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功能化固态电解质膜改性锂金属负极的研究进展 被引量:3
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作者 钱华明 李喜飞 《物理化学学报》 SCIE CAS CSCD 北大核心 2021年第2期90-106,共17页
对高比能量锂离子电池需求的不断增加激发了锂金属负极的应用研究。锂金属具有高放电比容量(3860 mAh·g^(−1)),低电极电位(−3.04 V),是锂离子电池的理想负极材料。然而,锂金属在循环过程中会形成不稳定的固态电解质(SEI)膜,而且会... 对高比能量锂离子电池需求的不断增加激发了锂金属负极的应用研究。锂金属具有高放电比容量(3860 mAh·g^(−1)),低电极电位(−3.04 V),是锂离子电池的理想负极材料。然而,锂金属在循环过程中会形成不稳定的固态电解质(SEI)膜,而且会生成枝晶,枝晶的生长会引发电池短路等安全问题,极大地阻碍了其应用。理想的SEI膜应具有良好的锂离子传导性、表面电子绝缘性和机械强度,可调控锂离子在表面均匀沉积,促进离子传输,抑制枝晶生长,因此构筑功能化SEI膜是解决锂金属负极所面临挑战的一项有效策略。本综述以锂金属枝晶形成和生长的机理为出发点,分析总结SEI膜的构建策略、不同组成SEI膜的结构和功能特性及其对锂金属负极性能的影响,并对锂金属实用化面临的挑战及未来发展方向进行了展望。 展开更多
关键词 锂金属负极 锂枝晶生长 功能化SEI膜 锂均匀沉积 高比能电池
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Widely linear UKF constant modulus algorithm for blind adaptive beamforming
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作者 huaming qian Ke Liu +2 位作者 Long Li Linchen qian Junda Ma 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2017年第3期413-423,共11页
Based on a uniform linear array, a new widely linear unscented Kalman filter-based constant modulus algorithm (WL-UKF-CMA) for blind adaptive beamforming is proposed. The new algorithm is designed according to the con... Based on a uniform linear array, a new widely linear unscented Kalman filter-based constant modulus algorithm (WL-UKF-CMA) for blind adaptive beamforming is proposed. The new algorithm is designed according to the constant modulus criterion and takes full advantage of the noncircular property of the signal of interest (SOI), significantly increasing the output signal-to interference-plus-noise ratio (SINR), enhancing the convergence speed and decreasing the steady-state misadjustment. Since it requires no known training data, the proposed algorithm saves a large amount of the available spectrum. Theoretical analysis and simulation results are presented to demonstrate its superiority over the conventional linear least mean square-based CMA (L-LMS-CMA), the conventional linear recursive least square-based CMA (L-RLS-CMA), WL-LMS-CMA, WL-RLS-CMA and L-UKF-CMA. 展开更多
关键词 widely linear filtering blind beamforming noncircular signals constant modulus algorithm unscented Kalman filtering
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Adaptive robust cubature Kalman filtering for satellite attitude estimation 被引量:11
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作者 Zhenbing QIU huaming qian Guoqing WANG 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2018年第4期806-819,共14页
This paper is concerned with the adaptive robust cubature Kalman filtering problem for the case that the dynamics model error and the measurement model error exist simultaneously in the satellite attitude estimation s... This paper is concerned with the adaptive robust cubature Kalman filtering problem for the case that the dynamics model error and the measurement model error exist simultaneously in the satellite attitude estimation system. By using Hubel-based robust filtering methodology to correct the measurement covariance formulation of cubature Kalman filter, the proposed filtering algorithm could effectively suppress the measurement model error. To further enhance this effect and reduce the impact of the dynamics model error, two different adaptively robust filtering algorithms,one with the optimal adaptive factor based on the estimated covariance matrix of the predicted residuals and the other with multiple fading factors based on strong tracking algorithm, are developed and applied for the satellite attitude estimation. The quaternion is employed to represent the global attitude parameter, and three-dimensional generalized Rodrigues parameters are introduced to define the local attitude error. A multiplicative quaternion error is derived from the local attitude error to maintain quaternion normalization constraint in the filter. Simulation results indicate that the proposed novel algorithm could exhibit higher accuracy and faster convergence compared with the multiplicative extended Kalman filter, the unscented quaternion estimator, and the adaptive robust unscented Kalman filter. 展开更多
关键词 Attitude estimation Cubature Kalman filter Multiple fading factors Optimal adaptive factor Robust filtering
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Surface Doping vs.Bulk Doping of Cathode Materials for Lithium-Ion Batteries:A Review 被引量:7
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作者 huaming qian Haoqi Ren +8 位作者 Ying Zhang Xianfeng He Wenbin Li Jingjing Wang Junhua Hu Hong Yang Hirbod Maleki Kheimeh Sari Yu Chen Xifei Li 《Electrochemical Energy Reviews》 SCIE EI 2022年第4期254-285,共32页
To address the capacity degradation,voltage fading,structural instability and adverse interface reactions in cathode materi-als of lithium-ion batteries(LIBs),numerous modification strategies have been developed,mainl... To address the capacity degradation,voltage fading,structural instability and adverse interface reactions in cathode materi-als of lithium-ion batteries(LIBs),numerous modification strategies have been developed,mainly including coating and doping.In particular,the important strategy of doping(surface doping and bulk doping)has been considered an effective strategy to modulate the crystal lattice structure of cathode materials.However,special insights into the mechanisms and effectiveness of the doping strategy,especially comparisons between surface doping and bulk doping in cathode materials,are still lacking.In this review,recent significant progress in surface doping and bulk doping strategies is demonstrated in detail by focusing on their inherent differences as well as effects on the structural stability,lithium-ion(Li-ion)diffusion and electrochemical properties of cathode materials from the following mechanistic insights:preventing the exposure of reactive Ni on the surface,stabilizing the Li slabs,mitigating the migration of transition metal(TM)ions,alleviating unde-sired structural transformations and adverse interface issues,enlarging the Li interslab spacing,forming three-dimensional(3D)Li-ion diffusion channels,and providing more active sites for the charge-transfer process.Moreover,insights into the correlation between the mechanisms of hybrid surface engineering strategies(doping and coating)and their influences on the electrochemical performance of cathode materials are provided by emphasizing the stabilization of the Li slabs,the enhancement of the surface chemical stability,and the alleviation of TM ion migration.Furthermore,the existing challenges and future perspectives in this promising field are indicated. 展开更多
关键词 Lithium-ion batteries Cathode materials Surface doping Bulk doping Hybrid surface engineering Structural stability Lithium-ion diffusion
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