Comprehensive Summary A greener and more convenient alternative to traditional methods for the generation of thiyl radical as hydrogen atom transfer(HAT)catalyst is developed,using molecular oxygen to oxidize thiol wi...Comprehensive Summary A greener and more convenient alternative to traditional methods for the generation of thiyl radical as hydrogen atom transfer(HAT)catalyst is developed,using molecular oxygen to oxidize thiol without the need for chemical initiators or light irradiation.The thiol/oxygen catalysis enables selective and efficient difunctionalization of borane.展开更多
基金supported by research start-up fund(Project No.4933621)from the Chinese University of Hong Kong.Mr.Weixuan Sun is thanked for checking the experimental procedure。
文摘Comprehensive Summary A greener and more convenient alternative to traditional methods for the generation of thiyl radical as hydrogen atom transfer(HAT)catalyst is developed,using molecular oxygen to oxidize thiol without the need for chemical initiators or light irradiation.The thiol/oxygen catalysis enables selective and efficient difunctionalization of borane.
