Polyalkylmethacrylates(PAMAs) are well-known as viscosity index improvers and dispersant boosters.This paper shows that PAMAs are able to adsorb from oil solution on to metal surfaces,to produce thick,viscous boundary...Polyalkylmethacrylates(PAMAs) are well-known as viscosity index improvers and dispersant boosters.This paper shows that PAMAs are able to adsorb from oil solution on to metal surfaces,to produce thick,viscous boundary films.These films enhance lubricant film formation in slow speed and high temperature conditions and thus produce a significant reduction of friction.A systematic study of this phenomenon has made use of the highly flexible nature of PAMA chemistry.A range of dispersant and non-dispersant polymethacrylates has been synthesized.The influence of different functionalities,molecular weights and architectures on both boundary film formation and friction has been explored using optical interferometry and friction-speed charting.From the results, guidelines have been developed for designing PAMAs having optimal boundary lubricating properties.Through their ability to form boundary films PAMAs can significantly contribute to reduce wear in engine,gear and hydraulic lubrication.As a consequence of their viscometric and tribological performance PAMAs can furthermore improve fuel and energy efficiency in different,namely engine and hydraulic applications.Extensive work is currently conducted in the lubricant industry to develop engine oils with lower sulfur,phosphorus and metal content(low SAPS) and to optimize their frictional properties through the use of friction modifiers or synthetic base stocks.We have investigated the contribution of PAMA viscosity index improvers and boosters to improve fuel economy and to reduce wear levels.This paper reports our efforts to develop a new range of PAMAs that have been optimized in terms of composition,architecture,molecular weight and functionality and which can be used in low viscosity,low SAPS formulations to help meet the stringent requirements of modern engine oils.展开更多
In stress-augmented thermal activation, the activation energy barrier that controls the rate of atomic and molecular processes is reduced by the application of stress, with the result that the rate of these processes ...In stress-augmented thermal activation, the activation energy barrier that controls the rate of atomic and molecular processes is reduced by the application of stress, with the result that the rate of these processes increases exponentially with applied stress. This concept has particular relevance to Tribology, and since its development in the early twentieth century, it has been applied to develop important models of plastic flow, sliding friction, rheology, wear, and tribochemistry. This paper reviews the development of stress-augmented thermal activation and its application to all of these areas of Tribology. The strengths and limitations of the approach are then discussed and future directions considered. From the scientific point of view, the concept of stress-augmented thermal activation is important since it enables the development of models that describe macroscale tribological performance, such as friction coefficient or tribofilm formation, in terms of the structure and behaviour of individual atoms and molecules. This both helps us understand these processes at a fundamental level and also provides tools for the informed design of lubricants and surfaces.展开更多
文摘Polyalkylmethacrylates(PAMAs) are well-known as viscosity index improvers and dispersant boosters.This paper shows that PAMAs are able to adsorb from oil solution on to metal surfaces,to produce thick,viscous boundary films.These films enhance lubricant film formation in slow speed and high temperature conditions and thus produce a significant reduction of friction.A systematic study of this phenomenon has made use of the highly flexible nature of PAMA chemistry.A range of dispersant and non-dispersant polymethacrylates has been synthesized.The influence of different functionalities,molecular weights and architectures on both boundary film formation and friction has been explored using optical interferometry and friction-speed charting.From the results, guidelines have been developed for designing PAMAs having optimal boundary lubricating properties.Through their ability to form boundary films PAMAs can significantly contribute to reduce wear in engine,gear and hydraulic lubrication.As a consequence of their viscometric and tribological performance PAMAs can furthermore improve fuel and energy efficiency in different,namely engine and hydraulic applications.Extensive work is currently conducted in the lubricant industry to develop engine oils with lower sulfur,phosphorus and metal content(low SAPS) and to optimize their frictional properties through the use of friction modifiers or synthetic base stocks.We have investigated the contribution of PAMA viscosity index improvers and boosters to improve fuel economy and to reduce wear levels.This paper reports our efforts to develop a new range of PAMAs that have been optimized in terms of composition,architecture,molecular weight and functionality and which can be used in low viscosity,low SAPS formulations to help meet the stringent requirements of modern engine oils.
文摘In stress-augmented thermal activation, the activation energy barrier that controls the rate of atomic and molecular processes is reduced by the application of stress, with the result that the rate of these processes increases exponentially with applied stress. This concept has particular relevance to Tribology, and since its development in the early twentieth century, it has been applied to develop important models of plastic flow, sliding friction, rheology, wear, and tribochemistry. This paper reviews the development of stress-augmented thermal activation and its application to all of these areas of Tribology. The strengths and limitations of the approach are then discussed and future directions considered. From the scientific point of view, the concept of stress-augmented thermal activation is important since it enables the development of models that describe macroscale tribological performance, such as friction coefficient or tribofilm formation, in terms of the structure and behaviour of individual atoms and molecules. This both helps us understand these processes at a fundamental level and also provides tools for the informed design of lubricants and surfaces.
