One marine bacterial strain, R3, has been newly isolated from the intertidal zone of Dinghai sea area. Measurements of a-keto acids and H2O2existing in fermentation supernatant were carried out to show that R3 can pro...One marine bacterial strain, R3, has been newly isolated from the intertidal zone of Dinghai sea area. Measurements of a-keto acids and H2O2existing in fermentation supernatant were carried out to show that R3 can produce L-amino acid oxidase (LAAO) with a broad substrate specificity. Physiological and biochemical analysis showed that it can grow great at the conditions with sodium chloride concentration of 1.5%-3%, temperature of 15?C -35?C and pH of 6-7. In addition, molecular identification of 16S rDNA was performed to show that R3 was proximal toPseudoalteromonasspp. with the highest identity of 98.5% toPseudoalteromonasrubra. Therefore, it was designated asPseudoalteromonassp. R3. Further studies are required to arrive at a better understanding of this LAAO and secure an application.展开更多
Using a ball-milling technique,polymorphous iron particles were prepared by changing only the liquid-solid ratioλ.Effects of λon their morphology,structure,conductivity,and electromagnetic properties were studied.Th...Using a ball-milling technique,polymorphous iron particles were prepared by changing only the liquid-solid ratioλ.Effects of λon their morphology,structure,conductivity,and electromagnetic properties were studied.The results show that an increase ofλfrom 0 to 0.25 causes a nonlinear decrease of the conductivity in the ranges of 88.50-2.25 S cm-1 and a regular variation of the electromagnetic parameters,corresponding to the as-obtained iron particles.This is ascribed to a combination of the increased shape anisotropy and the decreased fresh surface with active atoms deriving from the weakened welding-on action and the enhanced micro-malleation action in the ball-milling process.Hereinto,the iron flakes formed at wet-milling with λ=0.08-0.25 have lower conductivity,higher permittivity and permeability,and more excellent absorption property compared with the irregular iron particles obtained at dry-milling withλ=0.It is a consequence of the synergistic effect of dielectric relaxation loss,exchange energy and conductance loss originating from the flake-shape structures.This indicates that the morphology,structure,conductivity,and electromagnetic properties of the products can be effectively controlled by changingλ.展开更多
Domain switching around electrically permeable and impermeable cracks in ferro-electric single crystals subjected to a mechanical load is investigated by using a phase field model.It is found that the electrical bound...Domain switching around electrically permeable and impermeable cracks in ferro-electric single crystals subjected to a mechanical load is investigated by using a phase field model.It is found that the electrical boundary conditions have little effect on the polarization distribution without any external load when the initial polarization is parallel to the crack,which is totally different from previous studies where the initial polarization is perpendicular to the crack.How-ever,the simulation results show that the electrical boundary conditions have great influence on the polarization distribution as well as the domain switching behavior when a mechanical load is applied.The critical mechanical load of domain switching with a permeable crack is much smaller than that in the case of an impermeable crack.展开更多
Although the{10-12}twinning behavior of Mg alloys under uniaxial tension and compression has been extensively investigated,the simulations of{10-12}twinning behavior under biaxial tension have rarely been reported.In ...Although the{10-12}twinning behavior of Mg alloys under uniaxial tension and compression has been extensively investigated,the simulations of{10-12}twinning behavior under biaxial tension have rarely been reported.In this work,the EVPSC-TDT model is first employed to systematically investigate the deformation behavior of a Mg alloy AZ31 plate under biaxial tension in the RD-TD and ND-TD planes.The RD,TD and ND refer to the rolling direction,transverse direction,and normal direction of the hot rolled plate.The measured stress-strain curves and texture evolutions are well predicted and the con-tours of plastic work under biaxial tension are also constructed for comparison with experiments.The plastic response has been interpreted in terms of relative activities of various deformation modes.For bi-axial tension in the RD-TD plane,basal and pyramidal slips mainly contribute to the plastic deformation for stress ratios ofσRD:σTD=1:2 to 2:1.Prismatic slip becomes more active forσRD:σTD=1:4 and 4:1.Compression twinning could be activated and so cause texture reorientation at large strains,especially forσRD:σTD=1:1.The six-fold feature of{10-10}pole figure could still be observed forσRD:σTD=1:4 and 4:1 at large strain.For biaxial tension in the ND-TD plane,tensile twinning plays an important role forσND:σTD≥1:2,while prismatic slip contributes to plastic deformation for the other cases.With the in-crease of stress ratio fromσND:σTD≥1:1 to 1:0,the predicted twin volume fractions(VFs)at a specific strain along the ND,εND,almost linearly decrease,however,it is seen that the experimental ones at given strains along the ND do not follow such a trend with the measured twin VFs within the range of stress ratios,2:1≤σND:σTD≤6:1,clearly being overestimated,and the difference between experiments and simulations becomes most obvious at the relatively small strain ofεND=0.015.The possible reasons for the observed difference are discussed.展开更多
文摘One marine bacterial strain, R3, has been newly isolated from the intertidal zone of Dinghai sea area. Measurements of a-keto acids and H2O2existing in fermentation supernatant were carried out to show that R3 can produce L-amino acid oxidase (LAAO) with a broad substrate specificity. Physiological and biochemical analysis showed that it can grow great at the conditions with sodium chloride concentration of 1.5%-3%, temperature of 15?C -35?C and pH of 6-7. In addition, molecular identification of 16S rDNA was performed to show that R3 was proximal toPseudoalteromonasspp. with the highest identity of 98.5% toPseudoalteromonasrubra. Therefore, it was designated asPseudoalteromonassp. R3. Further studies are required to arrive at a better understanding of this LAAO and secure an application.
基金supported in part by Natural Scientific Foundation of Zhejiang Province(Project Nos.Y4100022 and Y4100074)New Bud Talents Grant from Zhejiang Province,Science and Technology Projects from Jinhua City(Grant No.2010A12066)+1 种基金Doctoral Startup Foundation from Zhejiang Normal University(Grant No.ZC304009094)Open Lab Project and the 12th Research Task from Zhejiang Normal University
文摘Using a ball-milling technique,polymorphous iron particles were prepared by changing only the liquid-solid ratioλ.Effects of λon their morphology,structure,conductivity,and electromagnetic properties were studied.The results show that an increase ofλfrom 0 to 0.25 causes a nonlinear decrease of the conductivity in the ranges of 88.50-2.25 S cm-1 and a regular variation of the electromagnetic parameters,corresponding to the as-obtained iron particles.This is ascribed to a combination of the increased shape anisotropy and the decreased fresh surface with active atoms deriving from the weakened welding-on action and the enhanced micro-malleation action in the ball-milling process.Hereinto,the iron flakes formed at wet-milling with λ=0.08-0.25 have lower conductivity,higher permittivity and permeability,and more excellent absorption property compared with the irregular iron particles obtained at dry-milling withλ=0.It is a consequence of the synergistic effect of dielectric relaxation loss,exchange energy and conductance loss originating from the flake-shape structures.This indicates that the morphology,structure,conductivity,and electromagnetic properties of the products can be effectively controlled by changingλ.
基金supported by the National Natural Science Foundation of China (Nos. 10832009,11002123 and 11090333)the Zhejiang Provincial Natural Science Foundation under grant R6110115+1 种基金the Chinese Universities Scientific Fund under grant 2009QNA4035the program of Key Team of Technological Innovation of Zhejiang Province under grant2011R09025-07
文摘Domain switching around electrically permeable and impermeable cracks in ferro-electric single crystals subjected to a mechanical load is investigated by using a phase field model.It is found that the electrical boundary conditions have little effect on the polarization distribution without any external load when the initial polarization is parallel to the crack,which is totally different from previous studies where the initial polarization is perpendicular to the crack.How-ever,the simulation results show that the electrical boundary conditions have great influence on the polarization distribution as well as the domain switching behavior when a mechanical load is applied.The critical mechanical load of domain switching with a permeable crack is much smaller than that in the case of an impermeable crack.
基金Y.C.Xin was financially supported by the National Natural Sci-ence Foundation of China(Nos.52071039 and 51871032)the Natural Science Foundation of Jiangsu Province(No.BK20202010)P.D.Wu was financially supported by the Natural Sciences and En-gineering Research Council of Canada(No.RGPIN-2016-06464).
文摘Although the{10-12}twinning behavior of Mg alloys under uniaxial tension and compression has been extensively investigated,the simulations of{10-12}twinning behavior under biaxial tension have rarely been reported.In this work,the EVPSC-TDT model is first employed to systematically investigate the deformation behavior of a Mg alloy AZ31 plate under biaxial tension in the RD-TD and ND-TD planes.The RD,TD and ND refer to the rolling direction,transverse direction,and normal direction of the hot rolled plate.The measured stress-strain curves and texture evolutions are well predicted and the con-tours of plastic work under biaxial tension are also constructed for comparison with experiments.The plastic response has been interpreted in terms of relative activities of various deformation modes.For bi-axial tension in the RD-TD plane,basal and pyramidal slips mainly contribute to the plastic deformation for stress ratios ofσRD:σTD=1:2 to 2:1.Prismatic slip becomes more active forσRD:σTD=1:4 and 4:1.Compression twinning could be activated and so cause texture reorientation at large strains,especially forσRD:σTD=1:1.The six-fold feature of{10-10}pole figure could still be observed forσRD:σTD=1:4 and 4:1 at large strain.For biaxial tension in the ND-TD plane,tensile twinning plays an important role forσND:σTD≥1:2,while prismatic slip contributes to plastic deformation for the other cases.With the in-crease of stress ratio fromσND:σTD≥1:1 to 1:0,the predicted twin volume fractions(VFs)at a specific strain along the ND,εND,almost linearly decrease,however,it is seen that the experimental ones at given strains along the ND do not follow such a trend with the measured twin VFs within the range of stress ratios,2:1≤σND:σTD≤6:1,clearly being overestimated,and the difference between experiments and simulations becomes most obvious at the relatively small strain ofεND=0.015.The possible reasons for the observed difference are discussed.