Influence of calendering process on the structural mechanics and heat transfer characteristics of lithium-ion battery electrodes via DEM simulations

Elucidating the intricate correlation between calendering,structure,and performance is crucial to comprehending the relationship between performance parameters and process steps of lithium-ion batteries(LIBs).Discrete element method(DEM)simulations were adopted in this work to calculate the interparticle force and stress tensor under incremental calendering process conditions,which revealed the effect of the anisotropy of complex contact force network on the anisotropy of heat transfer within porous electrode.The thermal conductivity of electrode was predicted using porosity to characterize the process-structure-performance correlation.The comprehensive influence of contact number and con-tact area between particles and current collector determines the magnitude of interfacial thermal resistance and interfacial heat transfer coefficient.For the first time,this work quantitatively analyzed the structural mechanics and heat transfer mechanism during calendering process of porous electrodes,and the results indicate a promising way to optimize and design battery electrode structures.

Cast-rolling force model of multi-roll solid–liquid cast-rolling bonding process for fabricating metal cladding materials

Based on twin-roll casting technology and multi-roll groove rolling technology,a Multi-Roll Solid-Liquid Cast-Rolling Bonding(MRSLCRB)process was proposed to fabricate Cu/steel cladding bars,which processes the advantages of short flow and high-efficiency.However,it is a typical 3-D thermal-fluid-mechanics coupled problem,and determining cast-rolling force is difficult during the equipment design.Therefore,the geometrical evolution of the cast-rolling area was studied,laying the foundation to establish contact boundary equations and analyze mechanical schematics and metal flow.Then,a 3-D steady-state thermal-fluid coupled simulation model,including casting roll,substrate bar,and cladding metal,was established.The Kissing Point(KP)height,average outlet temperature,and process window were predicted,and simulation results of the three-roll layout indicate that the KP distribution along the circumferential direction can be considered uniform.Hence,the engineering cast-rolling force model was derived based on the differential element method and plane deformation hypothesis.The accuracy was verified by the 3-D finite element model,and the influences of process layouts and technological parameters on the castrolling force were analyzed.Through the indirect multi-field coupled analysis method,the temperature–pressure evolution and reasonable process window can be predicted,which provides a significant basis for guiding equipment design and improving product quality.