A novel ammonia synthesis catalyst, potassium-promoted ruthenium supported on carbon nanotubes, was developed. It was found that the Ru-K/carbon nanotubes catalyst had higher activity for ammonia synthesis (20.85 ml N...A novel ammonia synthesis catalyst, potassium-promoted ruthenium supported on carbon nanotubes, was developed. It was found that the Ru-K/carbon nanotubes catalyst had higher activity for ammonia synthesis (20.85 ml NH3/h/g-cat) than the Ru-K/fullerenes ( 13.3 ml NH3/h/g-cat) at atmospheric pressure and 623 K. The catalyst had activity even at 473 K, and had the highest activity( 23.46 ml NH3/h/g-cat) at 643 K. It was suggested that the multi-walled structure favored the electron transfer, the hydrogen-storage and the hydrogen-spill which were favorable to ammonia synthesis.展开更多
A series of olefin hydroformylations over supported aqueous-phase rhodium catalyst with the substitUtion of CO/D2 for CO/H2 were cAned out to study the isotope effects of deuterium. The rate of aldehyde formation in C...A series of olefin hydroformylations over supported aqueous-phase rhodium catalyst with the substitUtion of CO/D2 for CO/H2 were cAned out to study the isotope effects of deuterium. The rate of aldehyde formation in CO/D2 was about 1.3 times faster than that in COns2, indicating that the aldehyde formation shows noticeable inverse deuterium isotope effect over SAP catalyst. The results of in-situIR stUdy of ethylene hydroformylation suggest that the reaction rate of acylhydrogenolysis forming aldehyde is the slowest one. It may be inferred from these results that the rate-determining step involved\in aldehyde formation is very probably astep ofhydrogenation.展开更多
Raman peaks at 1951 and 2165 cm^(-1) can be confirmed further by H_2/D_2 isotope exchange as H-adspecies on the doubly promoted iron catalyst for ammonia synthesis and are probably ascribed to two terminally adsorbed ...Raman peaks at 1951 and 2165 cm^(-1) can be confirmed further by H_2/D_2 isotope exchange as H-adspecies on the doubly promoted iron catalyst for ammonia synthesis and are probably ascribed to two terminally adsorbed H-species.展开更多
基金NSF of China !(#29773037 )NSF of Fujian province!(#E9910001 )opening project grant from the State Key Lab of phys. Chem.
文摘A novel ammonia synthesis catalyst, potassium-promoted ruthenium supported on carbon nanotubes, was developed. It was found that the Ru-K/carbon nanotubes catalyst had higher activity for ammonia synthesis (20.85 ml NH3/h/g-cat) than the Ru-K/fullerenes ( 13.3 ml NH3/h/g-cat) at atmospheric pressure and 623 K. The catalyst had activity even at 473 K, and had the highest activity( 23.46 ml NH3/h/g-cat) at 643 K. It was suggested that the multi-walled structure favored the electron transfer, the hydrogen-storage and the hydrogen-spill which were favorable to ammonia synthesis.
文摘A series of olefin hydroformylations over supported aqueous-phase rhodium catalyst with the substitUtion of CO/D2 for CO/H2 were cAned out to study the isotope effects of deuterium. The rate of aldehyde formation in CO/D2 was about 1.3 times faster than that in COns2, indicating that the aldehyde formation shows noticeable inverse deuterium isotope effect over SAP catalyst. The results of in-situIR stUdy of ethylene hydroformylation suggest that the reaction rate of acylhydrogenolysis forming aldehyde is the slowest one. It may be inferred from these results that the rate-determining step involved\in aldehyde formation is very probably astep ofhydrogenation.
基金Supported from the State Key Laboratory for Physical Chemistry of the Solid Surface of Xiamen University.
文摘Raman peaks at 1951 and 2165 cm^(-1) can be confirmed further by H_2/D_2 isotope exchange as H-adspecies on the doubly promoted iron catalyst for ammonia synthesis and are probably ascribed to two terminally adsorbed H-species.
