Soil contamination by metals is a worldwide environmental problem. Electrokinetic extraction is a promising technology for in-situ remediation of contaminated soils of low hydraulic permeability. However, the extracti...Soil contamination by metals is a worldwide environmental problem. Electrokinetic extraction is a promising technology for in-situ remediation of contaminated soils of low hydraulic permeability. However, the extraction of metals is usually hindered by the high buffer capacity of natural soils. Organophosphonates are strong metal chelates as ethylenediaminetetraacetic acid(EDTA) which has been widely studied in the enhancement of electrokinetic remediation. In this study, batch desorption experiments and bench-scale electrokinetic extraction experiments were carried out to study the effect of two organophosphonates, i.e.,(nitrilotrimethylene)triphosphonate(NTMP) &(ethylenedinitrilo)-tetramethylenephosphonate(EDTMP), on the extraction of cadmium from a natural clay in comparison with EDTA. Results of the batch desorption experiments showed that more than 75% of the sorbed cadmium could be dissolved into solution using 0.1 mol·L^(-1) organophosphonates or EDTA in the wide p H range of 1–11. Results of the electrokinetic extraction experiments showed that the cadmium spiked in the specimen migrated towards the anode with the enhancement of NTMP,EDTMP, and EDTA under a constant voltage gradient of approximately 1.0 V·cm-1. Although cadmium mobilization enhanced by EDTA was more efficient than that by the organophosphonates, accumulation of cadmium was observed in the vicinity of the anode. The average removal efficiencies of cadmium from the soil after approximately 5 days of electrokinetic extraction enhanced by 0.1 mol·L-1 NTMP(22.8%) and EDTMP(22.4%) were higher than that by 0.1 mol·L^(-1) EDTA(15.1%).展开更多
Converting CO2 to carbon-containing fuels is an effective approach to relieving energy shortages.Carbon quantum dots(CQDs) have shown distinct properties and attracted tremendous interest in CO2 reduction.Herein,we re...Converting CO2 to carbon-containing fuels is an effective approach to relieving energy shortages.Carbon quantum dots(CQDs) have shown distinct properties and attracted tremendous interest in CO2 reduction.Herein,we report a joint experimental-computational mechanistic study of photoreduction CO2 to CO on the model catalyst 9-hydroxyphenal-1-one(HPHN) CQDs with known structure.Our theoretical calculations reveal that the rate-determining step is COOH·formation,which is closely related to the proton and electron transfer induced by hydrogen bonding in the excited state.According to the calculated volcano plot,the solution we proposed is addition Zn^(2+) ions.The active center changed from the hydroxyl oxygen atom to the Zn atom and the barrier of the COOH·formation step is noticeably decreased when Zn^(2+) ions are added.It is further confirmed by the experimental data that the activity of CO2 reduction increases 2.9 times when Zn^(2+) ions are added.展开更多
To avoid pollution of generator exhaust port after the ship docked, the use of shore power supply is developing direction of port. And the shore power grounding method and related standards needed to be carried out. A...To avoid pollution of generator exhaust port after the ship docked, the use of shore power supply is developing direction of port. And the shore power grounding method and related standards needed to be carried out. According to developing status of foreign medium voltage ship and characteristics of navy shipboard power supply, this paper presents a shore power supply network structure and its grounding method. The simulation results show the power supply network structure can effectively suppress the single-phase intermittent ground fault on the system to produce the harm.展开更多
The pots discovered in Inner Mongolia and Hebei Province are huge with a maximum diameter of 9 m and a depth of 3.5 m, singular in shape,caused by weathering and wind erosion and have certain direction. They are a kin...The pots discovered in Inner Mongolia and Hebei Province are huge with a maximum diameter of 9 m and a depth of 3.5 m, singular in shape,caused by weathering and wind erosion and have certain direction. They are a kind of typical climatic geomorphology. This展开更多
The series voltage source converter(SVSC)is widely used in the power electronic equipment,such as series active power filter,dynamic voltage restorer,unified power flow controller and so on.However,while the SVSC is m...The series voltage source converter(SVSC)is widely used in the power electronic equipment,such as series active power filter,dynamic voltage restorer,unified power flow controller and so on.However,while the SVSC is more vulnerable to the impact of fault current,its applications are increasing,bringing huge challenges to the safe operation of the grid.In recent years,the topology and control strategy of the series voltage source converter with fault current limiting(SVSC-FCL)are a research hotspot.In this paper,it suggests classifying SVSC-FCL based SVSC into two groups:the control scheme optimization group and the existing topology improvement group.The research challenges and perspectives of the SVSC-FCL are introduced in detail.This paper aims to illustrate current research progress on SVSC-FCL and enrich the available pool of the multi-functional power electronic equipment.展开更多
Bifacial monolithic all-perovskite tandem solar cells have the promise of delivering higher output power density by inheriting the advantages of both tandem and bifacial architectures simultaneously.Herein,we demonstr...Bifacial monolithic all-perovskite tandem solar cells have the promise of delivering higher output power density by inheriting the advantages of both tandem and bifacial architectures simultaneously.Herein,we demonstrate,for the first time,the bifacial monolithic all-perovskite tandem solar cells and reveal their output power potential.The bifacial tandems are realized by replacing the rear metal electrodes of monofacial tandems with transparent conduction oxide electrodes.Bandgap engineering is deployed to achieve current matching under various rear illumination conditions.The bifacial tandems show a high output power density of 28.51 mW cm−2 under a realistic rear illumination(30 mW cm−2).Further energy yield calculation shows substantial energy yield gain for bifacial tandems compared with the monofacial tandems under various ground albedo for different climatic conditions.This work provides a new device architecture for higher output power for all-perovskite tandem solar cells under real-world conditions.展开更多
Approximately 7000 m^3 of aged refuse （AR） with a placement of over eight years was excavated from Shanghai Refuse Landfill, the largest landfill in China, and used for the construction of a two-stage bioreactor （A...Approximately 7000 m^3 of aged refuse （AR） with a placement of over eight years was excavated from Shanghai Refuse Landfill, the largest landfill in China, and used for the construction of a two-stage bioreactor （AR biofilter） media for the biological treatment of 100 m3 of refuse landfill leachate. It was found that over 64% of COD, 96.9%-99.8% of NH4^＋-N, and 95.8%-99.8% of BOD5 could be removed by the AR biofilter, when the leachate with initial COD, BOD5, and NH4^＋-N concentrations were 986-4128 mg/L, 264--959 mg/L,m and 538-1583 mg/L, respectively. The corresponding concentrations in the effluent were reduced to below 30（000 mg/L, 2-12 mg/L, and 10-20 mg/L, respectively. The effluent was clear and pale yellow with suspended solid below 150 mg/L and color below 150 Pt/Co degree. Meanwhile, the total nitrogen removal was only 49%-63%, indicating a relative poor denitrification capacity of AR biofilter. The effluent pH was neutral and the population of Escherichia coli was less than 10^-1 CFU/mL. Hence, it was considered that the demonstration project can work well for the effective treatment of leachate.展开更多
基金Supported by the National Natural Science Foundation of China(41201303)Shandong Province Natural Science Foundation,China(ZR2017QEE016)+1 种基金the Fundamental Research for the Central Universities(14CX02191A,17CX02075)State Key Laboratory of Pollution Control and Resource Reuse Foundation(PCRRF13023)
文摘Soil contamination by metals is a worldwide environmental problem. Electrokinetic extraction is a promising technology for in-situ remediation of contaminated soils of low hydraulic permeability. However, the extraction of metals is usually hindered by the high buffer capacity of natural soils. Organophosphonates are strong metal chelates as ethylenediaminetetraacetic acid(EDTA) which has been widely studied in the enhancement of electrokinetic remediation. In this study, batch desorption experiments and bench-scale electrokinetic extraction experiments were carried out to study the effect of two organophosphonates, i.e.,(nitrilotrimethylene)triphosphonate(NTMP) &(ethylenedinitrilo)-tetramethylenephosphonate(EDTMP), on the extraction of cadmium from a natural clay in comparison with EDTA. Results of the batch desorption experiments showed that more than 75% of the sorbed cadmium could be dissolved into solution using 0.1 mol·L^(-1) organophosphonates or EDTA in the wide p H range of 1–11. Results of the electrokinetic extraction experiments showed that the cadmium spiked in the specimen migrated towards the anode with the enhancement of NTMP,EDTMP, and EDTA under a constant voltage gradient of approximately 1.0 V·cm-1. Although cadmium mobilization enhanced by EDTA was more efficient than that by the organophosphonates, accumulation of cadmium was observed in the vicinity of the anode. The average removal efficiencies of cadmium from the soil after approximately 5 days of electrokinetic extraction enhanced by 0.1 mol·L-1 NTMP(22.8%) and EDTMP(22.4%) were higher than that by 0.1 mol·L^(-1) EDTA(15.1%).
基金supported by the National Natural Science Foundation of China (Grant Nos. 21677029, 21606040)the Fundamental Research Funds for the Central Universities (DUT18LK26)。
文摘Converting CO2 to carbon-containing fuels is an effective approach to relieving energy shortages.Carbon quantum dots(CQDs) have shown distinct properties and attracted tremendous interest in CO2 reduction.Herein,we report a joint experimental-computational mechanistic study of photoreduction CO2 to CO on the model catalyst 9-hydroxyphenal-1-one(HPHN) CQDs with known structure.Our theoretical calculations reveal that the rate-determining step is COOH·formation,which is closely related to the proton and electron transfer induced by hydrogen bonding in the excited state.According to the calculated volcano plot,the solution we proposed is addition Zn^(2+) ions.The active center changed from the hydroxyl oxygen atom to the Zn atom and the barrier of the COOH·formation step is noticeably decreased when Zn^(2+) ions are added.It is further confirmed by the experimental data that the activity of CO2 reduction increases 2.9 times when Zn^(2+) ions are added.
文摘To avoid pollution of generator exhaust port after the ship docked, the use of shore power supply is developing direction of port. And the shore power grounding method and related standards needed to be carried out. According to developing status of foreign medium voltage ship and characteristics of navy shipboard power supply, this paper presents a shore power supply network structure and its grounding method. The simulation results show the power supply network structure can effectively suppress the single-phase intermittent ground fault on the system to produce the harm.
文摘The pots discovered in Inner Mongolia and Hebei Province are huge with a maximum diameter of 9 m and a depth of 3.5 m, singular in shape,caused by weathering and wind erosion and have certain direction. They are a kind of typical climatic geomorphology. This
基金Supported by National Natural Science Foundation of China 51707014in part by Scientific Research Fund of Hunan Provincial Education Department 17C0040+1 种基金in part by Key Laboratory of Renewable Energy Electric-Technology of Hunan Province 2017ZNDL005in part by Open Research Project of the State Key Laboratory of Industrial Control Technology(Zhejiang University)(ICT170316).
文摘The series voltage source converter(SVSC)is widely used in the power electronic equipment,such as series active power filter,dynamic voltage restorer,unified power flow controller and so on.However,while the SVSC is more vulnerable to the impact of fault current,its applications are increasing,bringing huge challenges to the safe operation of the grid.In recent years,the topology and control strategy of the series voltage source converter with fault current limiting(SVSC-FCL)are a research hotspot.In this paper,it suggests classifying SVSC-FCL based SVSC into two groups:the control scheme optimization group and the existing topology improvement group.The research challenges and perspectives of the SVSC-FCL are introduced in detail.This paper aims to illustrate current research progress on SVSC-FCL and enrich the available pool of the multi-functional power electronic equipment.
基金National Key R&D Program of China(2018YFB1500102)National Natural Science Foundation of China(61974063,U21A2076)+3 种基金Natural Science Foundation of Jiangsu Province(BK20202008,BK20190315)Fundamental Research Funds for the Central Universities(0213/14380206,0205/14380252)Frontiers Science Center for Critical Earth Material Cycling Fund(DLTD2109)Program for Innovative Talents and Entrepreneur in Jiangsu。
文摘Bifacial monolithic all-perovskite tandem solar cells have the promise of delivering higher output power density by inheriting the advantages of both tandem and bifacial architectures simultaneously.Herein,we demonstrate,for the first time,the bifacial monolithic all-perovskite tandem solar cells and reveal their output power potential.The bifacial tandems are realized by replacing the rear metal electrodes of monofacial tandems with transparent conduction oxide electrodes.Bandgap engineering is deployed to achieve current matching under various rear illumination conditions.The bifacial tandems show a high output power density of 28.51 mW cm−2 under a realistic rear illumination(30 mW cm−2).Further energy yield calculation shows substantial energy yield gain for bifacial tandems compared with the monofacial tandems under various ground albedo for different climatic conditions.This work provides a new device architecture for higher output power for all-perovskite tandem solar cells under real-world conditions.
文摘Approximately 7000 m^3 of aged refuse （AR） with a placement of over eight years was excavated from Shanghai Refuse Landfill, the largest landfill in China, and used for the construction of a two-stage bioreactor （AR biofilter） media for the biological treatment of 100 m3 of refuse landfill leachate. It was found that over 64% of COD, 96.9%-99.8% of NH4^＋-N, and 95.8%-99.8% of BOD5 could be removed by the AR biofilter, when the leachate with initial COD, BOD5, and NH4^＋-N concentrations were 986-4128 mg/L, 264--959 mg/L,m and 538-1583 mg/L, respectively. The corresponding concentrations in the effluent were reduced to below 30（000 mg/L, 2-12 mg/L, and 10-20 mg/L, respectively. The effluent was clear and pale yellow with suspended solid below 150 mg/L and color below 150 Pt/Co degree. Meanwhile, the total nitrogen removal was only 49%-63%, indicating a relative poor denitrification capacity of AR biofilter. The effluent pH was neutral and the population of Escherichia coli was less than 10^-1 CFU/mL. Hence, it was considered that the demonstration project can work well for the effective treatment of leachate.
