Exploring efficient and nonprecious metal electrocatalysts of oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)is crucial for developing rechargeable zinc-air batteries(ZABs).Herein,an alloying-degree c...Exploring efficient and nonprecious metal electrocatalysts of oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)is crucial for developing rechargeable zinc-air batteries(ZABs).Herein,an alloying-degree control strategy was employed to fabricate nitrogen-doped carbon sphere(NCS)decorated with dual-phase Co/Co_(7)Fe_(3)heterojunctions(CoFe@NCS).The phase composition of materials has been adjusted by controlling the alloying degree.The optimal CoFe_(0.08)@NCS electrocatalyst displays a half-wave potential of 0.80 V for ORR and an overpotential of 283 mV at 10 mA·cm^(-2)for OER in an alkaline electrolyte.The intriguing bifunctional electrocatalytic activity and durability is attributed to the hierarchically porous structure and interfacial electron coupling of highly-active Co_(7)Fe_(3)alloy and metallic Co species.When the CoFe_(0.08)@NCS material is used as air-cathode catalyst of rechargeable liquid-state zinc-air battery(ZAB),the device shows a high peak power-density(157 mW·cm^(-2))and maintains a stable voltage gap over 150 h,outperforming those of the benchmark(Pt/C+RuO_(2))-based device.In particular,the as-fabricated solid-state flexible ZAB delivers a reliable compatibility under different bending conditions.Our work provides a promising strategy to develop metal/alloy-based electrocatalysts for the application in renewable energy conversion technologies.展开更多
Over the past few decades,one of the most significant advances in dam construction has been the inven-tion of the rock-filled concrete(RFC)dam,which is constructed by pouring high-performance self-compacting concrete(...Over the past few decades,one of the most significant advances in dam construction has been the inven-tion of the rock-filled concrete(RFC)dam,which is constructed by pouring high-performance self-compacting concrete(HSCC)to fill the voids in preplaced large rocks.The innovative use of large rocks in dam construction provides engineers with a material that requires less cement consumption and hydration heat while enhancing construction efficiency and environmental friendliness.However,two fundamental scientific issues related to RFC need to be addressed:namely,the pouring compactness and the effect of large rocks on the mechanical and physical properties of RFC.This article provides a timely review of fundamental research and innovations in the design,construction,and quality control of RFCdams.Prospects for next-generation concrete dams are discussed from the perspectives of envi-ronmental friendliness,intrinsic safety,and labor savings.展开更多
混合储能系统HESS(hybrid energy storage system)在微电网中有着广泛的应用,其研究主要集中在能量管理、功率分配和拓扑设计等方面。对于功率分配的研究,大多只涉及到基本的功率分配,而无功功率、负序功率和谐波功率的分配问题却很少...混合储能系统HESS(hybrid energy storage system)在微电网中有着广泛的应用,其研究主要集中在能量管理、功率分配和拓扑设计等方面。对于功率分配的研究,大多只涉及到基本的功率分配,而无功功率、负序功率和谐波功率的分配问题却很少被提及。为此,提出了适用于不平衡负载和非线性负载环境的混合储能系统及其协调控制策略。在系统内部,电池功率转换系统工作在下垂模式,提供能量,只输出基本的有功功率;超电容器系统工作在补偿模式,分析总输出功率构成,输出无功、负序和谐波功率。该策略可以在不平衡和非线性负载条件下提供更好的系统性能;此外,该混合储能系统采用双逆变结构,有利于现有设备的升级改造;最后,仿真和实验结果验证了该策略的有效性。展开更多
Numerical simulations of wind turbine blade-tower interaction by using the open source OpenFOAM tools coupled with arbitrary mesh interface （AMI） method were presented. The governing equations were the unsteady Reyn...Numerical simulations of wind turbine blade-tower interaction by using the open source OpenFOAM tools coupled with arbitrary mesh interface （AMI） method were presented. The governing equations were the unsteady Reynolds-averaged Navier-Stokes （RANS） which were solved by the pimpleDyMFoam solver, and the AMI method was employed to handle mesh movements. The National Renewable Energy Laboratory （NREL） phase VI wind turbine in upwind configuration was selected for numerical tests with different incoming wind speeds （5, 10, 15, and 25 m/s） at a fixed blade pitch and constant rotational speed. Detailed numerical results of vortex structure, time histories of thrust, and pressure distribution on the blade and tower were presented. The findings show that the wind turbine tower has little effect on the whole aerodynamic performance of an upwind wind turbine, while the rotating rotor will induce an obvious cyclic drop in the front pressure of the tower. Also, strong interaction of blade tip vortices with separation from the tower was observed.展开更多
基金financially supported by the National Natural Science Foundation of China(No.22279047)the Instrumental Analysis Center of Jiangsu University of Science and Technology。
文摘Exploring efficient and nonprecious metal electrocatalysts of oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)is crucial for developing rechargeable zinc-air batteries(ZABs).Herein,an alloying-degree control strategy was employed to fabricate nitrogen-doped carbon sphere(NCS)decorated with dual-phase Co/Co_(7)Fe_(3)heterojunctions(CoFe@NCS).The phase composition of materials has been adjusted by controlling the alloying degree.The optimal CoFe_(0.08)@NCS electrocatalyst displays a half-wave potential of 0.80 V for ORR and an overpotential of 283 mV at 10 mA·cm^(-2)for OER in an alkaline electrolyte.The intriguing bifunctional electrocatalytic activity and durability is attributed to the hierarchically porous structure and interfacial electron coupling of highly-active Co_(7)Fe_(3)alloy and metallic Co species.When the CoFe_(0.08)@NCS material is used as air-cathode catalyst of rechargeable liquid-state zinc-air battery(ZAB),the device shows a high peak power-density(157 mW·cm^(-2))and maintains a stable voltage gap over 150 h,outperforming those of the benchmark(Pt/C+RuO_(2))-based device.In particular,the as-fabricated solid-state flexible ZAB delivers a reliable compatibility under different bending conditions.Our work provides a promising strategy to develop metal/alloy-based electrocatalysts for the application in renewable energy conversion technologies.
基金the support from the Key Program Grant from National Natural Science Foundation of China (52039005)Grant from State Key Laboratory of Hydroscience and Engineering (2022-KY-01).
文摘Over the past few decades,one of the most significant advances in dam construction has been the inven-tion of the rock-filled concrete(RFC)dam,which is constructed by pouring high-performance self-compacting concrete(HSCC)to fill the voids in preplaced large rocks.The innovative use of large rocks in dam construction provides engineers with a material that requires less cement consumption and hydration heat while enhancing construction efficiency and environmental friendliness.However,two fundamental scientific issues related to RFC need to be addressed:namely,the pouring compactness and the effect of large rocks on the mechanical and physical properties of RFC.This article provides a timely review of fundamental research and innovations in the design,construction,and quality control of RFCdams.Prospects for next-generation concrete dams are discussed from the perspectives of envi-ronmental friendliness,intrinsic safety,and labor savings.
文摘混合储能系统HESS(hybrid energy storage system)在微电网中有着广泛的应用,其研究主要集中在能量管理、功率分配和拓扑设计等方面。对于功率分配的研究,大多只涉及到基本的功率分配,而无功功率、负序功率和谐波功率的分配问题却很少被提及。为此,提出了适用于不平衡负载和非线性负载环境的混合储能系统及其协调控制策略。在系统内部,电池功率转换系统工作在下垂模式,提供能量,只输出基本的有功功率;超电容器系统工作在补偿模式,分析总输出功率构成,输出无功、负序和谐波功率。该策略可以在不平衡和非线性负载条件下提供更好的系统性能;此外,该混合储能系统采用双逆变结构,有利于现有设备的升级改造;最后,仿真和实验结果验证了该策略的有效性。
基金Supported by the National Natural Science Foundation of China under Grant Nos.50739004 and 11072154.
文摘Numerical simulations of wind turbine blade-tower interaction by using the open source OpenFOAM tools coupled with arbitrary mesh interface （AMI） method were presented. The governing equations were the unsteady Reynolds-averaged Navier-Stokes （RANS） which were solved by the pimpleDyMFoam solver, and the AMI method was employed to handle mesh movements. The National Renewable Energy Laboratory （NREL） phase VI wind turbine in upwind configuration was selected for numerical tests with different incoming wind speeds （5, 10, 15, and 25 m/s） at a fixed blade pitch and constant rotational speed. Detailed numerical results of vortex structure, time histories of thrust, and pressure distribution on the blade and tower were presented. The findings show that the wind turbine tower has little effect on the whole aerodynamic performance of an upwind wind turbine, while the rotating rotor will induce an obvious cyclic drop in the front pressure of the tower. Also, strong interaction of blade tip vortices with separation from the tower was observed.
