This paper analyzed the trend of seed industry development in-depth and studied changes in quantity and quality of demands for seed industry talents. To adapt to " breeding,propagating and selling" integrati...This paper analyzed the trend of seed industry development in-depth and studied changes in quantity and quality of demands for seed industry talents. To adapt to " breeding,propagating and selling" integration and internationalized trend of seed industry,it stated that hierarchical training mode is an ideal mode for training outstanding seed industry talents. Finally,it elaborated specific objectives and requirements of the hierarchical training mode,i. e. undergraduate- master- doctor.展开更多
Porous liquids(PLs),an emerging porous material with permanent cavities,have attracted extensive attention in recent years.However,the current construction methods are complicated and resulting PLs possess high viscos...Porous liquids(PLs),an emerging porous material with permanent cavities,have attracted extensive attention in recent years.However,the current construction methods are complicated and resulting PLs possess high viscosity values,which cannot meet the requirements of practical industrial applications.Herein,we demonstrate a generalizable and simple strategy to prepare type III PLs with low viscosity based on the rule of“like dissolves like”.Specifically,the monoglycidyl ether terminated polydimethylsiloxane(denoted by E-PDMS)is attached to the surface of Universitetet i Oslo(UiO)-66-NH_(2)via covalent linkage,constructing the pore generator(UiO-66-NH_(2)-E-PDMS,denoted by P-UiO-66).Then,P-UiO-66 is dispersed into different types and amounts of sterically hindered solvents(PDMS400 or PDMS6000),obtaining a series of type III PLs(denoted by P-UiO-66-PLs)with permanent cavities and low viscosities.The gas sorption-desorption test shows that P-UiO-66-PLs have an enormous potential for CO_(2)/N_(2) selective separation.Besides,the porosity of P-UiO-66-PLs and the CO_(2)sorption mechanism are demonstrated by molecular simulation.Furthermore,the generality of the synthesis strategy is confirmed by the successful construction of PLs using two other amino-metal-organic frameworks(MOFs)(MIL-53(Al)-NH_(2)and MIL-88B(Fe)-NH_(2)).Importantly,it’s worth noting that the strategy based on the rule of“like dissolves like”sheds light on the preparation of other types of PLs for task-specific applications.展开更多
基金Supported by Study on Dynamic Adjustment Mechanism for University-Enterprise Cooperation and Specialized Structure(12xn0042)
文摘This paper analyzed the trend of seed industry development in-depth and studied changes in quantity and quality of demands for seed industry talents. To adapt to " breeding,propagating and selling" integration and internationalized trend of seed industry,it stated that hierarchical training mode is an ideal mode for training outstanding seed industry talents. Finally,it elaborated specific objectives and requirements of the hierarchical training mode,i. e. undergraduate- master- doctor.
基金This work is supported by the Aeronautical Science Foundation of China(No.2018ZF53065)the Key Project of Shaanxi Provincial Natural Science Foundation(No.2021JZ-09)+1 种基金the National Undergraduate Training Program for Innovation and Entrepreneurship(No.201910699113)the Shaanxi Province Science Foundation for Youths(No.2023-JC-QN-0146).
文摘Porous liquids(PLs),an emerging porous material with permanent cavities,have attracted extensive attention in recent years.However,the current construction methods are complicated and resulting PLs possess high viscosity values,which cannot meet the requirements of practical industrial applications.Herein,we demonstrate a generalizable and simple strategy to prepare type III PLs with low viscosity based on the rule of“like dissolves like”.Specifically,the monoglycidyl ether terminated polydimethylsiloxane(denoted by E-PDMS)is attached to the surface of Universitetet i Oslo(UiO)-66-NH_(2)via covalent linkage,constructing the pore generator(UiO-66-NH_(2)-E-PDMS,denoted by P-UiO-66).Then,P-UiO-66 is dispersed into different types and amounts of sterically hindered solvents(PDMS400 or PDMS6000),obtaining a series of type III PLs(denoted by P-UiO-66-PLs)with permanent cavities and low viscosities.The gas sorption-desorption test shows that P-UiO-66-PLs have an enormous potential for CO_(2)/N_(2) selective separation.Besides,the porosity of P-UiO-66-PLs and the CO_(2)sorption mechanism are demonstrated by molecular simulation.Furthermore,the generality of the synthesis strategy is confirmed by the successful construction of PLs using two other amino-metal-organic frameworks(MOFs)(MIL-53(Al)-NH_(2)and MIL-88B(Fe)-NH_(2)).Importantly,it’s worth noting that the strategy based on the rule of“like dissolves like”sheds light on the preparation of other types of PLs for task-specific applications.