The electrochemical behavior of a bis (N-2-methylphenyl-salicyldenaminato)copper (II) complex spiked in a carbon paste electrode (BMPSCu-CPE) and its electrocatalytic reduc-tion of H2 O2 were examined using cyclic vol...The electrochemical behavior of a bis (N-2-methylphenyl-salicyldenaminato)copper (II) complex spiked in a carbon paste electrode (BMPSCu-CPE) and its electrocatalytic reduc-tion of H2 O2 were examined using cyclic voltammetry, chronoamperometry, and differen-tial pulse voltammetry. Cyclic voltammetry was used to study the redox properties of BMPSCu-CPE at various potential scan rates. The apparent charge transfer rate constant and the transfer coefficient for the electron transfer between BMPSCu and the carbon paste electrode (CPE) were 1.9 ± 0.1 s–1 and 0.43, respectively. BMPSCu-CPE had excel-lent electrocatalytic activity for H2 O2 reduction in 0.1 mol/L phosphate buffer solution (pH 5.0), and it decreased the overpotential by 300 mV as compared to CPE alone. The diffusion coefficient and kinetic parameters such as the heterogeneous catalytic electron transfer rate constant and electron transfer coefficient for the reduction of H2 O2 at the BMPSCu-CPE surface were also determined using electrochemical methods. Differential pulse voltammetry showed two linear dynamic ranges of 1.0–10.0 and 10.0–300.0 μmol/L and a detection limit of 0.63 μmol/L H2 O2. The BMPSCu-CPE has excellent repro-ducibility and long term stability, and it was successfully applied for the determination of H2 O2 in two pharmaceutical samples: an antiseptic solution and a hair dying cream.展开更多
文摘The electrochemical behavior of a bis (N-2-methylphenyl-salicyldenaminato)copper (II) complex spiked in a carbon paste electrode (BMPSCu-CPE) and its electrocatalytic reduc-tion of H2 O2 were examined using cyclic voltammetry, chronoamperometry, and differen-tial pulse voltammetry. Cyclic voltammetry was used to study the redox properties of BMPSCu-CPE at various potential scan rates. The apparent charge transfer rate constant and the transfer coefficient for the electron transfer between BMPSCu and the carbon paste electrode (CPE) were 1.9 ± 0.1 s–1 and 0.43, respectively. BMPSCu-CPE had excel-lent electrocatalytic activity for H2 O2 reduction in 0.1 mol/L phosphate buffer solution (pH 5.0), and it decreased the overpotential by 300 mV as compared to CPE alone. The diffusion coefficient and kinetic parameters such as the heterogeneous catalytic electron transfer rate constant and electron transfer coefficient for the reduction of H2 O2 at the BMPSCu-CPE surface were also determined using electrochemical methods. Differential pulse voltammetry showed two linear dynamic ranges of 1.0–10.0 and 10.0–300.0 μmol/L and a detection limit of 0.63 μmol/L H2 O2. The BMPSCu-CPE has excellent repro-ducibility and long term stability, and it was successfully applied for the determination of H2 O2 in two pharmaceutical samples: an antiseptic solution and a hair dying cream.
