Single-ion conducting polymer electrolytes have attracted great attention as safe alternatives to liquid electrolytes in high energy density lithium-ion batteries.Herein,we report the first example of a crystalline an...Single-ion conducting polymer electrolytes have attracted great attention as safe alternatives to liquid electrolytes in high energy density lithium-ion batteries.Herein,we report the first example of a crystalline anionic helical polymer as a single lithium-ion conducting solid polymer electrolyte(SPE).Single-crystal X-ray analysis shows that the polymer folds into densely packed double helices,with bundles of unidirectional negatively charged channels formed that can facilitate lithium-ion transportation.展开更多
基金supported by the University of Colorado Boulder。
文摘Single-ion conducting polymer electrolytes have attracted great attention as safe alternatives to liquid electrolytes in high energy density lithium-ion batteries.Herein,we report the first example of a crystalline anionic helical polymer as a single lithium-ion conducting solid polymer electrolyte(SPE).Single-crystal X-ray analysis shows that the polymer folds into densely packed double helices,with bundles of unidirectional negatively charged channels formed that can facilitate lithium-ion transportation.
