Quantum electrodynamics(QED)effects may be included in physical processes of magnetar and pulsar magnetospheres with strong magnetic fields.Involving the quantum corrections,Maxwell electrodynamics is modified to nonl...Quantum electrodynamics(QED)effects may be included in physical processes of magnetar and pulsar magnetospheres with strong magnetic fields.Involving the quantum corrections,Maxwell electrodynamics is modified to nonlinear electrodynamics.In this work,we study the force-free magnetosphere in nonlinear electrodynamics in a general framework.The pulsar equation describing a steady and axisymmetric magnetosphere is derived,which now admits solutions with corrections.We derive the first-order nonlinear corrections to the near-zone dipole magnetosphere in some popular nonlinear effective theories.The field lines of the corrected dipole tend to converge on the rotational axis so that the fields in the polar region are stronger compared to the pure dipole case.展开更多
A method to measure the detailed performance of polycapillary x-ray optics by a pinhole and charge coupled device(CCD)detector was proposed in this study.The pinhole was located between the x-ray source and the polyca...A method to measure the detailed performance of polycapillary x-ray optics by a pinhole and charge coupled device(CCD)detector was proposed in this study.The pinhole was located between the x-ray source and the polycapillary x-ray optics to determine the illuminating region of the incident x-ray beam on the input side of the optics.The CCD detector placed downstream of the polycapillary x-ray optics ensured that the incident x-ray beam controlled by the pinhole irradiated a specific region of the input surface of the optics.The intensity of the output beam of the polycapillary x-ray optics was obtained from the far-field image of the output beam of the optics captured by CCD detector.As an application example,the focal spot size,gain in power density,transmission efficiency,and beam divergence of different parts of a polycapillary focusing x-ray lenses(PFXRL)were measured by a pinhole and CCD detector.Three pinholes with diameters of 500,1000,and 2000μm were used to adjust the diameter of the incident x-ray beam illuminating the PFXRL from 500μm to the entire surface of the input side of the PFXRL.The focal spot size of the PFXRL,gain in power density,transmission efficiency,and beam divergence ranged from 27.1μm to 34.6μm,400 to 3460,26.70%to 5.38%,and 16.8 mrad to 84.86 mrad,respectively.展开更多
Starquakes probably occur in rapidly spinning or ultra high field neutron stars. In this article, we argue that highly compressed gas containing electron–positron pairs could evaporate and erupt from inside the neutr...Starquakes probably occur in rapidly spinning or ultra high field neutron stars. In this article, we argue that highly compressed gas containing electron–positron pairs could evaporate and erupt from inside the neutron star when a crack forms and then heals during a starquake. Under the influence of the existing oscillation modes of the star, the crack may have sufficiently large size and long lifetime. An appropriate amount of gas can erupt into the magnetosphere with relativistic and nearly uniform velocity, producing various transient and bursting phenomena.展开更多
PA1012/calcium silicate whisker nanocomposites with contents of whisker ranging from 10 wt% to 40 wt%, are prepared by twin screw extruder without any additions of coupling agent. The effect of whisker on the matrix i...PA1012/calcium silicate whisker nanocomposites with contents of whisker ranging from 10 wt% to 40 wt%, are prepared by twin screw extruder without any additions of coupling agent. The effect of whisker on the matrix is analyzed by the studies of morphology, the mechanical properties, water absorption and thermal stabilities. SEM micrographs obviously demonstrate, even under the high filler content of 40 wt% and without surface treatment, calcium silicate whisker can be homogeneously dispersed in polyamide, directly leading to the enhanced mechanical properties. The mechanism of higher efficiency of reinforcement is needle-like shape whisker, having access to be intercalated, and mutual affinity caused by hydrogen bonding interaction between carbonyl group in polyamide chain and hydroxyl group in whisker surface. Both aspects attach matrix with excellent stress-transfer properties. In addition, with the assistance of whisker, the nanocomposite favors an improved water absorption as well as thermal stability, which is intimately associated with physical performance.展开更多
Carbon dioxide mineral sequestration with steelmaking slag is a promising method for reducing carbon dioxide in a large- scale setting. Existing calcium oxide or calcium hydroxide in steelmaking slag can be easily lea...Carbon dioxide mineral sequestration with steelmaking slag is a promising method for reducing carbon dioxide in a large- scale setting. Existing calcium oxide or calcium hydroxide in steelmaking slag can be easily leached by water, and the formed calcium carbonate can be easily wrapped on the surface of unreacted steelmaking slag particles. Thus, further increase in the carbonation reaction rate can be prevented. Enhanced carbon dioxide mineral sequestration with steel- making slag in dilute alkali solution was analysed in this study through experiments and process evaluation. Operating conditions, namely alkali concentration, reaction temperature and time, and liquid-to-solid ratio, were initially investigated. Then, the material and energy balance of the entire process was calculated, and the net carbon dioxide sequestration efficiency at different reaction times was evaluated. Results showed that dilute alkali solution participated in slowing down the leaching of active calcium in the steelmaking slag and in significantly improving carbonation conversion rate. The highest carbonation conversion rate of approximately 50% can be obtained at the optimal conditions of 20 g/L alkali concentration, 2 mL/L liquid-to-solid ratio, and 70 ℃ reaction temperature. Carbonation reaction time significantly influences the net carbon dioxide sequestration efficiency. According to calculation, carbon dioxide emission of 52.6 kg/t- slag was avoided at a relatively long time of 120 min.展开更多
A simple and efficient method of enhancing biomass saccharification by microwave-assisted pretreatment with dimethyl sulfoxide/1-allyl-3-methylimidazolium chloride is proposed. Softwood(pine wood(PW)), hardwoods(...A simple and efficient method of enhancing biomass saccharification by microwave-assisted pretreatment with dimethyl sulfoxide/1-allyl-3-methylimidazolium chloride is proposed. Softwood(pine wood(PW)), hardwoods(poplar wood, catalpa bungi, and Chinese parasol), and agricultural wastes(rice straw, wheat straw, and corn stover(CS)) were exploited. Results showed that the best pretreatment effect was in PW with 54.3% and 31.7% dissolution and extraction ratios, respectively. The crystal form of cellulose in PW extract transformed from I to II, and the contended cellulose ratio and glucose conversion ratio reached 85.1% and 85.4%, respectively. CS after steam explosion achieved a similar pretreating effect as PW, with its cellulose hydrolysis ratio reaching as high as 91.5% after IL pretreatment.展开更多
A set of mono-and bimetallic(Zn-Co) supported ZSM-5 catalysts was first prepared by PEG-additive method. The physicochemical properties of the catalysts were investigated by FTIR, XPS, XRD, N2adsorption-desorption m...A set of mono-and bimetallic(Zn-Co) supported ZSM-5 catalysts was first prepared by PEG-additive method. The physicochemical properties of the catalysts were investigated by FTIR, XPS, XRD, N2adsorption-desorption measurements, SEM, EDS and NH3-TPD techniques. The physicochemical properties showed that the Zn Co2O4 spinel oxide was formed on the ZSM-5 support and provided effectual synergetic effect between Zn and Co species for the bimetallic catalyst. Furthermore, bimetallic supported ZSM-5 catalyst exhibited weak, moderate and strong acidic sites, while the monometallic supported ZSM-5 catalyst showed only weak and moderate or strong acidic sites. Their catalytic performances for thermal decomposition of hexamethylene–1,6–dicarbamate(HDC) to hexamethylene–1,6–diisocyanate(HDI) were then studied. It was found that the bimetallic supported ZSM-5 catalysts,especially Zn-2Co/ZSM-5 catalyst showed excellent catalytic performance due to the good synergetic effect between Co and Zn species, which provided a suitable contribution of acidic sites. HDC conversion of 100% with HDI selectivity of 91.2% and by-products selectivity of 1.3% could be achieved within short reaction time of 2.5 h over Zn-2Co/ZSM-5 catalyst.展开更多
基金supported by the Yunnan Natural Science Foundation(2017FB005 and 2014FB188).
文摘Quantum electrodynamics(QED)effects may be included in physical processes of magnetar and pulsar magnetospheres with strong magnetic fields.Involving the quantum corrections,Maxwell electrodynamics is modified to nonlinear electrodynamics.In this work,we study the force-free magnetosphere in nonlinear electrodynamics in a general framework.The pulsar equation describing a steady and axisymmetric magnetosphere is derived,which now admits solutions with corrections.We derive the first-order nonlinear corrections to the near-zone dipole magnetosphere in some popular nonlinear effective theories.The field lines of the corrected dipole tend to converge on the rotational axis so that the fields in the polar region are stronger compared to the pure dipole case.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11675019,12105020,and 12075031)the Bud Project of Beijing Academy of Science and Technology(Grant No.BGS202106)the National Key Research and Development Program of China(Grant No.2021YFF0701202)
文摘A method to measure the detailed performance of polycapillary x-ray optics by a pinhole and charge coupled device(CCD)detector was proposed in this study.The pinhole was located between the x-ray source and the polycapillary x-ray optics to determine the illuminating region of the incident x-ray beam on the input side of the optics.The CCD detector placed downstream of the polycapillary x-ray optics ensured that the incident x-ray beam controlled by the pinhole irradiated a specific region of the input surface of the optics.The intensity of the output beam of the polycapillary x-ray optics was obtained from the far-field image of the output beam of the optics captured by CCD detector.As an application example,the focal spot size,gain in power density,transmission efficiency,and beam divergence of different parts of a polycapillary focusing x-ray lenses(PFXRL)were measured by a pinhole and CCD detector.Three pinholes with diameters of 500,1000,and 2000μm were used to adjust the diameter of the incident x-ray beam illuminating the PFXRL from 500μm to the entire surface of the input side of the PFXRL.The focal spot size of the PFXRL,gain in power density,transmission efficiency,and beam divergence ranged from 27.1μm to 34.6μm,400 to 3460,26.70%to 5.38%,and 16.8 mrad to 84.86 mrad,respectively.
文摘Starquakes probably occur in rapidly spinning or ultra high field neutron stars. In this article, we argue that highly compressed gas containing electron–positron pairs could evaporate and erupt from inside the neutron star when a crack forms and then heals during a starquake. Under the influence of the existing oscillation modes of the star, the crack may have sufficiently large size and long lifetime. An appropriate amount of gas can erupt into the magnetosphere with relativistic and nearly uniform velocity, producing various transient and bursting phenomena.
基金financially supported by the Ministry of Science and Technology of China(No.2013BAE02B02)
文摘PA1012/calcium silicate whisker nanocomposites with contents of whisker ranging from 10 wt% to 40 wt%, are prepared by twin screw extruder without any additions of coupling agent. The effect of whisker on the matrix is analyzed by the studies of morphology, the mechanical properties, water absorption and thermal stabilities. SEM micrographs obviously demonstrate, even under the high filler content of 40 wt% and without surface treatment, calcium silicate whisker can be homogeneously dispersed in polyamide, directly leading to the enhanced mechanical properties. The mechanism of higher efficiency of reinforcement is needle-like shape whisker, having access to be intercalated, and mutual affinity caused by hydrogen bonding interaction between carbonyl group in polyamide chain and hydroxyl group in whisker surface. Both aspects attach matrix with excellent stress-transfer properties. In addition, with the assistance of whisker, the nanocomposite favors an improved water absorption as well as thermal stability, which is intimately associated with physical performance.
基金financially supported by the National Natural Science Foundation of China (No. 21300212)
文摘Carbon dioxide mineral sequestration with steelmaking slag is a promising method for reducing carbon dioxide in a large- scale setting. Existing calcium oxide or calcium hydroxide in steelmaking slag can be easily leached by water, and the formed calcium carbonate can be easily wrapped on the surface of unreacted steelmaking slag particles. Thus, further increase in the carbonation reaction rate can be prevented. Enhanced carbon dioxide mineral sequestration with steel- making slag in dilute alkali solution was analysed in this study through experiments and process evaluation. Operating conditions, namely alkali concentration, reaction temperature and time, and liquid-to-solid ratio, were initially investigated. Then, the material and energy balance of the entire process was calculated, and the net carbon dioxide sequestration efficiency at different reaction times was evaluated. Results showed that dilute alkali solution participated in slowing down the leaching of active calcium in the steelmaking slag and in significantly improving carbonation conversion rate. The highest carbonation conversion rate of approximately 50% can be obtained at the optimal conditions of 20 g/L alkali concentration, 2 mL/L liquid-to-solid ratio, and 70 ℃ reaction temperature. Carbonation reaction time significantly influences the net carbon dioxide sequestration efficiency. According to calculation, carbon dioxide emission of 52.6 kg/t- slag was avoided at a relatively long time of 120 min.
基金supported by the National Natural Science Foundation of China(No.21006118)the National High Technology Research and Development Program of China(863Project,Nos.2012AA101807 and 2012AA022301)
文摘A simple and efficient method of enhancing biomass saccharification by microwave-assisted pretreatment with dimethyl sulfoxide/1-allyl-3-methylimidazolium chloride is proposed. Softwood(pine wood(PW)), hardwoods(poplar wood, catalpa bungi, and Chinese parasol), and agricultural wastes(rice straw, wheat straw, and corn stover(CS)) were exploited. Results showed that the best pretreatment effect was in PW with 54.3% and 31.7% dissolution and extraction ratios, respectively. The crystal form of cellulose in PW extract transformed from I to II, and the contended cellulose ratio and glucose conversion ratio reached 85.1% and 85.4%, respectively. CS after steam explosion achieved a similar pretreating effect as PW, with its cellulose hydrolysis ratio reaching as high as 91.5% after IL pretreatment.
基金supported by National Natural Science Foundation of China(Nos.21476244 and 21406245)Youth Innovation Promotion Association CAS
文摘A set of mono-and bimetallic(Zn-Co) supported ZSM-5 catalysts was first prepared by PEG-additive method. The physicochemical properties of the catalysts were investigated by FTIR, XPS, XRD, N2adsorption-desorption measurements, SEM, EDS and NH3-TPD techniques. The physicochemical properties showed that the Zn Co2O4 spinel oxide was formed on the ZSM-5 support and provided effectual synergetic effect between Zn and Co species for the bimetallic catalyst. Furthermore, bimetallic supported ZSM-5 catalyst exhibited weak, moderate and strong acidic sites, while the monometallic supported ZSM-5 catalyst showed only weak and moderate or strong acidic sites. Their catalytic performances for thermal decomposition of hexamethylene–1,6–dicarbamate(HDC) to hexamethylene–1,6–diisocyanate(HDI) were then studied. It was found that the bimetallic supported ZSM-5 catalysts,especially Zn-2Co/ZSM-5 catalyst showed excellent catalytic performance due to the good synergetic effect between Co and Zn species, which provided a suitable contribution of acidic sites. HDC conversion of 100% with HDI selectivity of 91.2% and by-products selectivity of 1.3% could be achieved within short reaction time of 2.5 h over Zn-2Co/ZSM-5 catalyst.