基于GLCT和FPO的时变工况行星齿轮箱故障特征提取

时变转速下行星齿轮箱故障诊断存在两个问题,一是由于空间和经济条件的限制,转速传感器无法安装就无法获得设备的实时转速,二是常用的短时傅里叶变换方法时频分辨率低,难以提取到反映设备健康状态的有价值特征信息。为了克服这两个问题,提出基于广义线性调频小波变换(General Linear Chirplet Transform,GLCT)与快速路径最优(Fast Path Optimization,FPO)的无转速阶次分析故障特征提取方法。首先,使用GLCT对振动信号进行时频表征,从而提高时频分辨率,能够清晰地反映齿轮箱的时变运行状态;然后,利用FPO算法从GLCT时频表示中精确提取转频趋势线,进而采用转频曲线对原始振动信号等角度重采样将其映射到平稳的角域中;最后,从角域信号的包络阶次谱中准确地提取行星齿轮箱故障特征信息。数值仿真和应用实例的分析结果表明该方法具有较高的时频分辨率和噪声鲁棒性,能够在无转速计的情况下有效地实现时变转速行星齿轮箱齿轮故障诊断。

工程试验堆主泵压力脉动及振动特性试验研究

不稳定压力脉动引起的振动严重威胁工程试验堆主泵的安全稳定运行,为探究工程试验堆主泵进出口压力脉动特性及其对主泵振动的影响,试验同步采集不同流量工况下的压力脉动及振动信号并进行分析。结果表明,工程试验堆主泵在流体流出方向振动强度最大,出口压力脉动比进口压力脉动波动更强烈;压力脉动和振动主要频率特征相同,以叶频和2倍叶频为主,且主要特征频率幅值随流量变化趋势一致。相干分析发现,压力脉动信号与振动信号在叶频及其倍频处相干性最强。研究结果可为工程试验堆主泵的减振降噪提供一定参考。

AZIDE-ALKYNE CLICK POLYMERIZATION:AN UPDATE

The great achievements of click chemistry have encouraged polymer scientists to use this reaction in their field. This review assembles an update of the advances of using azide-alkyne click polymerization to prepare functional polytriazoles（PTAs） with linear and hyperbranched structures.The Cu（I）-mediated click polymerization furnishes 1,4-regioregular PTAs,whereas,the metal-free click polymerization of propiolates and azides produces PTAs with 1,4-regioisomer contents up to 90%.The PTAs display advanced functions,such as aggregation-induced emission,thermal stability,biocompatibility and optical nonlinearity.

Synthesis of Functional Hyperbranched Poly(methyltriazolylcarboxylate)s by Catalyst-free Click Polymerization of Butynoates and Azides

Azide-alkyne click polymerization has become a powerful tool for polymer synthesis.However,the click polymerization between internal alkynes and azides is rarely utilized to prepare functional polymers.In this work,the polymerization reactions of activated internal alkyne monomers of tris(2-butynoate)s(1)with tetraphenylethene-containing diazides(2)were performed in dimethylformamide(DMF)under simple heating,affording four hyperbranched poly(methyltriazolylcarboxylate)s(hb-PMTCs)with high molecular weights(A4W up to 2.4 x 104)and regioregularities(up to 83.9%)in good yields.The hb-PMTCs are soluble in common organic solvents,and thermally stable with 5%weight loss temperatures up to 400℃.They are non-emissive in dilute solution,but become highly emissive in aggregated state,exhibiting aggregationinduced emission characteristics.The polymers can generate fluorescent photopatterns with high resolution,and can work as fluorescent sensors to detect nitroaromatic explosive with high sensitivity.

Facile Synthesis of Functional Poly(methyltriazolylcarboxylate)s by Solvent-and Catalyst-free Butynoate-Azide Polycycloaddition

The copper-catalyzed and metal-free azide-alkyne click polymerizations have become efficient tools for polymer synthesis. However,the 1,3-dipolar polycycloadditions between internal alkynes and azides are rarely employed to construct functional polymers. Herein, the polycycloadditions of dibutynoate(1) and tetraphenylethene-containing diazides(2) were carried out at 100 °C for 12 h under solvent-and catalyst-free conditions, producing soluble poly(methyltriazolylcarboxylate)s(PMTCs) with high molecular weights in high yields. The resultant polymers were thermally stable with 5% weight loss temperatures up to 377 °C. The PMTCs showed aggregation-induced emission(AIE)properties. They could work as fluorescent sensors for detecting explosive with high sensitivity, and generate two-dimensional fluorescent photopatterns with high resolution. Furthermore, their triazolium salts could be utilized for cell-imaging applications.