This paper deals with the bio-oxidation of galena particles （-80 meshes） using Acidithiobacillus ferrooxidans and compares it with Fe^3＋ oxidation. Experimental results show that, at least, 0.00197 mol galena was l...This paper deals with the bio-oxidation of galena particles （-80 meshes） using Acidithiobacillus ferrooxidans and compares it with Fe^3＋ oxidation. Experimental results show that, at least, 0.00197 mol galena was leached from lOOmL pulp （density of 3.8%） with 39 days＇ bio-oxidation, as compared to 0.00329 mol galena by Fe^3＋ with 9 days＇ oxidation. Because Fe^3＋ was constantly consumed, leaching by Fe^3＋ almost stopped after 9 days. Large amounts of lead sulfate were detected in both bio-oxidation and Fe^3＋ oxidation of galena. A. ferrooxidans followed a unique growth pattern during the bio-oxidation of galena. In the initial 15 days, the bacteria attached themselves to the galena surface with the formation of erosion pits similar in shape and length to those of the bacteria, and there were hardly any bacteria suspended in the solution. After 15 days, suspended bacteria increased. It is thus suggested that A. ferrooxidans may directly oxidize galena.展开更多
High resolution sampling, for Sr isotope and REE analyses, was carried out along a transaction of L vent chimney collected from East Pacific Rise 9oN–10oN. Sr isotopes show these anhydrites are precipitated from a mi...High resolution sampling, for Sr isotope and REE analyses, was carried out along a transaction of L vent chimney collected from East Pacific Rise 9oN–10oN. Sr isotopes show these anhydrites are precipitated from a mixture between hydrothermal fluid and seawater. The calculated relative proportion of seawater and hydrothermal fluid shows that the mixing is heterogeneous on the transection of the L vent chimney. Anhydrites from the chimney show uniform chondrite-normalized REE pattern with enrichment of LREE and positive Eu anomaly. While normalized to the REE of end-member hydrothermal fluid, anhydrites also show uniform REE pattern but with negative Eu anomaly and enrichment of HREE. Combining previous studies on REEs of hydrothermal fluids from different hydrothermal systems and the hydrothermal fluid data from this region, we suggested that REE-anion complexing, rather than crystallography controlling, is the main factor that controls the REE partition behavior in the anhydrite during its precipitation from the mixture of hydrothermal fluid and seawater.展开更多
基金This work was supported by the National Natural Science Foundation of China （Grant Nos. 40532011, 40403004 and 40473032）；Important Direction Project of Knowledge Innovation Program of the Chinese Academy of Sciences （Grant No. KZCX3-SW-223）.
文摘This paper deals with the bio-oxidation of galena particles （-80 meshes） using Acidithiobacillus ferrooxidans and compares it with Fe^3＋ oxidation. Experimental results show that, at least, 0.00197 mol galena was leached from lOOmL pulp （density of 3.8%） with 39 days＇ bio-oxidation, as compared to 0.00329 mol galena by Fe^3＋ with 9 days＇ oxidation. Because Fe^3＋ was constantly consumed, leaching by Fe^3＋ almost stopped after 9 days. Large amounts of lead sulfate were detected in both bio-oxidation and Fe^3＋ oxidation of galena. A. ferrooxidans followed a unique growth pattern during the bio-oxidation of galena. In the initial 15 days, the bacteria attached themselves to the galena surface with the formation of erosion pits similar in shape and length to those of the bacteria, and there were hardly any bacteria suspended in the solution. After 15 days, suspended bacteria increased. It is thus suggested that A. ferrooxidans may directly oxidize galena.
基金supported by the China Ocean Mineral Resource R & D Association (COMRA) Projects (Nos. DY125-13-R-08, DY125-13-R-01, and DY125-13-R-05)
文摘High resolution sampling, for Sr isotope and REE analyses, was carried out along a transaction of L vent chimney collected from East Pacific Rise 9oN–10oN. Sr isotopes show these anhydrites are precipitated from a mixture between hydrothermal fluid and seawater. The calculated relative proportion of seawater and hydrothermal fluid shows that the mixing is heterogeneous on the transection of the L vent chimney. Anhydrites from the chimney show uniform chondrite-normalized REE pattern with enrichment of LREE and positive Eu anomaly. While normalized to the REE of end-member hydrothermal fluid, anhydrites also show uniform REE pattern but with negative Eu anomaly and enrichment of HREE. Combining previous studies on REEs of hydrothermal fluids from different hydrothermal systems and the hydrothermal fluid data from this region, we suggested that REE-anion complexing, rather than crystallography controlling, is the main factor that controls the REE partition behavior in the anhydrite during its precipitation from the mixture of hydrothermal fluid and seawater.
