In this paper, (-)menthyl methacrylate((-)MnMA) was polymerized at 78C in toluene with three types of anionic catalysts, which were complexes of fluorenyllithium with (-)sparteine - ((-)-Sp) , (S, S)-(+)-2, 3-dimethox...In this paper, (-)menthyl methacrylate((-)MnMA) was polymerized at 78C in toluene with three types of anionic catalysts, which were complexes of fluorenyllithium with (-)sparteine - ((-)-Sp) , (S, S)-(+)-2, 3-dimethoxy-1, 4-bis(dimethylamino)butane((+)DDB) and N,N,N,N-tetra- methylethylenediamine(TMEDA), and the chiral optical property of the obtained polymer was studied. The circular dichroism (CD) spectrum of the polymer showed negative Cotton effect.展开更多
基金the National Natural Science Foundation of China for financial support
文摘In this paper, (-)menthyl methacrylate((-)MnMA) was polymerized at 78C in toluene with three types of anionic catalysts, which were complexes of fluorenyllithium with (-)sparteine - ((-)-Sp) , (S, S)-(+)-2, 3-dimethoxy-1, 4-bis(dimethylamino)butane((+)DDB) and N,N,N,N-tetra- methylethylenediamine(TMEDA), and the chiral optical property of the obtained polymer was studied. The circular dichroism (CD) spectrum of the polymer showed negative Cotton effect.
