The electrodeposition of aluminum(Al)was studied using two electrolyte solutions,such as anhydrous AlCl3-urea and hydrated AlCl3·6 H2 O-urea.A systematic examination using cell voltages 1.0–2.0 V was carried out...The electrodeposition of aluminum(Al)was studied using two electrolyte solutions,such as anhydrous AlCl3-urea and hydrated AlCl3·6 H2 O-urea.A systematic examination using cell voltages 1.0–2.0 V was carried out at temperatures((50–100)±2)°C.A needle-shaped cathode was employed for the deposition of aluminum.A dendrite and particulate microstructure of Al were observed on the needle-shaped cathode.An improved condition for the manufacturing of small sizes and high purity of aluminum deposits was obtained.Pure Al with a current efficiency(yield)of 84%–99%was obtained from those of non-aqueous electrolytes and only of 8.6%–9.3%from those of hydrated electrolytes.The electrical conductivities of electrolytes remained considerable at((50–100)±2)°C.The improved aluminum powders were used for the reaction with water.The aluminum reacts with water at room temperature,producing pure H2 with 100%yield.The electrodeposited aluminum metal can be used as an excellent energy carrier.展开更多
基金the financial support from Ministry of Science and Technology,Taiwan,China Grant number:MOST 106-2113-M-033-008。
文摘The electrodeposition of aluminum(Al)was studied using two electrolyte solutions,such as anhydrous AlCl3-urea and hydrated AlCl3·6 H2 O-urea.A systematic examination using cell voltages 1.0–2.0 V was carried out at temperatures((50–100)±2)°C.A needle-shaped cathode was employed for the deposition of aluminum.A dendrite and particulate microstructure of Al were observed on the needle-shaped cathode.An improved condition for the manufacturing of small sizes and high purity of aluminum deposits was obtained.Pure Al with a current efficiency(yield)of 84%–99%was obtained from those of non-aqueous electrolytes and only of 8.6%–9.3%from those of hydrated electrolytes.The electrical conductivities of electrolytes remained considerable at((50–100)±2)°C.The improved aluminum powders were used for the reaction with water.The aluminum reacts with water at room temperature,producing pure H2 with 100%yield.The electrodeposited aluminum metal can be used as an excellent energy carrier.
