Ta As,the first experimentally discovered Weyl semimetal material,has attracted a lot of attention due to its high carrier mobility,high anisotropy,nonmagnetic properties and strong interaction with light.These make i...Ta As,the first experimentally discovered Weyl semimetal material,has attracted a lot of attention due to its high carrier mobility,high anisotropy,nonmagnetic properties and strong interaction with light.These make it an ideal candidate for the study of Weyl fermions and applications in quantum computation,thermoelectric devices,and photodetection.For further basic physics studies and potential applications,large-size and high-quality Ta As films are urgently needed.However,it is difficult to grow As-stoichiometry Ta As films due to the volatilization of As during the growth.To solve this problem,we attempted to grow Ta As films on different substrates using targets with different As stoichiometric ratios via pulsed laser deposition(PLD).In this work,we found that partial As ions of the Ga As substrate are likely to diffuse into the Ta As films during growth,which was preliminarily confirmed by structural characterization,surface topography and composition analysis.As a result,the As content in the Ta As film was improved and the Ta As phase was achieved.Our work presents an effective method for the fabrication of Ta As films using PLD,enabling possible use of the Weyl semimetal film for functional devices.展开更多
The k·p method is significant in condensed matter physics for the compact and analytical Hamiltonian.In the presence of magnetic field,it is described by the effective Zeeman's coupling Hamiltonian with Land&...The k·p method is significant in condensed matter physics for the compact and analytical Hamiltonian.In the presence of magnetic field,it is described by the effective Zeeman's coupling Hamiltonian with Landég-factors.Here,we develop an open-source package VASP2KP(including two parts:vasp2mat and mat2kp)to compute k·p parameters and Landég-factors directly from the wavefunctions provided by the density functional theory(DFT)as implemented in Vienna ab initio Simulation Package(VASP).First,we develop a VASP patch vasp2mat to compute matrix representations of the generalized momentum operatorπ=p+1/2mc^(2)[s×■V(r)],spin operator s,time reversal operatorT,and crystalline symmetry operatorsR on the DFT wavefunctions.Second,we develop a python code mat2kp to obtain the unitary transformation U that rotates the degenerate DFT basis towards the standard basis,and then automatically compute the k·p parameters and g-factors.The theory and the methodology behind VASP2KP are described in detail.The matrix elements of the operators are derived comprehensively and computed correctly within the projector augmented wave method.We apply this package to some materials,e.g.,Bi2Se3,Na3Bi,Te,InAs and 1H-TMD monolayers.The obtained effective model's dispersions are in good agreement with the DFT data around the specific wave vector,and the g-factors are consistent with experimental data.The VASP2KP package is available at https://github.com/zjwang11/VASP2KP.展开更多
One of the greatest triumph of condensed matter physics in the past ten years is the classification of materials by the principle of topology.The existence of topological protected dissipationless surface state makes ...One of the greatest triumph of condensed matter physics in the past ten years is the classification of materials by the principle of topology.The existence of topological protected dissipationless surface state makes topological insulators great potential for applications and hotly studied.However,compared with the prosperity of strong topological insulators,theoretical predicted candidate materials and experimental confirmation of weak topological insulators(WTIs) are both extremely rare.By combining systematic first-principles calculation and angle-resolved photoemission spectroscopy measurements,we have studied the electronic structure of the dark surface of the WTI candidate Zintl Ba_(3)Cd_(2)Sb_(4)and another related material Ba_(3)Cd_(2)As_(4).The existence of two Dirac surface states on specific side surfaces predicted by theoretical calculations and the observed two band inversions in the Brillouin zone give strong evidence to prove that the Ba_(3)Cd_(2)Sb_(4)is a WTI.The spectroscopic characterization of this Zintl Ba_(3)Cd_(2)N_(4)(N = As and Sb) family materials will facilitate applications of their novel topological properties.展开更多
High resolution angle resolved photoemission measurements and band structure calculations are carried out to study the electronic structure of BaMnSb_(2). All the observed bands are nearly linear that extend to a wide...High resolution angle resolved photoemission measurements and band structure calculations are carried out to study the electronic structure of BaMnSb_(2). All the observed bands are nearly linear that extend to a wide energy range. The measured Fermi surface mainly consists of one hole pocket around Γ and a strong spot at Y which are formed from the crossing points of the linear bands. The measured electronic structure of BaMnSb_(2) is unusual and deviates strongly from the band structure calculations. These results will stimulate further efforts to theoretically understand the electronic structure of BaMnSb_(2) and search for novel properties in this Dirac material.展开更多
We report the magnetoresistance(MR),de Haas-van Alphen(dHvA) oscillations and the electronic structures of single-crystal PtGa.The large unsaturated MR is observed with the magnetic field B ‖ [111].Evident dHvA oscil...We report the magnetoresistance(MR),de Haas-van Alphen(dHvA) oscillations and the electronic structures of single-crystal PtGa.The large unsaturated MR is observed with the magnetic field B ‖ [111].Evident dHvA oscillations with the B ‖ [001] configuration are observed,from which twelve fundamental frequencies are extracted and the spin-orbit coupling(SOC) induced band splitting is revealed.The light cyclotron effective masses are extracted from the fitting by the thermal damping term of the Lifshitz-Kosevich formula.Combining with the calculated frequencies from the first-principles calculations,the dHvA frequencies F1/F3 and F11/F12are confirmed to originate from the electron pockets at F and R,respectively.The first-principles calculations also reveal the existence of spin-3/2 Rarita-Schwinger-Weyl fermions and time-reversal doubling of the spin-1 excitation at Γ and R with large Chern numbers of ±4 when SOC is included.展开更多
The exploration of topological Dirac semimetals with intrinsic superconductivity can be a most plausible way to discover topological superconductors.We propose that type-II Dirac semimetal states exist in the band str...The exploration of topological Dirac semimetals with intrinsic superconductivity can be a most plausible way to discover topological superconductors.We propose that type-II Dirac semimetal states exist in the band structure of TaC,a well-known s-wave superconductor,by using the first-principles calculations and theκ· p effective model.The tilted gapless Dirac cones,which are composed of Ta d and C p orbitals and are protected by C4v symmetry,are found to be below the Fermi level.The bands from Ta d orbitals are greatly coupled with the acoustic modes around the zone boundary,indicating their significant contribution to the superconductivity.The relatively high transition temperature^10.5 K is estimated to be consistent with the experimental data.To bring the type-II Dirac points close to chemical potential,hole doping is needed.This seems to decrease the transition temperature a lot,making the realization of topological superconductivity impossible.展开更多
Kagome magnets with diverse topological quantum responses are crucial for next-generation topological engineering.The anisotropic magnetism and band evolution induced by ferromagnetic phase transition(FMPT)is reported...Kagome magnets with diverse topological quantum responses are crucial for next-generation topological engineering.The anisotropic magnetism and band evolution induced by ferromagnetic phase transition(FMPT)is reported in a newly discovered titanium-based kagome ferromagnet Sm Ti3Bi4,which features a distorted Ti kagome lattice and Sm atomic zig-zag chains.Temperature-dependent resistivity,heat capacity,and magnetic susceptibility reveal a ferromagnetic ordering temperature Tc of23.2 K.A large magnetic anisotropy,observed by applying the magnetic field along three crystallographic axes,identifies the b axis as the easy axis.Angle-resolved photoemission spectroscopy with first-principles calculations unveils the characteristic kagome motif,including the Dirac point at the Fermi level and multiple van Hove singularities.Notably,a band splitting and gap closing attributed to FMPT is observed,originating from the exchange coupling between Sm 4 f local moments and itinerant electrons of the kagome Ti atoms,as well as the time-reversal symmetry breaking induced by the long-range ferromagnetic order.Considering the large in-plane magnetization and the evolution of electronic structure under the influence of ferromagnetic ordering,such materials promise to be a new platform for exploring the intricate electronic properties and magnetic phases based on the kagome lattice.展开更多
Revealing the role of Coulomb interaction in topological semimetals with Dirac/Weyl-like band dispersion shapes a new frontier in condensed matter physics.Topological node-line semimetals(TNLSMs),anticipated as a fert...Revealing the role of Coulomb interaction in topological semimetals with Dirac/Weyl-like band dispersion shapes a new frontier in condensed matter physics.Topological node-line semimetals(TNLSMs),anticipated as a fertile ground for exploring electronic correlation effects due to the anisotropy associated with their node-line structure,have recently attracted considerable attention.In this study,we report an experimental observation for correlation effects in TNLSMs realized by black phosphorus(BP)under hydrostatic pressure.By performing a combination of nuclear magnetic resonance measurements and band calculations on compressed BP,a magnetic-field-induced electronic instability of Weyl-like fermions is identified under an external magnetic field parallel to the so-called nodal ring in the reciprocal space.Anomalous spin fluctuations serving as the fingerprint of electronic instability are observed at low temperatures,and they are observed to maximize at approximately 1.0 GPa.This study presents compressed BP as a realistic material platform for exploring the rich physics in strongly coupled Weyl-like fermions.展开更多
Both the intrinsic anisotropic optical materials and fullerene-assembled 2D materials have attracted much interest in fundamental science and potential applications.The synthesis of a monolayer(ML)fullerene makes the ...Both the intrinsic anisotropic optical materials and fullerene-assembled 2D materials have attracted much interest in fundamental science and potential applications.The synthesis of a monolayer(ML)fullerene makes the combination of these two features plausible.In this work,using first-principles calculations,we systematically study the electronic structure and optical properties of quasi-hexagonal phase(qHP)ML and quasi-tetragonal phase(qTP)ML fullerenes.The calculations of q HP ML show that it is a semiconductor with small anisotropic optical absorption,which agrees with the recent experimental measurements.However,the results for qTP ML reveal that it is a semimetal with highly in-plane anisotropic absorption.The dichroic ratio,namely the absorption ratio of x-and y-polarized lightα_(xx)/α_(yy),is around 12 at photon energy of 0.29 eV.This anisotropy is much more pronounced when the photon energy is between 0.7 and 1.4 eV,whereα_(xx)becomes nearly zero whileα_(yy)is more than two orders of magnitude larger.This indicates qTP ML as a candidate for long-pursuit lossless metal and a potential material for atomically thin polarizer.We hope this will stimulate further experimental eforts in the study of qTP ML and other fullerene-assembled 2D materials.展开更多
The search for new materials with Dirac points has been a fascinating subject of condensed matter physics.Here we first report the growth and band structure of HfGe_(0.92)Te single crystals featuring three different t...The search for new materials with Dirac points has been a fascinating subject of condensed matter physics.Here we first report the growth and band structure of HfGe_(0.92)Te single crystals featuring three different types of Dirac points.HfGe_(0.92)Te crystallizes in a nonsymmorphic tetragonal space group P4/nmm(No.129),having a square Ge-atom plane with vacancies of about 8%.Using angle-resolved photoemission spectroscopy(ARPES),the Dirac nodal line composed of conventional Dirac points vulnerable to spin-orbit coupling(SOC)is observed,accompanied by robust Dirac points protected by the nonsymmorphic symmetry against SOC and vacancies.In particular,spin-orbit Dirac points(SDPs)originating from the surface formed under significant SOC could exist based on ARPES and calculations.Quasi-two-dimensional(quasi-2D)characteristics are confirmed by angular-resolved magnetoresistance.HfGe_(0.92)Te bulk crystals can be easily exfoliated to flakes with a thickness of approximately 5 nm for the quasi-2D nature.Thus,HfGe_(0.92)Te provides a good platform to explore exotic topological phases or topological properties with three different types of Dirac points,which is a potential candidate to achieve novel 2D SDPs.展开更多
Two-dimensional(2D)materials have gained lots of attention due to the potential applications.In this work,we propose that based on first-principles calculations,the(2×2)patterned PtTe_(2)monolayer with kagome lat...Two-dimensional(2D)materials have gained lots of attention due to the potential applications.In this work,we propose that based on first-principles calculations,the(2×2)patterned PtTe_(2)monolayer with kagome lattice formed by the well-ordered Te vacancy(PtTe_(1.75))hosts large and tunable spin Hall conductivity(SHC)and excellent hydrogen evolution reaction(HER)activity.The unconventional nature relies on the A1@1b band representation of the highest valence band without spin–orbit coupling(SOC).The large SHC comes from the Rashba SOC in the noncentrosymmetric structure induced by the Te vacancy.Even though it has a metallic SOC band structure,theℤ_(2)invariant is well defined because of the existence of the direct bandgap and is computed to be nontrivial.The calculated SHC is as large as 1.25×10^(3)h/e(Ωcm)^(−1)at the Fermi level(EF).By tuning the chemical potential from EF−0.3 to EF+0.3 eV,it varies rapidly and monotonically from−1.2×10^(3)to 3.1×10^(3)h/e(Ωcm)^(−1)In addition,we also find that the Te vacancy in the patterned monolayer can induce excellent HER activity.Our results not only offer a new idea to search 2D materials with large SHC,i.e.,by introducing inversion–symmetry breaking vacancies in large SOC systems,but also provide a feasible system with tunable SHC(by applying gate voltage)and excellent HER activity.展开更多
Topological semimetals are newly discovered states of quantum matter, which have extended the con- cept of topological states from insulators to metals and attracted great research interest in recent years. In general...Topological semimetals are newly discovered states of quantum matter, which have extended the con- cept of topological states from insulators to metals and attracted great research interest in recent years. In general, there are three kinds of topological semimetals, namely Dirac semimetals, Weyl semimet- als, and nodal line semimetals. Nodal line semimetals can be considered as precursor states for other topological states. For example, starting from such nodal line states, the nodal line structure might evolve into Weyl points, convert into Dirac points, or become a topological insulator by introducing the spin-orbit coupling (SOC) or mass term. In this review paper, we introduce theoretical materials that show the nodal line semimetal state, including the all-carbon Mackay-Terrones crystal (MTC), anti-perovskite Cu3PdN, pressed black phosphorus, and the CaP3 family of materials, and we present the design principles for obtaining such novel states of matter.展开更多
Te search for artifcial structure with tunable topological properties is an interesting research direction of today’s topological physics.Here,we introduce a scheme to realize topological nodal states with a three-di...Te search for artifcial structure with tunable topological properties is an interesting research direction of today’s topological physics.Here,we introduce a scheme to realize topological nodal states with a three-dimensional periodic inductor-capacitor(LC)circuit lattice,where the topological nodal line state and Weyl state can be achieved by tuning the parameters of inductors and capacitors.A tight-binding-like model is derived to analyze the topological properties of the LC circuit lattice.Te key characters of the topological states,such as the drumhead-like surface bands for nodal line state and the Fermi arc-like surface bands for Weyl state,are found in these systems.We also show that the Weyl points are stable with the fabrication errors of electric devices.展开更多
Recently Guo et al.[1]have performed a systematic simulation on the high-pressure phases of the first experimentally available Weyl semimetals TaAs family.Through such a cheap but powerful technique,they theoretically...Recently Guo et al.[1]have performed a systematic simulation on the high-pressure phases of the first experimentally available Weyl semimetals TaAs family.Through such a cheap but powerful technique,they theoretically found a展开更多
Recently,a couple of Science papers[1,2]have reported the existence of Fermi arcs on the surface of a ferromagnetic compound,namely Co3Sn2S2,which was first proposed to be a magnetic Weyl semimetal(WSM)according to th...Recently,a couple of Science papers[1,2]have reported the existence of Fermi arcs on the surface of a ferromagnetic compound,namely Co3Sn2S2,which was first proposed to be a magnetic Weyl semimetal(WSM)according to the giant anomalous Hall effect[3,4].The new evidence is in agreement with this proposal,suggesting that the magnetic WSM has been found after a nearly eight year research[5,6].This finding,along with the discovery of nonmagnetic WSMs of TaAs family in 2015[7,8],has completed the WSM classification.In comparison with the nonmagnetic WSM,magnetic WSM has a long-range magnetic order coupled with Weyl nodes.Furthermore,it offers more ways to control and explore the properties of WSMs.展开更多
Node line band-touchings protected by mirror symmetry(named as m-NLs),the product of inversion and time reversal symmetry S=PT(named as s-NLs),or nonsymmorphic symmetry are nontrivial topological objects of topologica...Node line band-touchings protected by mirror symmetry(named as m-NLs),the product of inversion and time reversal symmetry S=PT(named as s-NLs),or nonsymmorphic symmetry are nontrivial topological objects of topological semimetals in the Brillouin Zone.In this work,we screened a family of MgSrSi-type crystals using first principles calculations,and discovered that more than 70 members are node-line semimetals.A new type of multi-loop structure was found in AsRhTi that a s-NL touches robustly with a m-NL at some“nexus point”,and in the meanwhile a second m-NL crosses with the s-NL to form a Hopf-link.Unlike the previously proposed Hopf-link formed by two s-NLs or two m-NLs,a Hopf-link formed by a s-NL and a m-NL requires a minimal three-band model to characterize its essential electronic structure.The associated topological surface states on different surfaces of AsRhTi crystal were also obtained.Even more complicated and exotic multi-loop structure of NLs were predicted in AsFeNb and PNiNb.Our work may shed light on search for exotic multi-loop node-line semimetals in real materials.展开更多
Based on the first-principles calculations and experimental measurements,we report that the hexagonal phase of ternary transition metal pnictides TT’X(T=Zr,Hf;T’=Ru;X=P,As),which are well-known noncentrosymmetric su...Based on the first-principles calculations and experimental measurements,we report that the hexagonal phase of ternary transition metal pnictides TT’X(T=Zr,Hf;T’=Ru;X=P,As),which are well-known noncentrosymmetric superconductors with relatively high transition temperatures,host nontrivial bulk topology.Before the superconducting phase transition,we find that HfRuP belongs to a Weyl semimetal phase with 12 pairs of type-II Weyl points,while ZrRuAs,ZrRuP and HfRuAs belong to a topological crystalline insulating phase with trivial Fu-Kane Z_(2) indices but nontrivial mirror Chern numbers.High-quality single crystal samples of the noncentrosymmetric superconductors with these two different topological states have been obtained and the superconductivity is verified experimentally.The wide-range band structures of ZrRuAs have been identified by ARPES and reproduced by theoretical calculations.Combined with intrinsic superconductivity,the nontrivial topology of the normal state may generate unconventional superconductivity in both bulk and surfaces.Our findings could largely inspire the experimental searching for possible topological superconductivity in these compounds.展开更多
基金Project supported by the National Key Research and Development Program of China(Grant No.2021YFA0718700)the National Natural Science Foundation of China(Grant No.12174347)+1 种基金the Synergetic Extreme Condition User Facility(SECUF)the Center for Materials Genome。
文摘Ta As,the first experimentally discovered Weyl semimetal material,has attracted a lot of attention due to its high carrier mobility,high anisotropy,nonmagnetic properties and strong interaction with light.These make it an ideal candidate for the study of Weyl fermions and applications in quantum computation,thermoelectric devices,and photodetection.For further basic physics studies and potential applications,large-size and high-quality Ta As films are urgently needed.However,it is difficult to grow As-stoichiometry Ta As films due to the volatilization of As during the growth.To solve this problem,we attempted to grow Ta As films on different substrates using targets with different As stoichiometric ratios via pulsed laser deposition(PLD).In this work,we found that partial As ions of the Ga As substrate are likely to diffuse into the Ta As films during growth,which was preliminarily confirmed by structural characterization,surface topography and composition analysis.As a result,the As content in the Ta As film was improved and the Ta As phase was achieved.Our work presents an effective method for the fabrication of Ta As films using PLD,enabling possible use of the Weyl semimetal film for functional devices.
基金supported by the National Key R&D Program of Chain(Grant No.2022YFA1403800)the National Natural Science Foundation of China(Grant Nos.11974395,12188101,11925408,12274436,and 11921004)+5 种基金the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDB33000000)the Center for Materials Genomesupported by the Innovation Program for Quantum Science and Technology(Grant No.2021ZD0302403)the National Natural Science Foundation of China(Grant No.12274005)the National Key Research and Development Program of China(Grant No.2021YFA1401900)supported by the Informatization Plan of the Chinese Academy of Sciences(Grant No.CASWX2021SF0102)。
文摘The k·p method is significant in condensed matter physics for the compact and analytical Hamiltonian.In the presence of magnetic field,it is described by the effective Zeeman's coupling Hamiltonian with Landég-factors.Here,we develop an open-source package VASP2KP(including two parts:vasp2mat and mat2kp)to compute k·p parameters and Landég-factors directly from the wavefunctions provided by the density functional theory(DFT)as implemented in Vienna ab initio Simulation Package(VASP).First,we develop a VASP patch vasp2mat to compute matrix representations of the generalized momentum operatorπ=p+1/2mc^(2)[s×■V(r)],spin operator s,time reversal operatorT,and crystalline symmetry operatorsR on the DFT wavefunctions.Second,we develop a python code mat2kp to obtain the unitary transformation U that rotates the degenerate DFT basis towards the standard basis,and then automatically compute the k·p parameters and g-factors.The theory and the methodology behind VASP2KP are described in detail.The matrix elements of the operators are derived comprehensively and computed correctly within the projector augmented wave method.We apply this package to some materials,e.g.,Bi2Se3,Na3Bi,Te,InAs and 1H-TMD monolayers.The obtained effective model's dispersions are in good agreement with the DFT data around the specific wave vector,and the g-factors are consistent with experimental data.The VASP2KP package is available at https://github.com/zjwang11/VASP2KP.
基金supported by the National Key R&D Program of China(Grant Nos.2022YFA1403800,2018YFA0305700,and 2019YFA0308602)the Chinese Academy of Sciences(Grant Nos.QYZDB-SSW-SLH043,XDB33000000,and XDB28000000)+2 种基金the National Natural Science Foundation of China (Grant Nos.U22A600018,U1832202,12074425,11874422,11925408,11921004,and 12188101)the Informatization Plan of Chinese Academy of Sciences (Grant No.CAS-WX2021SF-0102)the Synergetic Extreme Condition User Facility (SECUF)。
文摘One of the greatest triumph of condensed matter physics in the past ten years is the classification of materials by the principle of topology.The existence of topological protected dissipationless surface state makes topological insulators great potential for applications and hotly studied.However,compared with the prosperity of strong topological insulators,theoretical predicted candidate materials and experimental confirmation of weak topological insulators(WTIs) are both extremely rare.By combining systematic first-principles calculation and angle-resolved photoemission spectroscopy measurements,we have studied the electronic structure of the dark surface of the WTI candidate Zintl Ba_(3)Cd_(2)Sb_(4)and another related material Ba_(3)Cd_(2)As_(4).The existence of two Dirac surface states on specific side surfaces predicted by theoretical calculations and the observed two band inversions in the Brillouin zone give strong evidence to prove that the Ba_(3)Cd_(2)Sb_(4)is a WTI.The spectroscopic characterization of this Zintl Ba_(3)Cd_(2)N_(4)(N = As and Sb) family materials will facilitate applications of their novel topological properties.
基金supported by the National Key Research and Development Program of China (Grant Nos. 2016YFA0300600, 2018YFA0305602, 2016YFA0300300,2017YFA0302900)the National Natural Science Foundation of China (Grant Nos. 11974404, 11888101, 11922414, and 11404175)+8 种基金the Strategic Priority Research Program (B) of the Chinese Academy of Sciences (Grant Nos. XDB33000000 and XDB25000000)the Youth Innovation Promotion Association of CAS (Grant No. 2017013)the Natural Science Foundation of Henan Province,China (Grant Nos. 182300410274 and 202300410296)The theoretical calculations are supported by the National Natural Science Foundation of China (Grant Nos. 11674369, 11865019, and 11925408)the Beijing Natural Science Foundation,China (Grant No. Z180008)Beijing Municipal Science and Technology Commission,China (Grant No. Z191100007219013)the National Key Research and Development Program of China (Grant Nos. 2016YFA0300600 and 2018YFA0305700)the K. C. Wong Education Foundation (Grant No. GJTD-2018-01)the Strategic Priority Research Program of Chinese Academy of Sciences (Grant No. XDB33000000)。
文摘High resolution angle resolved photoemission measurements and band structure calculations are carried out to study the electronic structure of BaMnSb_(2). All the observed bands are nearly linear that extend to a wide energy range. The measured Fermi surface mainly consists of one hole pocket around Γ and a strong spot at Y which are formed from the crossing points of the linear bands. The measured electronic structure of BaMnSb_(2) is unusual and deviates strongly from the band structure calculations. These results will stimulate further efforts to theoretically understand the electronic structure of BaMnSb_(2) and search for novel properties in this Dirac material.
基金Supported by the National Key Research and Development Program of China(Grant Nos.2019YFA0308602, 2018YFA0305700 and 2016YFA0300600)the National Natural Science Foundation of China(Grant Nos.11874422 and 11574391)+6 种基金the Fundamental Research Funds for the Central Universitiesthe Research Funds of Renmin University of China(Grant Nos.19XNLG18 and 18 XNLG14)the Chinese Academy of Sciences(Grant No.XDB28000000)the Science Challenge Project(Grant No.TZ2016004)the K.C.Wong Education Foundation(Grant No.GJTD-2018-01)the Beijing Municipal Science&Technology Commission(Grant No.Z181100004218001)the Beijing Natural Science Foundation(Grant No.Z180008)
文摘We report the magnetoresistance(MR),de Haas-van Alphen(dHvA) oscillations and the electronic structures of single-crystal PtGa.The large unsaturated MR is observed with the magnetic field B ‖ [111].Evident dHvA oscillations with the B ‖ [001] configuration are observed,from which twelve fundamental frequencies are extracted and the spin-orbit coupling(SOC) induced band splitting is revealed.The light cyclotron effective masses are extracted from the fitting by the thermal damping term of the Lifshitz-Kosevich formula.Combining with the calculated frequencies from the first-principles calculations,the dHvA frequencies F1/F3 and F11/F12are confirmed to originate from the electron pockets at F and R,respectively.The first-principles calculations also reveal the existence of spin-3/2 Rarita-Schwinger-Weyl fermions and time-reversal doubling of the spin-1 excitation at Γ and R with large Chern numbers of ±4 when SOC is included.
基金Supported by the National Natural Science Foundation of China(Grant Nos.11974076,11674369 and 11925408)the Natural Science Foundation of Fujian Province of China(Grant No.2018J06001)+4 种基金the Beijing Natural Science Foundation(Grant No.Z180008)Beijing Municipal Science and Technology Commission(Grant No.Z191100007219013)National Key Research and Development Program of China(Grant Nos.2016YFA0300600 and 2018YFA0305700)the K.C.Wong Education Foundation(Grant No.GJTD-2018-01)the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDB33000000).
文摘The exploration of topological Dirac semimetals with intrinsic superconductivity can be a most plausible way to discover topological superconductors.We propose that type-II Dirac semimetal states exist in the band structure of TaC,a well-known s-wave superconductor,by using the first-principles calculations and theκ· p effective model.The tilted gapless Dirac cones,which are composed of Ta d and C p orbitals and are protected by C4v symmetry,are found to be below the Fermi level.The bands from Ta d orbitals are greatly coupled with the acoustic modes around the zone boundary,indicating their significant contribution to the superconductivity.The relatively high transition temperature^10.5 K is estimated to be consistent with the experimental data.To bring the type-II Dirac points close to chemical potential,hole doping is needed.This seems to decrease the transition temperature a lot,making the realization of topological superconductivity impossible.
基金supported by the Synergetic Extreme Condition User Facility(SECUF)the National Key Research and Development Program of China(Grant Nos.2022YFA1403800,2022YFA1403900,and 2018YFE0202600)+3 种基金the National Natural Science Foundation of China(Grant Nos.U22A6005,51832010,11888101,11925408,11921004,and 12188101)the Informatization Plan of the Chinese Academy of Sciences(Grant No.CASWX2021SF-0102)the Strategic Priority Research Program of Chinese Academy of Sciences(Grant Nos.XDB33000000,and XDB28000000)the“Dreamline”beamline of Shanghai Synchrotron Radiation Facility(SSRF)。
文摘Kagome magnets with diverse topological quantum responses are crucial for next-generation topological engineering.The anisotropic magnetism and band evolution induced by ferromagnetic phase transition(FMPT)is reported in a newly discovered titanium-based kagome ferromagnet Sm Ti3Bi4,which features a distorted Ti kagome lattice and Sm atomic zig-zag chains.Temperature-dependent resistivity,heat capacity,and magnetic susceptibility reveal a ferromagnetic ordering temperature Tc of23.2 K.A large magnetic anisotropy,observed by applying the magnetic field along three crystallographic axes,identifies the b axis as the easy axis.Angle-resolved photoemission spectroscopy with first-principles calculations unveils the characteristic kagome motif,including the Dirac point at the Fermi level and multiple van Hove singularities.Notably,a band splitting and gap closing attributed to FMPT is observed,originating from the exchange coupling between Sm 4 f local moments and itinerant electrons of the kagome Ti atoms,as well as the time-reversal symmetry breaking induced by the long-range ferromagnetic order.Considering the large in-plane magnetization and the evolution of electronic structure under the influence of ferromagnetic ordering,such materials promise to be a new platform for exploring the intricate electronic properties and magnetic phases based on the kagome lattice.
基金supported by the National Natural Science Foundation of China(U1832202,11888101,11920101005,12141402,and 12274459)the Chinese Academy of Sciences(QYZDB-SSW-SLH043,XDB33020100,and XDB28000000)+4 种基金the Beijing Municipal Science and Technology Commission(Z171100002017018,and Z200005)the National Key R&D Program of China(2018YFE0202600,2022YFA1403100,and 2022YFA1403800)the Fundamental Research Funds for the Central Universities and Research Funds of Renmin University of China(RUC)(18XNLG14,19XNLG13,19XNLG17,and 20XNH062)the Synergic Extreme Condition User Facility,Beijing,ChinaBeijing National Laboratory for Condensed Matter Physics。
基金supported by the National Key R&D Program of the Ministry of Science and Technology of China(Grant Nos.2017YFA0300201,and 2016YFA0303000)the Anhui Initiative in Quantum Information Technologies(Grant No.AHY160000)+1 种基金the National Natural Science Foundation of China(Grant No.11534010)the Key Research Program of Frontier Sciences,Chinese Academy of Sciences,China(Grant No.QYZDY-SSWSLH021)。
文摘Revealing the role of Coulomb interaction in topological semimetals with Dirac/Weyl-like band dispersion shapes a new frontier in condensed matter physics.Topological node-line semimetals(TNLSMs),anticipated as a fertile ground for exploring electronic correlation effects due to the anisotropy associated with their node-line structure,have recently attracted considerable attention.In this study,we report an experimental observation for correlation effects in TNLSMs realized by black phosphorus(BP)under hydrostatic pressure.By performing a combination of nuclear magnetic resonance measurements and band calculations on compressed BP,a magnetic-field-induced electronic instability of Weyl-like fermions is identified under an external magnetic field parallel to the so-called nodal ring in the reciprocal space.Anomalous spin fluctuations serving as the fingerprint of electronic instability are observed at low temperatures,and they are observed to maximize at approximately 1.0 GPa.This study presents compressed BP as a realistic material platform for exploring the rich physics in strongly coupled Weyl-like fermions.
基金supported by the National Natural Science Foundation of China(Grant Nos.11974076,11925408,11921004,12188101,and11874335)Key Project of Natural Science Foundation of Fujian Province(Grant No.2021J02012)+2 种基金Ministry of Science and Technology of China(Grant Nos.2018YFA0305700,and 2022YFA1403800)Chinese Academy of Sciences(Grant No.XDB33000000)Informatization Plan of Chinese Academy of Sciences(Grant No.CAS-WX2021SF-0102)。
文摘Both the intrinsic anisotropic optical materials and fullerene-assembled 2D materials have attracted much interest in fundamental science and potential applications.The synthesis of a monolayer(ML)fullerene makes the combination of these two features plausible.In this work,using first-principles calculations,we systematically study the electronic structure and optical properties of quasi-hexagonal phase(qHP)ML and quasi-tetragonal phase(qTP)ML fullerenes.The calculations of q HP ML show that it is a semiconductor with small anisotropic optical absorption,which agrees with the recent experimental measurements.However,the results for qTP ML reveal that it is a semimetal with highly in-plane anisotropic absorption.The dichroic ratio,namely the absorption ratio of x-and y-polarized lightα_(xx)/α_(yy),is around 12 at photon energy of 0.29 eV.This anisotropy is much more pronounced when the photon energy is between 0.7 and 1.4 eV,whereα_(xx)becomes nearly zero whileα_(yy)is more than two orders of magnitude larger.This indicates qTP ML as a candidate for long-pursuit lossless metal and a potential material for atomically thin polarizer.We hope this will stimulate further experimental eforts in the study of qTP ML and other fullerene-assembled 2D materials.
基金partially supported by the National Natural Science Foundation of China(Grant Nos.51832010,51902055,11925408,12005251,and 11921004)National Key Research and Development Program of China(Grant Nos.2018YFE0202602,2018YFA0305700,and 2017YFA0302902)。
文摘The search for new materials with Dirac points has been a fascinating subject of condensed matter physics.Here we first report the growth and band structure of HfGe_(0.92)Te single crystals featuring three different types of Dirac points.HfGe_(0.92)Te crystallizes in a nonsymmorphic tetragonal space group P4/nmm(No.129),having a square Ge-atom plane with vacancies of about 8%.Using angle-resolved photoemission spectroscopy(ARPES),the Dirac nodal line composed of conventional Dirac points vulnerable to spin-orbit coupling(SOC)is observed,accompanied by robust Dirac points protected by the nonsymmorphic symmetry against SOC and vacancies.In particular,spin-orbit Dirac points(SDPs)originating from the surface formed under significant SOC could exist based on ARPES and calculations.Quasi-two-dimensional(quasi-2D)characteristics are confirmed by angular-resolved magnetoresistance.HfGe_(0.92)Te bulk crystals can be easily exfoliated to flakes with a thickness of approximately 5 nm for the quasi-2D nature.Thus,HfGe_(0.92)Te provides a good platform to explore exotic topological phases or topological properties with three different types of Dirac points,which is a potential candidate to achieve novel 2D SDPs.
基金the National Natural Science Foundation of China(grant no.12204138,no.11974395,no.12188101,no.52188101,and no.51725103)the Strategic Priority Research Program of Chinese Academy of Sciences(grant no.XDB33000000),and the Center for Materials Genome。
文摘Two-dimensional(2D)materials have gained lots of attention due to the potential applications.In this work,we propose that based on first-principles calculations,the(2×2)patterned PtTe_(2)monolayer with kagome lattice formed by the well-ordered Te vacancy(PtTe_(1.75))hosts large and tunable spin Hall conductivity(SHC)and excellent hydrogen evolution reaction(HER)activity.The unconventional nature relies on the A1@1b band representation of the highest valence band without spin–orbit coupling(SOC).The large SHC comes from the Rashba SOC in the noncentrosymmetric structure induced by the Te vacancy.Even though it has a metallic SOC band structure,theℤ_(2)invariant is well defined because of the existence of the direct bandgap and is computed to be nontrivial.The calculated SHC is as large as 1.25×10^(3)h/e(Ωcm)^(−1)at the Fermi level(EF).By tuning the chemical potential from EF−0.3 to EF+0.3 eV,it varies rapidly and monotonically from−1.2×10^(3)to 3.1×10^(3)h/e(Ωcm)^(−1)In addition,we also find that the Te vacancy in the patterned monolayer can induce excellent HER activity.Our results not only offer a new idea to search 2D materials with large SHC,i.e.,by introducing inversion–symmetry breaking vacancies in large SOC systems,but also provide a feasible system with tunable SHC(by applying gate voltage)and excellent HER activity.
文摘Topological semimetals are newly discovered states of quantum matter, which have extended the con- cept of topological states from insulators to metals and attracted great research interest in recent years. In general, there are three kinds of topological semimetals, namely Dirac semimetals, Weyl semimet- als, and nodal line semimetals. Nodal line semimetals can be considered as precursor states for other topological states. For example, starting from such nodal line states, the nodal line structure might evolve into Weyl points, convert into Dirac points, or become a topological insulator by introducing the spin-orbit coupling (SOC) or mass term. In this review paper, we introduce theoretical materials that show the nodal line semimetal state, including the all-carbon Mackay-Terrones crystal (MTC), anti-perovskite Cu3PdN, pressed black phosphorus, and the CaP3 family of materials, and we present the design principles for obtaining such novel states of matter.
基金Te authors thank Hua Jiang,Yuanyuan Zhao,and Ang Cao for their very helpful discussions.Tis work was supported by the National Key Research and Development Program of China(nos.2017YFA0303402,2017YFA0304700,and 2016YFA0300600)and the National Natural Science Foundation of China(nos.11674077,11422428,11674369,and 11404024)Rui Yu acknowledges funding from the National Tousand Young Talents Program.Te numerical calculations in this work have been done on the supercomputing system in the Supercomputing Center of Wuhan University.
文摘Te search for artifcial structure with tunable topological properties is an interesting research direction of today’s topological physics.Here,we introduce a scheme to realize topological nodal states with a three-dimensional periodic inductor-capacitor(LC)circuit lattice,where the topological nodal line state and Weyl state can be achieved by tuning the parameters of inductors and capacitors.A tight-binding-like model is derived to analyze the topological properties of the LC circuit lattice.Te key characters of the topological states,such as the drumhead-like surface bands for nodal line state and the Fermi arc-like surface bands for Weyl state,are found in these systems.We also show that the Weyl points are stable with the fabrication errors of electric devices.
基金supported by the National Key Research and Development Program of China(Grant No.2016YFA0300600)the National Natural Science Foundation of China(Grant Nos.11674369,and 11422428)the“Strategic Priority Research Program(B)”of the Chinese Academy of Sciences(Grant No.XDB07020100)
文摘Recently Guo et al.[1]have performed a systematic simulation on the high-pressure phases of the first experimentally available Weyl semimetals TaAs family.Through such a cheap but powerful technique,they theoretically found a
基金supported by the National Key Research and Development Program of China(Grant Nos.2016YFA0300600,and 2018YFA0305700)the National Natural Science Foundation of China(Grant No.11674369)the K.C.Wong Education Foundation(Grant No.GJTD-2018-01)
文摘Recently,a couple of Science papers[1,2]have reported the existence of Fermi arcs on the surface of a ferromagnetic compound,namely Co3Sn2S2,which was first proposed to be a magnetic Weyl semimetal(WSM)according to the giant anomalous Hall effect[3,4].The new evidence is in agreement with this proposal,suggesting that the magnetic WSM has been found after a nearly eight year research[5,6].This finding,along with the discovery of nonmagnetic WSMs of TaAs family in 2015[7,8],has completed the WSM classification.In comparison with the nonmagnetic WSM,magnetic WSM has a long-range magnetic order coupled with Weyl nodes.Furthermore,it offers more ways to control and explore the properties of WSMs.
基金The work is supported by National Natural Science Foundation of China(NSFC)(Grants No.11574215,No.11575116,No.11274359,and No.11422428)H.M.W is also supported by the National 973 program of China(Grants No.2018YFA0305700 and No.2013CB921700)the“Strategic Priority Research Program(B)”of the Chinese Academy of Sciences(Grant No.XDB07020100).
文摘Node line band-touchings protected by mirror symmetry(named as m-NLs),the product of inversion and time reversal symmetry S=PT(named as s-NLs),or nonsymmorphic symmetry are nontrivial topological objects of topological semimetals in the Brillouin Zone.In this work,we screened a family of MgSrSi-type crystals using first principles calculations,and discovered that more than 70 members are node-line semimetals.A new type of multi-loop structure was found in AsRhTi that a s-NL touches robustly with a m-NL at some“nexus point”,and in the meanwhile a second m-NL crosses with the s-NL to form a Hopf-link.Unlike the previously proposed Hopf-link formed by two s-NLs or two m-NLs,a Hopf-link formed by a s-NL and a m-NL requires a minimal three-band model to characterize its essential electronic structure.The associated topological surface states on different surfaces of AsRhTi crystal were also obtained.Even more complicated and exotic multi-loop structure of NLs were predicted in AsFeNb and PNiNb.Our work may shed light on search for exotic multi-loop node-line semimetals in real materials.
基金This work was supported by the National Natural Science Foundation of China(11504117,11774399,11622435,U1832202)Beijing Natural Science Foundation(Z180008)+6 种基金the Ministry of Science and Technology of China(2016YFA0300600,2016YFA0401000 and 2018YFA0305700)the Chinese Academy of Sciences(XDB28000000,XDB07000000)the Beijing Municipal Science and Technology Commission(Z181100004218001,Z171100002017018)H.W.acknowledges support from the Science Challenge Project(No.TZ2016004)the K.C.Wong Education Foundation(GJTD-2018-01)Y.S.acknowledges the National Key Research and Development Program of China(No.2017YFA0302901)Z.W.acknowledges support from the National Thousand-Young-Talents Program and the CAS Pioneer Hundred Talents Program.
文摘Based on the first-principles calculations and experimental measurements,we report that the hexagonal phase of ternary transition metal pnictides TT’X(T=Zr,Hf;T’=Ru;X=P,As),which are well-known noncentrosymmetric superconductors with relatively high transition temperatures,host nontrivial bulk topology.Before the superconducting phase transition,we find that HfRuP belongs to a Weyl semimetal phase with 12 pairs of type-II Weyl points,while ZrRuAs,ZrRuP and HfRuAs belong to a topological crystalline insulating phase with trivial Fu-Kane Z_(2) indices but nontrivial mirror Chern numbers.High-quality single crystal samples of the noncentrosymmetric superconductors with these two different topological states have been obtained and the superconductivity is verified experimentally.The wide-range band structures of ZrRuAs have been identified by ARPES and reproduced by theoretical calculations.Combined with intrinsic superconductivity,the nontrivial topology of the normal state may generate unconventional superconductivity in both bulk and surfaces.Our findings could largely inspire the experimental searching for possible topological superconductivity in these compounds.
基金supported by the National Natural Science Foundation of China(11974395 and 12188101)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB33000000)+6 种基金the Center for Materials Genomesupport from the Ministry of Science and Technology of China under Grant Nos.2016YFA0300600 and 2018YFA0305700the Chinese Academy of Sciences under Grant No.XDB28000000the Science Challenge Project(TZ2016004)the K.C.Wong Education Foundation(GJTD-2018-01)Beijing Municipal Science&Technology Commission(Z181100004218001)Beijing Natural Science Foundation(Z180008)。
基金supported by the National Natural Science Foundation of China (11974395,11674369, and 11925408)the Strategic Priority Research Program of Chinese Academy of Sciences (CAS XDB33000000)+2 种基金the Center for Materials Genomesupport from the National Key Research and Development Program of China (2016YFA0300600, 2016YFA0302400, and 2018YFA0305700)the K. C. Wong Education Foundation (GJTD-2018-01)。