effective band-width can be obtained at 4.5 GHz with a matching thickness of 2.8 mm.The Co_(3)O_(4)@rGO/CDC_(13) compos-ite with multiple components(Co_(3)O_(4),CDC,rGO)and 3D net structure produces magnetic/dielectric loss combinations,interfacial polarization,and multiple reflections and scattering,and the CDC with half tube and half sheet structure is conducive to the optimization of impedance matching.The strategy of co-regulating dielectric properties of materials with double carbon provides a novel pathway for the prepa-ration of lightweight,low-cost,and high-performance absorbers.
