Three industry-supplied, well-shaped Mo/HZSM-5 catalysts, two binder-added and one binder-free, were tested for the first time in methane dehydroaromatization to benzene at 1073 K and 10000 mL/(g·h) in periodic...Three industry-supplied, well-shaped Mo/HZSM-5 catalysts, two binder-added and one binder-free, were tested for the first time in methane dehydroaromatization to benzene at 1073 K and 10000 mL/(g·h) in periodic CH4-H2 switch operation mode, and their catalytic performances were compared with those of three self-prepared, binder-free powder Mo/HZSM-5 catalysts. XRD, 27Al NMR, SEM, BET and NH3-TPD characterizations of all the catalysts show that the zeolites in the two binder-added catalysts are comparable to those in the three binder-free powder catalysts in crystallinity, crystal size, micropore volume and Br{/o}nsted acidity. The test results, on the other hand, show that the catalytic performances of the two binder-added catalysts are worse than those of the four binder-free catalysts on both catalyst mass and zeolite mass bases. Then, TPO and BET measurements of all spent samples were conducted to get a deep insight into the negative effects of binder addition, and the results suggest that the binder additives functioned mainly to enhance the polyaromatization of formed aromatics to coke on their external surfaces and consequently lower the catalysts' benzene formation activity and selectivity.展开更多
Nitrogen doped diamond-like carbon (DLC:N) films were prepared by electron cyclotron resonance chemical vapor deposition (ECR-CVD) on polycrystalline Si chips. Film thickness is about 50 nm. Auger electron spectr...Nitrogen doped diamond-like carbon (DLC:N) films were prepared by electron cyclotron resonance chemical vapor deposition (ECR-CVD) on polycrystalline Si chips. Film thickness is about 50 nm. Auger electron spectroscopy (AES) was used to evaluate nitrogen content, and increasing N2 flow improved N content from 0 to 7.6%. Raman and X-ray photoelectron spectroscopy (XPS) analysis results reveal CN-sp^3C and N-sp^2C structure. With increasing the N2 flow, sp^3C decreases from 73.74% down to 42.66%, and so does N-sp^3C from 68.04% down to 20.23%. The hardness decreases from 29.18 GPa down to 19.74 GPa, and the Young's modulus from 193.03 GPa down to 144.52 GPa.展开更多
Summary What is already known about this topic?Previous studies have indicated a possible association between reproductive tract infections(RTIs)and highrisk human papillomavirus(HPV)infection,but the evidence is stil...Summary What is already known about this topic?Previous studies have indicated a possible association between reproductive tract infections(RTIs)and highrisk human papillomavirus(HPV)infection,but the evidence is still inconclusive.What is added by this report?This multicenter study found significantly higher positive rates of HPV,including general HPV,highrisk HPV.展开更多
Accurate and reliable crack segmentation is a challenge and meaningful task.In this article,aiming at the characteristics of cracks on the concrete images,the intensity frequency information of source images which is ...Accurate and reliable crack segmentation is a challenge and meaningful task.In this article,aiming at the characteristics of cracks on the concrete images,the intensity frequency information of source images which is obtained by Discrete Wavelet Transform(DWT)is fed into deep learning-based networks to enhance the ability of network on crack segmentation.To well integrate frequency information into network an effective and novel DWTA module based on the DWT and scSE attention mechanism is proposed.The semantic information of cracks is enhanced and the irrelevant information is suppressed by DWTA module.And the gap between frequency information and convolution information from network is balanced by DWTA module which can well fuse wavelet information into image segmentation network.The Unet-DWTA is proposed to preserved the information of crack boundary and thin crack in intermediate feature maps by adding DWTA module in the encoderdecoder structures.In decoder,diverse level feature maps are fused to capture the information of crack boundary and the abstract semantic information which is beneficial to crack pixel classification.The proposed method is verified on three classic datasets including CrackDataset,CrackForest,and DeepCrack datasets.Compared with the other crack methods,the proposed Unet-DWTA shows better performance based on the evaluation of the subjective analysis and objective metrics about image semantic segmentation.展开更多
With the increasing development of Internet technology,computer Internet,intelligent terminal,cloud computing and other new technologies continue to emerge.All kinds of app based on mobile intelligent terminal are wid...With the increasing development of Internet technology,computer Internet,intelligent terminal,cloud computing and other new technologies continue to emerge.All kinds of app based on mobile intelligent terminal are widely used because of its convenience and intelligence.However,for the safety of the coal industry,how to use these technologies based on mobile intelligent terminal to establish a set of efficient long-term mechanism of safety inspection and risk control is a necessary method to upgrade the safety management mode.Therefore,in order to meet the requirements of hidden danger investigation and management,this paper designs an intelligent hidden danger investigation and management system.Based on Ionic,the system constructs a cross platform mixed mode mobile app development framework.The paper shows that the system can realize the basic hidden danger investigation requirements.展开更多
与 V <sub>2</sub 涂的独块巨石 SCR 催化剂 > O <sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> 被改变文件夹和涂层厚度准备。与独块巨石作比较与 100% V <sub>2</sub 渗出 ...与 V <sub>2</sub 涂的独块巨石 SCR 催化剂 > O <sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> 被改变文件夹和涂层厚度准备。与独块巨石作比较与 100% V <sub>2</sub 渗出 > O <sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> 粉末,有 260 的催化剂涂层层的涂的独块巨石吗?展开更多
An index system for evaluation of technologies for urban river rehabilitation was proposed and discussed.The index system includes indicators of cost,resources,environmental improvement,and social effects.The calculat...An index system for evaluation of technologies for urban river rehabilitation was proposed and discussed.The index system includes indicators of cost,resources,environmental improvement,and social effects.The calculation method for an objective value of each index based on its attributes and weights was presented.The Foshan Channel,which is a seriously polluted,black and malodorous urban river in Foshan City,China,was selected as a case study.The values of the attributes and the weights of the indices for the Foshan Channel were determined.The technologies for the rehabilitation of the Foshan Channel were evaluated based on this index system.Finally,a rehabilitation scheme for the Foshan Channel was proposed.展开更多
文摘Three industry-supplied, well-shaped Mo/HZSM-5 catalysts, two binder-added and one binder-free, were tested for the first time in methane dehydroaromatization to benzene at 1073 K and 10000 mL/(g·h) in periodic CH4-H2 switch operation mode, and their catalytic performances were compared with those of three self-prepared, binder-free powder Mo/HZSM-5 catalysts. XRD, 27Al NMR, SEM, BET and NH3-TPD characterizations of all the catalysts show that the zeolites in the two binder-added catalysts are comparable to those in the three binder-free powder catalysts in crystallinity, crystal size, micropore volume and Br{/o}nsted acidity. The test results, on the other hand, show that the catalytic performances of the two binder-added catalysts are worse than those of the four binder-free catalysts on both catalyst mass and zeolite mass bases. Then, TPO and BET measurements of all spent samples were conducted to get a deep insight into the negative effects of binder addition, and the results suggest that the binder additives functioned mainly to enhance the polyaromatization of formed aromatics to coke on their external surfaces and consequently lower the catalysts' benzene formation activity and selectivity.
文摘Nitrogen doped diamond-like carbon (DLC:N) films were prepared by electron cyclotron resonance chemical vapor deposition (ECR-CVD) on polycrystalline Si chips. Film thickness is about 50 nm. Auger electron spectroscopy (AES) was used to evaluate nitrogen content, and increasing N2 flow improved N content from 0 to 7.6%. Raman and X-ray photoelectron spectroscopy (XPS) analysis results reveal CN-sp^3C and N-sp^2C structure. With increasing the N2 flow, sp^3C decreases from 73.74% down to 42.66%, and so does N-sp^3C from 68.04% down to 20.23%. The hardness decreases from 29.18 GPa down to 19.74 GPa, and the Young's modulus from 193.03 GPa down to 144.52 GPa.
文摘Summary What is already known about this topic?Previous studies have indicated a possible association between reproductive tract infections(RTIs)and highrisk human papillomavirus(HPV)infection,but the evidence is still inconclusive.What is added by this report?This multicenter study found significantly higher positive rates of HPV,including general HPV,highrisk HPV.
基金National Natural Science Foundation of China under Grant 61972267National Natural Science Foundation of Hebei Province under Grant F2018210148University Science Research Project of Hebei Province under Grant ZD2021334。
文摘Accurate and reliable crack segmentation is a challenge and meaningful task.In this article,aiming at the characteristics of cracks on the concrete images,the intensity frequency information of source images which is obtained by Discrete Wavelet Transform(DWT)is fed into deep learning-based networks to enhance the ability of network on crack segmentation.To well integrate frequency information into network an effective and novel DWTA module based on the DWT and scSE attention mechanism is proposed.The semantic information of cracks is enhanced and the irrelevant information is suppressed by DWTA module.And the gap between frequency information and convolution information from network is balanced by DWTA module which can well fuse wavelet information into image segmentation network.The Unet-DWTA is proposed to preserved the information of crack boundary and thin crack in intermediate feature maps by adding DWTA module in the encoderdecoder structures.In decoder,diverse level feature maps are fused to capture the information of crack boundary and the abstract semantic information which is beneficial to crack pixel classification.The proposed method is verified on three classic datasets including CrackDataset,CrackForest,and DeepCrack datasets.Compared with the other crack methods,the proposed Unet-DWTA shows better performance based on the evaluation of the subjective analysis and objective metrics about image semantic segmentation.
文摘With the increasing development of Internet technology,computer Internet,intelligent terminal,cloud computing and other new technologies continue to emerge.All kinds of app based on mobile intelligent terminal are widely used because of its convenience and intelligence.However,for the safety of the coal industry,how to use these technologies based on mobile intelligent terminal to establish a set of efficient long-term mechanism of safety inspection and risk control is a necessary method to upgrade the safety management mode.Therefore,in order to meet the requirements of hidden danger investigation and management,this paper designs an intelligent hidden danger investigation and management system.Based on Ionic,the system constructs a cross platform mixed mode mobile app development framework.The paper shows that the system can realize the basic hidden danger investigation requirements.
文摘与 V <sub>2</sub 涂的独块巨石 SCR 催化剂 > O <sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> 被改变文件夹和涂层厚度准备。与独块巨石作比较与 100% V <sub>2</sub 渗出 > O <sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> 粉末,有 260 的催化剂涂层层的涂的独块巨石吗?
基金the Programme of Introducing Talents of Discipline to Universities(No.B07002)the National Water Pollution Control Special Project(No.2008ZX07313-006).
文摘An index system for evaluation of technologies for urban river rehabilitation was proposed and discussed.The index system includes indicators of cost,resources,environmental improvement,and social effects.The calculation method for an objective value of each index based on its attributes and weights was presented.The Foshan Channel,which is a seriously polluted,black and malodorous urban river in Foshan City,China,was selected as a case study.The values of the attributes and the weights of the indices for the Foshan Channel were determined.The technologies for the rehabilitation of the Foshan Channel were evaluated based on this index system.Finally,a rehabilitation scheme for the Foshan Channel was proposed.