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温度和共混浓度对激基复合物与电致激基复合物共存体系的磁效率调控 被引量:1
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作者 吴雨廷 朱洪强 +4 位作者 赵茜 刘俊宏 彭腾 汪波 熊祖洪 《科学通报》 EI CAS CSCD 北大核心 2024年第4期596-605,共10页
激基复合物(exciplex)和电致激基复合物(electroplex)经常同时产生于体异质结的有机发光二极管(organic light emitting diodes,OLEDs),有报道称利用这两种发射态共存的器件实现了高效率发光.器件高效率的物理机制与共存体系中自旋对态(... 激基复合物(exciplex)和电致激基复合物(electroplex)经常同时产生于体异质结的有机发光二极管(organic light emitting diodes,OLEDs),有报道称利用这两种发射态共存的器件实现了高效率发光.器件高效率的物理机制与共存体系中自旋对态(spin-pair states)的微观过程有关,相关微观过程还有待深入研究.本文以特征的有机磁场效应(organic magnetic field effects)作为主要探测工具,通过改变器件的工作温度和给体与受体的共混比例来研究这种双发射态共存体系中自旋对态的演变过程.实验结果表明:降低发光器件的环境温度不仅会减弱从高能激基复合物到低能电致激基复合物的Dexter能量传递过程,而且因器件偏压增高还会引起电致激基复合物电荷转移(charge-transfer,CT)态的场致解离,使其数量较少,导致其CT态的反向系间窜越(reverse intersystem crossing,RISC)过程减弱.另外,增加发光层中给体的浓度会引起电荷注入更不平衡,增强过剩的空穴载流子与电致激基复合物的解离反应,这也会减弱电致激基复合物CT态的RISC过程.因此,温度降低或给体含量增多,器件的磁效率(magneto-efficiency,Mη)从原来受RISC过程主导的负磁效应转化为受系间窜越(intersystem crossing,ISC)过程主导的正磁效应.本工作有利于深入理解激基复合物和电致激基复合物共存体系中自旋对态的物理微观机制. 展开更多
关键词 有机发光二极管 磁效率 反向系间窜越 激基复合物 电致激基复合物
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Three Indication Variables and Their Performance for the Troubled-Cell Indicator using K-Means Clustering 被引量:1
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作者 Zhihuan Wang Zhen Gao +2 位作者 Haiyun Wang Qiang Zhang hongqiang zhu 《Advances in Applied Mathematics and Mechanics》 SCIE 2023年第2期522-544,共23页
In Zhu,Wang and Gao(SIAM J.Sci.Comput.,43(2021),pp.A3009–A3031),we proposed a new framework of troubled-cell indicator(TCI)using K-means clustering and the numerical results demonstrate that it can detect the trouble... In Zhu,Wang and Gao(SIAM J.Sci.Comput.,43(2021),pp.A3009–A3031),we proposed a new framework of troubled-cell indicator(TCI)using K-means clustering and the numerical results demonstrate that it can detect the troubled cells accurately using the KXRCF indication variable.The main advantage of this TCI framework is its great potential of extensibility.In this follow-up work,we introduce three more indication variables,i.e.,the TVB,Fu-Shu and cell-boundary jump indication variables,and show their good performance by numerical tests to demonstrate that the TCI framework offers great flexibility in the choice of indication variables.We also compare the three indication variables with the KXRCF one,and the numerical results favor the KXRCF and the cell-boundary jump indication variables. 展开更多
关键词 Troubled-cell indicator indication variable discontinuous Galerkin method shock detection K-means clustering
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教育评价改革背景下高校教师身份认同研究——以英语专业教师为例 被引量:1
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作者 朱红强 吴悯妍 《外国语言与文化》 2022年第2期138-149,共12页
当下中国高等院校英语专业处于从外延式发展转向以质量为核心的内涵式发展阶段,在此背景下,本文采用问卷调查法,探讨内涵式教育模式下高校英语专业教师身份认同情况。研究发现:第一,在内涵式教育模式背景下,英语专业教师强调对专业内涵... 当下中国高等院校英语专业处于从外延式发展转向以质量为核心的内涵式发展阶段,在此背景下,本文采用问卷调查法,探讨内涵式教育模式下高校英语专业教师身份认同情况。研究发现:第一,在内涵式教育模式背景下,英语专业教师强调对专业内涵的质量提升,凸显出内涵式教育的支持者这一身份认同;第二,大部分教师在教学与科研之间表现出矛盾性,呈现教学者而非研究者这一身份认同;第三,教师通过表达自我发展的需求,构建出发展自我的学习者这一身份认同;同时,其身份认同也是教师主体与机构话语之间形成的一种互动关系。 展开更多
关键词 教育评价改革 内涵式教育模式 英语专业教师 教师身份 职业发展
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有机发光掺杂器件中的反常磁效应 被引量:7
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作者 邓金秋 汤仙童 +4 位作者 潘睿亨 胡叶倩 朱洪强 熊祖洪 陈晓莉 《科学通报》 EI CAS CSCD 北大核心 2018年第28期2974-2984,共11页
采用不同浓度的热活化延迟荧光(thermally activated delayed fluorescence,TADF)材料2,3,5,6-四(3,6-二苯基-9-咔唑基)-对苯二腈(2,3,5,6-tetrakis(3,6-diphenylcarbazol-9-yl)-1,4-dicyanobenzene,4CzTPN-Ph)为掺杂剂,三(8-羟基喹啉)... 采用不同浓度的热活化延迟荧光(thermally activated delayed fluorescence,TADF)材料2,3,5,6-四(3,6-二苯基-9-咔唑基)-对苯二腈(2,3,5,6-tetrakis(3,6-diphenylcarbazol-9-yl)-1,4-dicyanobenzene,4CzTPN-Ph)为掺杂剂,三(8-羟基喹啉)铝(tris-8-hydroxyquinoline aluminum,Alq3)为主体材料制备了发光层为Alq3:x%4CzTPN-Ph的有机发光二极管器件,并测量了室温下不同注入电流和不同掺杂浓度,以及固定某一电流和掺杂浓度在不同温度下器件的磁电致发光(magneto-electroluminescence,MEL)效应和磁电导(magneto-conductance,MC)效应.实验发现,在主客体掺杂类型器件中,与普通掺杂器件减小的磁效应相比,这种器件具有明显的反常磁效应——即表现出增强的MEL和MC幅值.以室温下注入电流为150μA的实验为例,发光层为Alq3:5%4CzTPN-Ph器件的MEL幅值在磁场为300m T处达到了10%左右,大约是参考器件(发光层为CBP:5%4CzTPN-Ph)的MEL幅值(~0.75%)的13倍,且该器件对应的MC幅值在磁场为300 m T处达到了6%左右,大约是此参考器件MC幅值(~0.12%)的50倍.此外,这种掺杂器件的MEL和MC明显受到掺杂浓度的调控,当掺杂浓度达15%左右时,MEL和MC幅值可达到最大值.在不同温度下,这种掺杂器件的MEL和MC值均随着温度的降低而减小.通过分析器件的能级结构和光谱可知,Alq3:4CzTPN-Ph器件具有主客体分子间特殊的能级排布,造成客体分子的能级陷阱较弱,外加磁场抑制三重态激子对电荷的散射作用(TQA)就可产生显著的MEL和MC幅值,从而得到不同于普通掺杂器件的反常磁效应.此外,由于TQA过程受三重态激子浓度与载流子浓度的影响,掺杂浓度和实验温度也能通过影响三重态激子浓度和载流子浓度来对TQA反应强弱进行调控,从而有效地调控这种反常磁效应.本研究工作有助于深入理解基于4CzTPN-Ph发光器件微观机制的演化过程,并将促进有机发光二极管在磁学器件方面的应用. 展开更多
关键词 热活化延迟荧光材料 磁电致发光效应 磁电导效应 散射过程 能级陷阱
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红荧烯掺入多种激基复合物器件的微观过程 被引量:1
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作者 马彩虹 汤仙童 +5 位作者 许静 叶晟楠 朱洪强 王影 屈芬兰 熊祖洪 《科学通报》 EI CAS CSCD 北大核心 2021年第1期63-72,共10页
红荧烯(5,6,11,12-tetraphenylnaphthacene,Rubrene)是一种典型的发射橙黄光的荧光客体材料,因具有丰富的微观过程而被广泛运用于主客体掺杂器件中,但将其掺杂在具有延迟荧光特性的激基复合物主体中的研究还较少.本文把2%的Rubrene掺杂... 红荧烯(5,6,11,12-tetraphenylnaphthacene,Rubrene)是一种典型的发射橙黄光的荧光客体材料,因具有丰富的微观过程而被广泛运用于主客体掺杂器件中,但将其掺杂在具有延迟荧光特性的激基复合物主体中的研究还较少.本文把2%的Rubrene掺杂到具有不同三重态激子能量的四种激基复合物主体里,以指纹式的有机电致发光磁响应(magneto-electroluminescence,MEL)曲线作为探测工具,研究了此类掺杂体系的能量传输和光发射机制.实验发现,当主体激基复合物的三重态激子(EX_(3))能量低于Rubrene客体的第二级三重态激子(T_(2,Rub))能量时,器件的MEL曲线表现为主体极化子对间的系间窜越(intersystem crossing,ISC)过程;否则,器件MEL低磁场部分的线型来源于Rubrene激子的高能级反向系间窜越(high-level reverse intersystem crossing,HL-RISC;T_(2,Rub)→S_(1,Rub))过程;MEL高磁场部分的线型在大电流密度下由Rubrene三重态激子间的聚合反应(T_(1,Rub)+T_(1,Rub)→S_(1,Rub)+S0,Rub)引起,在小电流密度下由单重态激子的分裂(S_(1,Rub)+S0,Rub→T_(1,Rub)+T_(1,Rub))过程决定.此外,温度和电流密度会通过调控Rubrene三重态激子(T_(1,Rub)和T_(2,Rub))的寿命和数量来影响上述微观过程的强弱程度.这是由于主体与客体的单、三重态激子的能级差会调控主客体间的能量转移,进而通过调节客体Rubrene分子上三重态激子的数量和寿命来影响三重态激子的利用率,最终影响器件的发光强度.本文工作既可加深基于Rubrene发光器件微观机制的认识,也可为增强其发光效率提供理论参考. 展开更多
关键词 红荧烯 电致发光磁响应 激基复合物 能量转移 高能级反向系间窜越
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红荧烯共混器件中光致发光及光电流的磁效应研究
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作者 王影 汤仙童 +4 位作者 马彩虹 叶晟楠 赵茜 朱洪强 熊祖洪 《中国科学:信息科学》 CSCD 北大核心 2020年第11期1756-1766,共11页
为了研究红荧烯共混体系中激子的反应过程,本文制备了一系列rubrene与3TPYMB共混的有机光电器件,并测量了不同比例的共混器件在不同温度和外加偏压条件下的光致发光和光电流的磁效应.实验发现,外加零偏压时,共混器件中光致发光磁效应(ma... 为了研究红荧烯共混体系中激子的反应过程,本文制备了一系列rubrene与3TPYMB共混的有机光电器件,并测量了不同比例的共混器件在不同温度和外加偏压条件下的光致发光和光电流的磁效应.实验发现,外加零偏压时,共混器件中光致发光磁效应(magneto-photoluminescence,MPL)在不同温度下均为类"W"线型,光电流的磁效应(magneto-photocurrent,MPC)则出现了没有报道过的类"M"线型,且MPC高场效应与低场效应随温度有不同的变化规律;同时,在外加偏压调控光电流为正的情况下,共混器件中的MPC幅值出现了正负转变.分析结果表明,器件中类"W"型曲线是受磁场调控的单重态激子分裂(singletfission,STT)过程引起的,而类"M"型MPC的低场上升部分是3TPYMB分子中极化子对间的系间窜越(intersystem crossing,ISC)过程的作用,高场下降部分则是由三重态激子–电荷湮灭(triplet-charge annihilation,TQA)过程所引起,MPC幅值的正负转变与外加偏压强度有关.本工作不仅有利于深入认识光电器件中光致发光与光电流的微观机制,而且为进一步优化红荧烯器件的光电性能提供了参考. 展开更多
关键词 红荧烯 光致发光磁效应 光电流磁效应 单重态激子裂变 三重态激子–电荷湮灭
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Ir(ppy)3调控Rubrene激子分裂和发光过程的微观机制研究
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作者 屈芬兰 汤仙童 +4 位作者 朱洪强 许静 段谋正 赵茜 熊祖洪 《中国科学:信息科学》 CSCD 北大核心 2020年第1期151-162,共12页
为探究红荧烯(Rubrene)内部的单重态激子分裂(S1+S0→T1+T1,STT)和发光过程的微观机制,本文选用具有强自旋轨道耦合(spin-orbit coupling,SOC)且发射绿光的磷光材料Ir(ppy)3,以不同比例混入到发射橙光的Rubrene薄膜中制备了一系列发光器... 为探究红荧烯(Rubrene)内部的单重态激子分裂(S1+S0→T1+T1,STT)和发光过程的微观机制,本文选用具有强自旋轨道耦合(spin-orbit coupling,SOC)且发射绿光的磷光材料Ir(ppy)3,以不同比例混入到发射橙光的Rubrene薄膜中制备了一系列发光器件,并在不同温度和电流下测量了器件的电致发光磁效应(magneto-electroluminescence,MEL)和电流–发光(I-B)曲线.实验发现:室温下不同混入比例的发光器件,其MEL线型均表现为磁场调制的STT指纹式特征曲线,但MEL幅值随混入比例的增加却表现出先增加后减小的特性,而其发光强度则表现为单调增加的特点,这与常规Rubrene掺杂器件(如mCP:y%Rubrene)随浓度增大其STT增强但发光减弱的结果不同.通过对Ir(ppy)3的单、三重态激子能级和发射谱以及Rubrene吸收谱的分析可知,器件中除了Rubrene分子间距会影响STT过程的强弱外,还包括由Ir(ppy)3强的SOC导致的激子间的系间穿越(intersystem crossing,ISC)和Ir(ppy)3的T1激子与Rubrene的S1激子间的能量传递(energy transfer,ET)过程,这3种微观机制的共同作用导致了器件MEL和发光的复杂变化,且电流密度的大小和器件工作温度的高低对它们还有较好的调控作用.显然,本研究有助于深入理解基于红荧烯光电器件的微观过程及其演化机制. 展开更多
关键词 红荧烯 单线态激子分裂 自旋轨道耦合 能量转移 发光的磁效应
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Radiative decay of theΞ(1620)in a hadronic molecule picture 被引量:1
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作者 Yin Huang Feng Yang hongqiang zhu 《Chinese Physics C》 SCIE CAS CSCD 2021年第7期142-150,共9页
Last year,the Ξ(1620) state,which is cataloged in the Particle Data Group(PDG) with only one star,was reported again in the Ξ-π+final state by the Belle Collaboration.Its properties,such as the spectroscopy and dec... Last year,the Ξ(1620) state,which is cataloged in the Particle Data Group(PDG) with only one star,was reported again in the Ξ-π+final state by the Belle Collaboration.Its properties,such as the spectroscopy and decay width,cannot be simply explained in the context of conventional constituent quark models.This inspires an active discussion on the structure of this resonance.In this paper,we study the radiative decays of the newly observed Ξ(1620) assuming that it is a meson-baryon molecular state of AK and with spin-parity JP=1/2-developed in our previous study.The partial decay widths of the AK-ΣK molecular state into Ξγ and Ξπγ final states through hadronic loops are evaluated using effective Lagrangians.The partial widths for Ξ(1620)^(0)→γΞ is evaluated to be approximately 118.76-174.21 keV,which may be accessible for the LHCb experiment.If Ξ(1620) is aΛK-∑K molecule,the radiative transition strength Ξ(1620)^(0)→γKA is considerably small and the decay width is of the order of 0.01 eV.Future experimental measurements of these processes can be useful to test the molecule interpretations of the Ξ(1620). 展开更多
关键词 meson-baryon molecular state decay widths radiative decays
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Strong decays of the P_(cs)(4459) as a Ξc D^(*) molecule
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作者 Feng Yang Yin Huang hongqiang zhu 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2021年第12期104-110,共7页
In this work,we study the strong decay of the newly observed P_(cs)(4459),assuming that it is a pureΞcD^(*)molecular state.Considering two possible spin-parity assignments J^(P)=1/2^(−)and J^(P)=3/2^(−),the partial d... In this work,we study the strong decay of the newly observed P_(cs)(4459),assuming that it is a pureΞcD^(*)molecular state.Considering two possible spin-parity assignments J^(P)=1/2^(−)and J^(P)=3/2^(−),the partial decay widths of theΞcD^(*)molecular state into J/ψΛ,D^(−)_(s)Λ^(+)_(c),and DΞ^((′))_(c) final states through hadronic loops are evaluated with the help of the effective Lagrangians.In comparison with the LHCb data,the S-waveD^(*)Ξc molecular with J^(P)=1/2^(−)assignment for P_(cs)(4459)is supported by our study,while the P_(cs)(4459)in spin-parity J^(P)=3/2^(−)case may be explained as an S-wave coupled bound state with lagerΞcD^(*)component.In addition,the calculated partial decay widths with J^(P)=1/2^(−)ΞcD^(*)molecular state picture indicate that allowed decay mode,DΞ′c,may have the biggest branching ratio.The experimental measurements for this strong decay process could be a crucial test for the molecule interpretation of the P_(cs)(4459). 展开更多
关键词 molecular state strong decay effective Lagrangians
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Radiative decay ofΞb(6227)in a hadronic molecule picture
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作者 hongqiang zhu Yin Huang 《Chinese Physics C》 SCIE CAS CSCD 2020年第8期16-22,共7页
The baryonΞb(6227)with the quantum number J^P=1/2−is considered as a molecular state composed of aΣb baryon and K¯meson.The partial decay widths of theΣbK¯molecular state intoΞbγandΞ′bγfinal states t... The baryonΞb(6227)with the quantum number J^P=1/2−is considered as a molecular state composed of aΣb baryon and K¯meson.The partial decay widths of theΣbK¯molecular state intoΞbγandΞ′bγfinal states through hadronic loops are evaluated with the help of the effective Lagrangians.The partial widths for theΞb(6227)→γΞb andΞb(6227)→γΞ′b transitions are evaluated at 1.50–1.02 keV and 17.56–24.91 keV,respectively,which may be accessible for the LHCb.Based on our results,we argue that an experimental determination of the radiative decay width ofΞb(6227)is important for the understanding of its intrinsic properties. 展开更多
关键词 effective Lagrangian approach molecular state decay widths
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An h-Adaptive Runge-Kutta Discontinuous Galerkin Method for Hamilton-Jacobi Equations
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作者 hongqiang zhu Jianxian Qiu 《Numerical Mathematics(Theory,Methods and Applications)》 SCIE 2013年第4期617-636,共20页
In[35,36],we presented an h-adaptive Runge-Kutta discontinuous Galerkin method using troubled-cell indicators for solving hyperbolic conservation laws.A tree data structure(binary tree in one dimension and quadtree in... In[35,36],we presented an h-adaptive Runge-Kutta discontinuous Galerkin method using troubled-cell indicators for solving hyperbolic conservation laws.A tree data structure(binary tree in one dimension and quadtree in two dimensions)is used to aid storage and neighbor finding.Mesh adaptation is achieved by refining the troubled cells and coarsening the untroubled"children".Extensive numerical tests indicate that the proposed h-adaptive method is capable of saving the computational cost and enhancing the resolution near the discontinuities.In this paper,we apply this h-adaptive method to solve Hamilton-Jacobi equations,with an objective of enhancing the resolution near the discontinuities of the solution derivatives.One-and two-dimensional numerical examples are shown to illustrate the capability of the method. 展开更多
关键词 Runge-Kutta discontinuous Galerkin method h-adaptive method Hamilton-Jacobi equation
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A Comparison of the Performance of Limiters for Runge-Kutta Discontinuous Galerkin Methods
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作者 hongqiang zhu Yue Cheng Jianxian Qiu 《Advances in Applied Mathematics and Mechanics》 SCIE 2013年第3期365-390,共26页
Discontinuities usually appear in solutions of nonlinear conservation laws even though the initial condition is smooth,which leads to great difficulty in computing these solutions numerically.The Runge-Kutta discontin... Discontinuities usually appear in solutions of nonlinear conservation laws even though the initial condition is smooth,which leads to great difficulty in computing these solutions numerically.The Runge-Kutta discontinuous Galerkin(RKDG)methods are efficientmethods for solving nonlinear conservation laws,which are highorder accurate and highly parallelizable,and can be easily used to handle complicated geometries and boundary conditions.An important component of RKDG methods for solving nonlinear conservation laws with strong discontinuities in the solution is a nonlinear limiter,which is applied to detect discontinuities and control spurious oscillations near such discontinuities.Many such limiters have been used in the literature on RKDG methods.A limiter contains two parts,first to identify the"troubled cells",namely,those cells which might need the limiting procedure,then to replace the solution polynomials in those troubled cells by reconstructed polynomials which maintain the original cell averages(conservation).[SIAM J.Sci.Comput.,26(2005),pp.995-1013.]focused on discussing the first part of limiters.In this paper,focused on the second part,we will systematically investigate and compare a few different reconstruction strategies with an objective of obtaining the most efficient and reliable reconstruction strategy.This work can help with the choosing of right limiters so one can resolve sharper discontinuities,get better numerical solutions and save the computational cost. 展开更多
关键词 LIMITER discontinuous Galerkin method hyperbolic conservation laws
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