The synthesis, the crystal structure and the reaction of the hetero-binuclear complex [MnRe(CO)6(-SH)(-SC(H)PPri3)(PPh3)] are reported. The results of single crystal X-ray structure analysis showed that the fragment...The synthesis, the crystal structure and the reaction of the hetero-binuclear complex [MnRe(CO)6(-SH)(-SC(H)PPri3)(PPh3)] are reported. The results of single crystal X-ray structure analysis showed that the fragments Mn(CO)3 and Re(CO)3 were bridged by SH and SC(H)PPri3. The title complexes can react with BunLi and RX forming complexes MnRe(CO)6(-SR)(-SC(H)PPri3)(PPh3) (R = Me, CH2CH=CH2, SnBu3n).展开更多
基金the National Natural Science Foundation of China (No. 29672018) for financial support.
文摘The synthesis, the crystal structure and the reaction of the hetero-binuclear complex [MnRe(CO)6(-SH)(-SC(H)PPri3)(PPh3)] are reported. The results of single crystal X-ray structure analysis showed that the fragments Mn(CO)3 and Re(CO)3 were bridged by SH and SC(H)PPri3. The title complexes can react with BunLi and RX forming complexes MnRe(CO)6(-SR)(-SC(H)PPri3)(PPh3) (R = Me, CH2CH=CH2, SnBu3n).
