P-induced electron transfer interaction for enhanced selective hydrogenation rearrangement of furfural to cyclopentanone

Optimizing the intrinsic activity of non-noble metal by precisely tailoring electronic structure offers an appealing way to construct cost-effective catalysts for selective biomass valorization.Herein,we reported a P-doping bifunctional catalyst(Ni-P/mSiO_(2))that achieved 96.6%yield for the hydrogenation rearrangement of furfural to cyclopentanone at mild conditions(1 MPaH_(2),150°C).The turnover frequency of Ni-P/mSiO_(2)was 411.9 h^(-1),which was 3.2-fold than that of Ni/mSiO_(2)(127.2 h^(-1)).Detailed characterizations and differential charge density calculations revealed that the electron-deficient Niδ+species were generated by the electron transfer from Ni to P,which promoted the ring rearrangement reaction.Density functional theory calculations illustrated that the presence of P atoms endowed furfural tilted adsorb on the Ni surface by the C=O group and facilitated the desorption of cyclopentanone.This work unraveled the connection between the localized electronic structures and the catalytic properties,so as to provide a promising reference for designing advanced catalysts for biomass valorization.

A Survey on Smart Collaborative Identifier Networks

The current Internet architecture was designed on the basis of a triple bindings model, which could meet the needs of the early Internet. However, with the tremendous growth of the Internet and the continuous innovations of applications, the triple bindings(namely, control/data binding, resource/location binding and user/network binding) have given rise to many problems for the Internet, such as scalability, mobility, and security. In order to solve these problems, many network techniques have been developed. Besides, novel future Internet architectures including Information-Centric Networks and Software-Defined Networks have emerged. However, these architectures only partially decouple the triple bindings. To completely separate the triple bindings, Smart Collaborative Identifier Networks(SINET) is proposed. There have been many research efforts on SINET, which built the foundation of SINET being a promising future Internet. In this paper, we comprehensively introduce SINET and these related research works. We start by introducing the motivation for SINET, explain its fundamental concepts and how it can make a difference. Next, we present in details the design principles of every layer in SINET, explaining how it can decouple the triple bindings and solve the problems of the current Internet. Finally, we discuss the state-of-theart challenges in SINET. We investigate the ongoing research works and commercial products in SINET, with aspects such as scalability, mobility, security and reliability.

Degree-Based Probabilistic Caching in Content-Centric Networking

Content-Centric Networking is a novel future network architecture that attracts increasing research interests in recent years. In-network caching has been regarded as a prominent feature of Content-Centric Networking since it is able to reduce the network traffic, alleviate the server bottleneck and decrease the user access latency. However, the CCN default caching scheme results in a high caching redundancy, causing an urgent need for an efficient caching scheme. To address this issue, we propose a novel implicit cooperative caching scheme to efficiently reduce the caching redundancy and improve the cache resources utilization. The simulation results show that our design achieves a higher hit ratio and a shorter cache hit distance in comparison with the other typical caching schemes.

Overall-Transparent Dynamic Identifier-Mapping Mechanism Against Scanning and Worm Propagation in the SINET

Static assignment of IP addresses or identifiers can be exploited by an adversary to attack a network. However, existing dynamic IP address assignment approaches suffer from two limitations, namely: participation of terminals in the assignment and inadequate network server management. Thus, in this paper, we propose an Overall-transparent Dynamic Identifier-mapping Mechanism(ODIM) to manage the identifier of network nodes to defend against scanning and worm propagation in the Smart Identifier NETwork(SINET). We establish the selection and allocation constraints, and present selection and allocation algorithms to determine the constraints. The non-repetition probability and cover cycle allow us to evaluate the defense efficiency against scanning. We propose the probability for routing identifiers and derive the defense efficiency of ODIM against worm propagation. Simulation results and theoretical analysis show that the proposed method effectively reduces the detection probability of Routing IDentifiers(RIDs) and thus improves defense capabilities against worm propagation.

Networking Automation and Intelligence:A New Era of Network Innovation

The origin of the Internet can be traced back to the late 1960s.As the progenitor of the Internet,the Advanced Research Projects Agency Network(ARPANET)was the first wide-area packetswitching network,with the main goal of enabling access to remote computers and exchanging data among several authorized computers.Over the latest decade,the Internet has achieved massive development.

Wireless Body Area Networks for Pervasive Healthcare and Smart Environments

Wireless body area networks （WBANs） use RF communication for interconnection of tiny sensor nodes located in, on, or in close prox- imity to the human body. A WBAN enables physiological signals, physical activity, and body position to be continuously monitored.

Whistle signal variations among three Indo-Pacific humpback dolphin populations in the South China Sea:a combined effect of the Qiongzhou Strait’s geographical barrier function and local ambient noise?

Geographic variations in the dolphin whistles could be useful in assessing association and isolation among populations.Whistle of free-ranging Indo-Pacific humpback dolphins(Sousa chinensis)among the Pearl River Estuary(PRE),Leizhou Bei(LZB)and Sanniang Bay(SNB)populations were investigated.A total of 2850 whistles with legible fundamental contour were extracted and 15 acoustic parameters were measured.Contrary to SNB,PRE and LZB had the same relative proportion of tonal type compositions with flat and sine representing the most frequent types.The generalized linear model analysis showed significant acoustic difference among populations and tonal types.All frequency parameters in SNB were significantly higher than those in PRE and LZB,where no significant variation was observed in most of the parameters either at the population level or within each tonal type.Canonical discriminant functions analysis showed a smaller difference between PRE and LZB than between PRE and SNB and between LZB and SNB.Compared with previous recordings,recent recordings demonstrated a consistent pattern of becoming higher in whistle frequency parameters in both LZB and SNB populations,suggesting that noise pollution in LZB and SNB increasing with time according to the acoustic niche hypothesis.Dolphin whistle’s geographic variations could be shaped by the combined function of the geographical barrier function of the Qiongzhou strait and local ambient noise.Considering the isolated condition and the relatively smaller population size of the humpback dolphin in the SNB,more effective and proactive conservation actions should be taken to prevent the extinction of small populations.