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联合脱氮法用于硝酸盐污染地下水修复的机理研究 被引量:3
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作者 黄国鑫 高云鹤 +2 位作者 Howard Fallowfield huade guan 刘菲 《岩矿测试》 CAS CSCD 北大核心 2012年第5期855-862,共8页
地下水硝酸盐已经成为了世界性环境和健康问题。目前针对硝酸盐的化学还原脱氮、自养脱氮、异养脱氮等单一脱氮方法研究较多;联合脱氮体系包括化学还原、自养脱氮和异养脱氮三种脱氮途径,综合了单一脱氮法的优点,但研究甚少。本研究通... 地下水硝酸盐已经成为了世界性环境和健康问题。目前针对硝酸盐的化学还原脱氮、自养脱氮、异养脱氮等单一脱氮方法研究较多;联合脱氮体系包括化学还原、自养脱氮和异养脱氮三种脱氮途径,综合了单一脱氮法的优点,但研究甚少。本研究通过静态批试验,采用零价铁、甲醇和混合菌液研究了联合脱氮法的脱氮能力、脱氮产物、脱氮途径及脱氮机理。结果表明,5 d后单一的零价铁化学还原、自养脱氮和异养脱氮的去除率分别为5.79%、14.30%和63.03%;而联合脱氮的去除率接近100%,去除效果显著优于单一的化学还原脱氮、自养脱氮或异养脱氮。在联合脱氮法体系中,零价铁化学还原、自养脱氮未引起亚硝酸盐积累,而异养脱氮造成了亚硝酸盐积累;化学还原、自养脱氮和异养脱氮引起的铵盐增量均<0.6 mg/L,绝大部分硝酸盐未被还原成铵盐,进而省去了后续除铵工艺;零价铁化学还原、自养脱氮、异氧脱氮三者发生协同作用,表现于在厌氧环境下,零价铁发生腐蚀,产生阴极氢和二价铁,为自养脱氮菌提供了电子供体,从而促进了自养脱氮;异养脱氮不仅占主导地位,而且还会产生CO2,CO2被自养脱氮菌作为无机碳源加以利用,从而提高了体系中自养脱氮能力。这种协同作用表现为联合脱氮法的去除率增加,而在单一的异养脱氮或自养脱氮体系中则无法形成这一良性过程。实验表明联合脱氮法是一种潜在的有效可行的地下水原位修复方法。 展开更多
关键词 零价铁化学还原 自养脱氮 异养脱氮 联合脱氮 硝酸盐污染 地下水修复
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Intercomparison of stable isotopes in precipitation simulated by GCMs with GNIP survey over East Asia 被引量:1
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作者 XinPing Zhang ZhiAn Sun +1 位作者 huade guan XinZhu Zhang 《Research in Cold and Arid Regions》 2012年第4期330-341,共12页
Using the isotope enabled ECHAM4, GISS E and HadCM3 GCMs, the spatial distribution of mean 6180 in precipitation, mean seasonality and the correlations of 6180 in precipitation with temperature and precipitation amoun... Using the isotope enabled ECHAM4, GISS E and HadCM3 GCMs, the spatial distribution of mean 6180 in precipitation, mean seasonality and the correlations of 6180 in precipitation with temperature and precipitation amount are analyzed. The simulated results are in agreement with stable isotopic features by GNIP observations. Over East Asia. the distribution of ~180 in precipita- tion is of marked latitude effect and altitude effect. The latitude effect is covered by the continent effect in some regions. The larg- est seasonality of^lSo in precipitation appears in eastern Siberia controlled by cold high pressure, and the smallest seasonality is in the western Pacific controlled by the subtropical high. Relatively weak seasonality appears in middle latitudes where oceanic and continental air masses frequently interact. However, three GCMs show significant systematic lower ~180 for inland mid-high lati- tudes than GNIP data, which is related to the used isotopic scheme in GCMs. Temperature effect occurs mainly in inland mid-high latitudes. The higher the latitude and the closer the distance to inland is, then the stronger the temperature effect. Amount effect occurs mainly in low-mid latitudes and monsoon areas, with the strongest effect in low-latitude coasts or islands. However, three GCMs provide virtually non-existent amount effect in arid regions over Central Asia. The enrichment action of stable isotopes in falling raindrops under a cloud base, which is enlarged by these modes, is responsible for such a result. A significant difference between spatial distributions of δ^18O statistics by GCMs simulations and by GNIP observations is that the standard deviation of GCMs statistics is greater than that of GNIP statistics. In contrast, by comparing parallel time series at a single station, the standard deviations of GCMs simulations are smaller than that of GNIP observations. 展开更多
关键词 GCM GN1P stable isotope simulation temperature effect amount effect
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