The solidification behavior and intermetallic phase evolution during homogenization annealing of an Al-Zn-Mg-Cu alloy with 0.12 wt%Ce addition were examined.The residual Al_(2)CuMg phase is completely dissolved after ...The solidification behavior and intermetallic phase evolution during homogenization annealing of an Al-Zn-Mg-Cu alloy with 0.12 wt%Ce addition were examined.The residual Al_(2)CuMg phase is completely dissolved after homogenization and is replaced by a large number of dispersed micro/nanoscaled AlCuCe enrichment phases within Al matrix.This change occurs because of the formation of a large number of finer lamellar eutectic network structures which are more easily dissolved into Al matrix during the homogenization process.In addition,the trapping of Cu atoms in the stable AlCuCe phase also prevents the formation of Al_(2)CuMg phase,leading to the complete dissolution of Al_(2)CuMg phase in the Al-Zn-MgCu alloy.The grain refinement behavior in Al alloy with Ce addition is similar to that in alloys with the addition of Sc,because of the formation of primary Ce-enriched Al_(11)Ce_(3)phase as the nucleation agent ofα(Al)during solidification.展开更多
基金supported by the Open Project of State Key Laboratory of Environment-friendly Energy Materials, China (No. 19kfgh07)R&D of Key Technology of Light Metal Air Battery, Transformation and Industrialization of Scientific and Technological Achievements of Hunan Province, China (No. 2020GK2071)R&D of Key Technology and Materials of Magnesium Air Battery, Transformation of Scientific and Technological Achievements of Changsha City, China (No. Kh2005186)。
基金the Natural Science Foundation of Shandong Province,China(Nos.ZR2017PEM005 and ZR2017MEM005)the Project of Scientific Research Development of Shandong Universities China(Nos.J17KA043 and J17KB076)+2 种基金the Key Research Program of Shandong Province,China(No.2015GGX102021)the Foundation for Applied Science and Technology Research and Development Program of Guangdong Province,China(No.2015B090926007)2015 Shandong Province Project of Outstanding Subject Talent Group。
文摘The solidification behavior and intermetallic phase evolution during homogenization annealing of an Al-Zn-Mg-Cu alloy with 0.12 wt%Ce addition were examined.The residual Al_(2)CuMg phase is completely dissolved after homogenization and is replaced by a large number of dispersed micro/nanoscaled AlCuCe enrichment phases within Al matrix.This change occurs because of the formation of a large number of finer lamellar eutectic network structures which are more easily dissolved into Al matrix during the homogenization process.In addition,the trapping of Cu atoms in the stable AlCuCe phase also prevents the formation of Al_(2)CuMg phase,leading to the complete dissolution of Al_(2)CuMg phase in the Al-Zn-MgCu alloy.The grain refinement behavior in Al alloy with Ce addition is similar to that in alloys with the addition of Sc,because of the formation of primary Ce-enriched Al_(11)Ce_(3)phase as the nucleation agent ofα(Al)during solidification.
