Preparation and property of a novel soluble electron transport POSS-based hybrid material

一个新奇基于 POSS 的器官 / 无机的混血儿 covalently 在分子的水平属于， 2-(4-(allyloxy ) 苯基)-5-(4-(octyloxy)phenyl)-1,3,4-oxadiazole-POSS (6 )( 作为 oxadiazole-POSS 缩短了) 被磅(dcp ) 综合催化剂。混血儿在象 CHCl3，甲苯， C2H4Cl2，和 THF 那样的普通器官的溶剂是可溶的。它的结构和性质分别地与 FTIR， 1H NMR， 13C NMR， 29Si NMR， EA， TGA， DSC， GPC，和 CV 被描绘并且评估。结果证明新奇混血儿拥有高热的稳定性和好电子注射能力。

Preparation and properties of a POSS-containing organic-inorganic hybrid crosslinked polymer

A novel POSS-containing organic-inorganic hybrid crosslinked polymer was prepared by hydrosilylation reaction of octahydridosilsesquioxane(T_8H_8) with 4,4'-bis(4-allyloxybenzoyloxy)phenyl(diene A).Its structure and property was characterized by FTIR,^(29)Si NMR,TGA and ellipsometer,respectively.The results show that the hybrid polymer possesses high thermal stability and low dielectric constant of 1.97 at optical frequencies.

Preparation and property of a novel soluble oxadiazole-containing functional polyacetylene

A novel high molecular weight functional polyacetylene bearing oxadiazole group as a pendant, poly{4-[2-(4-octoxyphenyl)- 1,3,4-oxadiazolyl]-benzenyloxypropynylene}, was synthesized by [Rh(nbd)Cl]2-Et3N catalyst. The polymer was soluble in common organic solvents such as CHCl3 and THF. The structures and properties of monomer and polymer were characterized and evaluated with FTIR, NMR, UV, TGA, GPC, and CV, respectively. The results show that the polymer possesses high thermal stability and well electron-injection property.

Synthesis and characterization of poly(methyl methacrylate-co-polyhedral oligomeric silsesquioxane)hybrid nanocomposites

一篇小说(甲基 methacrylate-co-polyhedral oligomeric silsesquioxane ) poly，混合 nanocomposite 被自由基聚合综合并且描绘了由(1 ) H NMR，(29 ) Si NMR，和 TGA 技术。与 PMMA 人聚合物相比， nanocomposite 有更好的热稳定性。

Preparation and Nonlinear Optical Property of Azobenzene Substituted Polyacetylene

Two new functional polyacetylenes bearing different azobenzene group, -{HC=C[azo-N (CH3)CH2CH2OH]}n-, [poly(EHAB); azo = 4,4′-azobenzene] and -{HC=C[azo-N(CH3)CH2CH2O COC3H7]}n-, [poly(EEAB)]} were prepared by [Rh(nbd)Cl]2-Et3N catalysts. Poly(EHAB) has poor solubility while poly(EEAB) can be dissolved in common solvent. The polymers were characterized by FTIR, 1H NMR, UV and GPC. The nonlinear optical property of the soluble poly(EEAB) was investigated with 8 ns width pulse at 532 nm by Z-scan technique. The results show that poly(EEAB) is endowed with the larger third-order nonlinear optical property.

Synthesis and optical limiting in copolymers of C_(60) and 1-phenyl-1-butyne

While WC16-Ph4Sn is a poor catalyst for the polymerization of l-phenyl-butyne （PB） at room temperature, it effectively polymerizes PB in the presence of C60, giving high molecular weight polymers in high yields. The polymer is soluble in THF and chloroform and spectroscopic analysis reveals that Coo has copolymerized with PB. Thus, C60 plays dual roles of comonomer and cocatalyst in the acetylene polymerization. The copolymers strongly attenuate 532-nm laser pulses, whose limiting performance is superior to that of parent

A novel poly[acrylonitrile-co-(3-ammoniumcarboxylate-butenoic acid-methylester)]copolymer for carbon fiber precursor

新奇 bifunctional comonomer 3-ammoniumcarboxylate-butenoic 酸甲基的酉旨(ACBM ) 为 poly 准备被综合[acrylonitrile-co-(3-ammoniumcarboxylate-butenoic 酸甲基的酉旨)][P (AN-co-ACBM )] 共聚物作为一位碳纤维先锋。微分扫描热量测定结果证明 P (AN-co-ACBM ) 与 polyacrylonitrile (平底锅) 相比展出显著地改进的稳定表演，例如更低的环合温度和热版本的更小的率，它主要通过离子的环合机制被归因于 ACBM 的开始。同时， rheological 分析证明 P (AN-co-ACBM ) 比平底锅拥有更好的 spinnability。

A versatile nanobuilding precursor for the effective architecture of well-defined organic/inorganic hybrid via click chemistry

新奇 octazido 代替了 nanobuilding 先锋， octakis [ dimethy ( p-azidomethylene ) siloxyl ] octasilsesquioxane ( ODA )，被 octakis 的常规重氮基转移的反应准备[ dimethy ( p-chloromethylene ) silyl ]有 NaN3 的 octasilsesquioxane ( ODC )，和它的结构被英尺红外描绘， 1H ， 13C ， 29Si NMR 和 MALDI-TOF MS 分别地。在在这个工作开发的 ODA 的合成策略的 POSS 核心的结构的重新整理有效地与传说的 azidization 过程比较被禁止。结果的 ODA 在象 CHCl3， THF，甲苯， DMF 和 DMSO 那样的普通溶剂是可溶的不仅，而且能有效地经由按化学为明确的 organicinorganic 混血儿的建筑学用作一位万用的 nanobuilding 先锋。

Preparation and near-infrared optical limiting property of fluorene-containing functional polyacetylene

包含是的 fluorene 组的新奇功能的 polyacetylene 一悬挂， poly (2-(p-methylstyrene )-7-acetylene-9,9-dioctylfluorene), 在中等产量被综合由[Rh (nbd ) Cl ] 2-Et3N 催化剂。单体和聚合物的结构和性质分别地与 FTIR， NMR， UVvis， GPC 和 Z 扫描被描绘并且评估。结果证明进 polyacetylene 的 fluorene 的加入基于二光子的吸收机制在波长 780 nm 为激光赋予了结果的聚合物以很好光的限制性质。