We present an efficient synthetic route towards two kinds of perylene-porphyrin arrays. Starting from 5, 10, 15, 20-meso-tetraphenylporphyrin, two novel 9a and 9b were designed and synthesized with 40.3% and 35.1% yi...We present an efficient synthetic route towards two kinds of perylene-porphyrin arrays. Starting from 5, 10, 15, 20-meso-tetraphenylporphyrin, two novel 9a and 9b were designed and synthesized with 40.3% and 35.1% yield, respectively.展开更多
Nanobelts, flower-like and rhizoid-like nanostructures of pure polyaniline （PANI） doped with sulfuric acid or hydrochloric acid were prepared via electrospinning by using a coagulation bath as the collector after op...Nanobelts, flower-like and rhizoid-like nanostructures of pure polyaniline （PANI） doped with sulfuric acid or hydrochloric acid were prepared via electrospinning by using a coagulation bath as the collector after optimizing the fabrication parameters. The morphologies of these nanostructures were characterized by scanning electron microscope （SEM）. The possible formation mechanisms were discussed.展开更多
An asymmetrical perylene diimide 3, N-（4-methoxyphenyl）-N＇-（4-nitrophenyl）-perylene-3,4,9,10-tetracarboxylic diimide, was synthesized, and its self-assembly and dissociation behaviors in chloroform was studied in...An asymmetrical perylene diimide 3, N-（4-methoxyphenyl）-N＇-（4-nitrophenyl）-perylene-3,4,9,10-tetracarboxylic diimide, was synthesized, and its self-assembly and dissociation behaviors in chloroform was studied in detail by UV-vis and fluorescence spectroscopies. The resulting unique helical nanostructures from 3 were proposed to be self-assembled via the cooperative actions of π-π stacking, steric hindrance and electrophile-nucleophile type pairing.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.50073018 and 90101008)
文摘We present an efficient synthetic route towards two kinds of perylene-porphyrin arrays. Starting from 5, 10, 15, 20-meso-tetraphenylporphyrin, two novel 9a and 9b were designed and synthesized with 40.3% and 35.1% yield, respectively.
基金support of the National Natural Science Foundation of China(Nos.50433020,50673083 and 50520150165)the developing program of Changjiang Scholar and Innovation Team from Ministry of Education of China(No.IRT0651)the Doctoral Program of Higher Education in China(No.20060335078).
文摘Nanobelts, flower-like and rhizoid-like nanostructures of pure polyaniline （PANI） doped with sulfuric acid or hydrochloric acid were prepared via electrospinning by using a coagulation bath as the collector after optimizing the fabrication parameters. The morphologies of these nanostructures were characterized by scanning electron microscope （SEM）. The possible formation mechanisms were discussed.
基金National Natural Science Foundation of China(Nos.50433020,50403022 and 50520150165)the developing program of Changjiang Scholar and Innovation Team from Education Department of China under Grant No.IRT0651.
文摘An asymmetrical perylene diimide 3, N-（4-methoxyphenyl）-N＇-（4-nitrophenyl）-perylene-3,4,9,10-tetracarboxylic diimide, was synthesized, and its self-assembly and dissociation behaviors in chloroform was studied in detail by UV-vis and fluorescence spectroscopies. The resulting unique helical nanostructures from 3 were proposed to be self-assembled via the cooperative actions of π-π stacking, steric hindrance and electrophile-nucleophile type pairing.
