The quest of exact and nonperturbative methods on quantum dissipation with nonlinear coupling environments remains in general a great challenge.In this review we present a comprehensive account on two approaches to th...The quest of exact and nonperturbative methods on quantum dissipation with nonlinear coupling environments remains in general a great challenge.In this review we present a comprehensive account on two approaches to the entangled system-and-environment dynamics,in the presence of linear-plus-quadratic coupling bath.One is the dissipaton-equation-ofmotion(DEOM)theory that has been extended recently to treat the nonlinear coupling environment.Another is the extended Fokker-Planck quantum master equation(FP-QME)approach that will be constructed in this work,based on its DEOM correspondence.We closely compare these two approaches,with the focus on the underlying quasi-particle picture,physical implications,and implementations.展开更多
We present a semiclassical （SC） approach for quantum dissipative dynamics, constructed on basis of the hierarchical-equation-of-motion （HEOM） formalism. The dynamical components considered in the developed SC-HEOM...We present a semiclassical （SC） approach for quantum dissipative dynamics, constructed on basis of the hierarchical-equation-of-motion （HEOM） formalism. The dynamical components considered in the developed SC-HEOM are wavepackets＇ phase-space moments of not only the primary reduced system density operator but also the auxiliary density operators （ADOs） of HEOM. It is a highly numerically efficient method, meanwhile taking into account the high-order effcts of system-bath couplings. The SC-HEOM methodology is exemplified in this work on the hierarchical quantum master equation [J. Chem. Phys. 131, 214111 （2009）] and numerically demonstrated on linear spectra of anharmonic oscillators.展开更多
The hierarchical equation of motion method has become one of the most popular numerical methods for describing the dissipative dynamics of open quantum systems linearly coupled to environment.However,its applications ...The hierarchical equation of motion method has become one of the most popular numerical methods for describing the dissipative dynamics of open quantum systems linearly coupled to environment.However,its applications to systems with strong electron correlation are largely restrained by the computational cost,which is mainly caused by the high truncation tier L required to accurately characterize the strong correlation effect.In this work,we develop an adiabatic terminator by decoupling the principal dissipation mode with the fastest dissipation rate from the slower ones.The adiabatic terminator leads to substantially enhanced convergence with respect to L as demonstrated by the numerical tests carried out on a single impurity Anderson model.Moreover,the adiabatic terminator alleviates the numerical instability problems in the long-time dissipative dynamics.展开更多
基金This work was supported from the Ministry of Science and Technology(No.2016YFA0400900),the National Natural Science Foundation of China(No.21373191,No.21633006,and No.21303090),and the Fundamental Research Funds for the Central Universities(No.2030020028).
文摘The quest of exact and nonperturbative methods on quantum dissipation with nonlinear coupling environments remains in general a great challenge.In this review we present a comprehensive account on two approaches to the entangled system-and-environment dynamics,in the presence of linear-plus-quadratic coupling bath.One is the dissipaton-equation-ofmotion(DEOM)theory that has been extended recently to treat the nonlinear coupling environment.Another is the extended Fokker-Planck quantum master equation(FP-QME)approach that will be constructed in this work,based on its DEOM correspondence.We closely compare these two approaches,with the focus on the underlying quasi-particle picture,physical implications,and implementations.
基金supported by the National Natural Science Foundation of China(No.21373191,No.21573202,No.21633006,and No.21703225)the Fundamental Research Funds for the Central Universities(No.2030020028,No.2060030025,and No.2340000074)
文摘We present a semiclassical （SC） approach for quantum dissipative dynamics, constructed on basis of the hierarchical-equation-of-motion （HEOM） formalism. The dynamical components considered in the developed SC-HEOM are wavepackets＇ phase-space moments of not only the primary reduced system density operator but also the auxiliary density operators （ADOs） of HEOM. It is a highly numerically efficient method, meanwhile taking into account the high-order effcts of system-bath couplings. The SC-HEOM methodology is exemplified in this work on the hierarchical quantum master equation [J. Chem. Phys. 131, 214111 （2009）] and numerically demonstrated on linear spectra of anharmonic oscillators.
文摘The hierarchical equation of motion method has become one of the most popular numerical methods for describing the dissipative dynamics of open quantum systems linearly coupled to environment.However,its applications to systems with strong electron correlation are largely restrained by the computational cost,which is mainly caused by the high truncation tier L required to accurately characterize the strong correlation effect.In this work,we develop an adiabatic terminator by decoupling the principal dissipation mode with the fastest dissipation rate from the slower ones.The adiabatic terminator leads to substantially enhanced convergence with respect to L as demonstrated by the numerical tests carried out on a single impurity Anderson model.Moreover,the adiabatic terminator alleviates the numerical instability problems in the long-time dissipative dynamics.
