期刊文献+
共找到6篇文章
< 1 >
每页显示 20 50 100
Pt/ZnO在室温水相无碱条件下绿色催化苯甲醇选择性氧化(英文) 被引量:4
1
作者 刘娟娟 邹世辉 +3 位作者 吴嘉超 Hisayoshi Kobayashi 赵红挺 范杰 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2018年第6期1081-1089,共9页
醇类化合物选择性氧化是有机合成中一个非常重要的反应,在精细化工领域具有重要应用.而以水为绿色溶剂,分子氧为绿色氧化剂实现醇类化合物选择性氧化是绿色化学领域的一大挑战.Pt催化剂由于其优异的活化氧气和C-H键的能力在该反应中得... 醇类化合物选择性氧化是有机合成中一个非常重要的反应,在精细化工领域具有重要应用.而以水为绿色溶剂,分子氧为绿色氧化剂实现醇类化合物选择性氧化是绿色化学领域的一大挑战.Pt催化剂由于其优异的活化氧气和C-H键的能力在该反应中得到了广泛应用.但是,常规的Pt催化剂通常需要在较高温度和较高氧气压力以及加碱的条件下才能发挥作用,从而引起了催化剂腐蚀等一系列问题.从绿色化学角度出发,进一步优化Pt催化剂,让其能够在室温无碱条件下以空气为氧化剂选择性氧化醇类合成羰基化合物具有重要的研究价值和应用前景.本文通过化学还原法制备了Pt/ZnO催化剂,系统研究了该催化剂在水相无碱条件下选择性氧化苯甲醇生成苯甲醛反应中的催化性能.X射线电子衍射和透射电镜等结果表明,Pt颗粒较小(3.2±0.3 nm),均匀分散在ZnO载体上;X射线光电子能谱表明ZnO载体能够稳定Pt纳米颗粒表面的Pt^0物种.上述催化剂在水相苯甲醇选择性氧化反应中,在室温下即可催化空气高选择性氧化苯甲醇到苯甲醛(选择性>99%),并表现出比Pt/SiO_2,Pt/Al_2O_3,Pt/TiO_2,Pt/Ca(Mg)-ZSM-5等催化剂更为优异的催化活性.这可归结于Pt和ZnO之间的协同作用.该协同作用通过动力学实验和密度泛函理论计算(DFT)得到了证实.氧分压实验表明,在以空气为氧化剂时,O_2的活化并不是限制Pt/ZnO催化活性的关键因素,而动力学同位素效应实验则证实了苯甲醇的C-H键活化是整个反应的决速步骤.通过构建不同的理论模型,分别计算了Pt/ZnO界面处以及纯Pt位点上苯甲醇选择性氧化的反应过程.结果表明,苯甲醇和氧气分子倾向于分别在ZnO和Pt上进行吸附,随后由吸附的氧气分子来活化苯甲醇中的C-H键,进而生成苯甲醛和水.而当ZnO不参与苯甲醇的吸附活化时,整个反应的活化能会大大提高,表明ZnO和Pt之间的协同作用对于整个反应至关重要.此外,Pt/ZnO表现出非常优异的稳定性,循环使用4次后,催化剂结构以及催化活性没有显著变化.进一步向Pt/ZnO催化剂中引入少量Bi元素对Pt的电子结构进行修饰,可以将Pt/ZnO的催化活性提高3倍.所制备的Pt/Bi-ZnO复合物是目前报道的相同条件下催化苯甲醇选择性氧化反应转化频率(45.1 h^(-1))最高的催化剂. 展开更多
关键词 铂/氧化锌 选择性氧化 苯甲醇 C-H活化 水相 室温
下载PDF
Survey on Blockchain Incentive Mechanism
2
作者 Jiyue Huang Kai Lei +4 位作者 Maoyu Du hongting zhao Huafang Liu Jin Liu Zhuyun Qi 《国际计算机前沿大会会议论文集》 2019年第1期393-395,共3页
The current research on the blockchain includes study on network architecture and the incentive. In this paper, an introduction to the architecture of information technology was given and the goal and research status ... The current research on the blockchain includes study on network architecture and the incentive. In this paper, an introduction to the architecture of information technology was given and the goal and research status of the incentive layer of blockchain were illustrated with digital economy development as the backdrop. The existing issuance of token was elaborated from computation, storage and transmission, three core facets of network technology. The development of the token allocation and the path was analyzed to confirm its rationality. It discusses the possible directions and challenges of the future research on blockchain incentive. 展开更多
关键词 Blockchain INCENTIVE MECHANISM DIGITAL ECONOMY
下载PDF
Mitochondrial Calcium Homeostasis in the Pathology and Therapeutic Application in Friedreich's Ataxia 被引量:1
3
作者 hongting zhao Zhuoyuan Li +2 位作者 Yutong Liu Meng Zhang Kuanyu Li 《Neuroscience Bulletin》 SCIE CAS CSCD 2023年第4期695-698,共4页
Friedreich's ataxia(FRDA)is the most common neurodegenerative disease caused by an autosomal recessive singlegene mutation,affecting 2-4 per 100,000 Caucasians[1].The causative gene is frataxin(FXN),located on chr... Friedreich's ataxia(FRDA)is the most common neurodegenerative disease caused by an autosomal recessive singlegene mutation,affecting 2-4 per 100,000 Caucasians[1].The causative gene is frataxin(FXN),located on chromosome 9q13,and it encodes a 210-amino-acid mitochondrial matrix protein. 展开更多
关键词 Friedreich THERAPEUTIC STASIS
原文传递
季节性流感疫苗和新型冠状病毒疫苗同时接种工作的思考和建议 被引量:1
4
作者 寇增强 刘丽珺 +11 位作者 许长沙 赵宏婷 张肇南 杨孝坤 彭质斌 冯录召 徐爱强 王大燕 陈直平 郑建东 冯子健 余文周 《中华预防医学杂志》 CAS CSCD 北大核心 2022年第10期1395-1400,共6页
在新型冠状病毒肺炎(新冠肺炎)全球大流行的环境下, 流感的流行强度、流行特征和人群的感染风险均呈现出新的特点, 且全球多地区已出现新冠肺炎和流感共同流行的情况。新冠肺炎和流感的传播方式、临床症状等方面相似, 流感病毒与新型冠... 在新型冠状病毒肺炎(新冠肺炎)全球大流行的环境下, 流感的流行强度、流行特征和人群的感染风险均呈现出新的特点, 且全球多地区已出现新冠肺炎和流感共同流行的情况。新冠肺炎和流感的传播方式、临床症状等方面相似, 流感病毒与新型冠状病毒对细胞的作用机制上也存在相似之处, 同时做好新冠肺炎和流感的防控工作具有较强可行性和重大现实意义。本文从流感疫苗接种预防共同感染、流感疫苗和新冠病毒疫苗同时接种等方面, 探讨了流感和新冠共同防控的相关策略和措施, 提出了相应的思考和建议, 以期为季节性流感疫苗和新型冠状病毒疫苗接种策略的制订提供科学支撑。 展开更多
关键词 流感疫苗 新型冠状病毒肺炎 同时接种
原文传递
Forest soil CO_2 fluxes as a function of understory removal and N-fixing species addition 被引量:3
5
作者 Haifang Li Shenglei Fu +1 位作者 hongting zhao Hanping Xia 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2011年第6期949-957,共9页
We report on the effects of forest management practices of understory removal and N-fixing species(Cassia alata) addition on soil CO2 fluxes in an Eucalyptus urophylla plantation(EUp),Acacia crassicarpa plantation(ACp... We report on the effects of forest management practices of understory removal and N-fixing species(Cassia alata) addition on soil CO2 fluxes in an Eucalyptus urophylla plantation(EUp),Acacia crassicarpa plantation(ACp),10-species-mixed plantation(Tp),and 30-species-mixed plantation(THp) using the static chamber method in southern China.Four forest management treatments,including(1) understory removal(UR);(2) C.alata addition(CA);(3) understory removal and replacement with C.alata(UR+CA);and(4) control without any disturbances(CK),were applied in the above four forest plantations with three replications for each treatment.The results showed that soil CO2 fluxes rates remained at a high level during the rainy season(from April to September),followed by a rapid decrease after October reaching a minimum in February.Soil CO2 fluxes were significantly higher(P < 0.01) in EUp(132.6 mg/(m2.hr)) and ACp(139.8 mg/(m2.hr)) than in Tp(94.0 mg/(m2.hr)) and THp(102.9 mg/(m2.hr)).Soil CO2 fluxes in UR and CA were significantly higher(P < 0.01) among the four treatments,with values of 105.7,120.4,133.6 and 112.2 mg/(m2.hr) for UR+CA,UR,CA and CK,respectively.Soil CO2 fluxes were positively correlated with soil temperature(P < 0.01),soil moisture(P < 0.01),NO3?-N(P < 0.05),and litterfall(P < 0.01),indicating that all these factors might be important controlling variables for soil CO2 fluxes.This study sheds some light on our understanding of soil CO2 flux dynamics in forest plantations under various management practices. 展开更多
关键词 CO2通量 森林土壤 拆除 物种 固氮 尾叶桉人工林 乌拉圭回合 森林管理
原文传递
Eleven COVID-19 Outbreaks with Local Transmissions Caused by the Imported SARS-CoV-2 Delta VOC-China,July-August,2021 被引量:13
6
作者 Lei Zhou Kai Nie +36 位作者 hongting zhao Xiang zhao Bixiong Ye Ji Wang Cao Chen Hong Wang Jiangli Di Jinsong Li Chao Li Zhixiao Chen Ruiqi Ren Peihua Niu Hui Chen Tao Chen Yali Wang Lili Li Bingxue Han Ruhan A Si Chen Dan Li Dan Li Chunxia Jin Xin Zhang Jiangmei Liu Chunyu Xu Yecheng Yao Yenan Feng Zhili Li Bike Zhang Yang Song Peter Hao Yanping Zhang Hao Li Qun Li George F.Gao Guoqing Shi Wenbo Xu 《China CDC weekly》 2021年第41期863-868,共6页
Starting from December 2019,Wuhan,China,encountered the first outbreak of coronavirus disease 2019(COVID-19)(1-2).The epidemic was successfully suppressed by strict containment so that the number of infected people wa... Starting from December 2019,Wuhan,China,encountered the first outbreak of coronavirus disease 2019(COVID-19)(1-2).The epidemic was successfully suppressed by strict containment so that the number of infected people was reduced to 0 on April 8,2020(3–4).After that,China experienced roughly 3 dozen outbreaks with local transmission caused by imported severe acute respiratory syndrome coronavirus 2(SARS-CoV-2). 展开更多
关键词 acute RESPIRATORY COV
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部