发射峰为875 nm的高热稳定性立方相Sc(PO_(3))_(3):Cr^(3+)荧光粉

近红外(NIR)荧光粉转换型发光二极管(pc-LED)具有尺寸小、效率高以及光谱易于调节的特点,在特种照明、传感、微型近红外光谱仪等各领域有很好的应用前景.目前,已报道的发射波长超过850 nm的近红外荧光粉的荧光热稳定性较差.在本项研究中,我们合成了一种立方相结构的Sc(PO_(3))_(3):xCr^(3+)(x=0,1,5,10,12,14,16,18 at%)荧光粉,其具有725–1150 nm的宽发射带,发射峰为875 nm,与之前报道的发射峰超过850 nm的荧光粉相比,其表现出优异的热稳定性,在423 K下,5 at%样品的积分发光强度保留了室温下的73.4%.通过对比研究立方相和单斜相Sc(PO_(3))_(3):Cr^(3+)荧光粉变温X射线衍射,发现立方相荧光粉优异的荧光热稳定性可能归因于高温下较小的键长和键角变化.利用该荧光粉制备的NIR pc-LED在150 mA电流驱动下,产生了26.62 mW的NIR辐射功率.驱动电流为10 mA时,最高电光转换效率为11.87%.这项工作为开发具有优异荧光热稳定性的Cr^(3+)离子掺杂近红外荧光粉提供了思路.

The model of electrified cell clusters in biological tissues basing on the resting potential difference

The resting potential is the potential difference that exists between the inner and outer sides of the cell membrane when the cell is not stimulated.The resting membrane potential is a key regulator of phenomena such as cell proliferation,morphogenesis,migration and differentiation.In this paper,we proposed a model of electrified cell clusters that considers the resting potential of cell clusters in the resting state.By measuring the potential difference between the inner and outer sides of biological tissues,it is verified that the cell cluster has a negative potential difference when taking the outer potential as the reference.In the absence of external conductors,the tissue is electrically neutral;while in the presence of external conductors,the positive net charges escape freely under repulsive forces and the biological tissues form a negative electrical equilibrium system.The model proposed in this study explored the potential situation above the cellular level in the resting state,providing a new perspective for the research on resting potential.

Turbulent characteristics and rotation correction of wall function in rotating channel with high local rotation parameter

The turbulent fluctuation and the rotation correction of wall function law are investigated in the entrance section of a rotating channel. The one-dimensional hot wire probe and the X-type probe are utilized to measure the boundary layer at four streamwise stations. Through the analysis on the boundary layer near the leading side and trailing side, it is found that the turbulent fluctuation is promoted in the trailing side whereas suppressed in the leading side. This difference is attributed to the Coriolis instability near the trailing side. In addition, considering the local rotation parameter Rc, whose maximum absolute value is 0.014, is larger than that in previous research, whose maximum value is 0.007, the whole process of the relaminarization is captured. To understand this phenomenon better, the effects of the generation term and the Coriolis term in the transport equation of the Reynolds stress are discussed. In addition, the rotation correction of the viscous-Coriolis region and the Coriolis region are discussed, a new revising method for the wall function is proposed.

Convenient synthesis of twin-Christmas tree-like PbWO4 microcrystals and their photocatalytic properties

Novel twin-Christmas tree-like PbWO4 microcrystals have been prepared via a convenient aqueous solution route at room temperature under the assistance of 13- cyclodextrin （13-CD）. The product was characterized by XRD, EDX, SEM, TEM, UV-vis and PL and BET techniques. It was found that 13-CD plays an important role in the forming of twin-Christmas tree-like PbWO4 microcrystals. A five-step growth mechanism was proposed to explain the formation of such twin-Christmas tree-like structures. The photocatalytic performance of PbWO4 microcrystals was evaluated by measuring the decomposition rate of methylene blue （MB） and malachite green （MG） solution under the UV irradiation, and the photocatalytic results indicated that as-prepared PbWO4 microcrystals exhibit good and versatile photocatalytic activity as well as excellent recyclability.