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瞬态自由基与污染物的液相快速反应动力学
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作者 冯慧娟 童鑫 王黎明 《大学化学》 CAS 2023年第2期163-169,共7页
介绍了一种测量瞬态自由基快速液相反应速率系数的方法。采用激光脉冲光解产生瞬态自由基,采用吸收光谱法测量从微秒到毫秒时间尺度内的瞬态自由基浓度变化,采用绝对速率法和相对速率法得到反应的二级速率系数。本实验可加深对反应动力... 介绍了一种测量瞬态自由基快速液相反应速率系数的方法。采用激光脉冲光解产生瞬态自由基,采用吸收光谱法测量从微秒到毫秒时间尺度内的瞬态自由基浓度变化,采用绝对速率法和相对速率法得到反应的二级速率系数。本实验可加深对反应动力学的理解,并引导学生在有机污染物环境光化学方面开展创新性研究。 展开更多
关键词 瞬态吸收光谱 激光闪光光解 碳酸根离子自由基 羟基自由基
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Folding of Tubular Waterbomb 被引量:7
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作者 Jiayao Ma huijuan feng +2 位作者 Yan Chen Degao Hou Zhong You 《Research》 EI CAS 2020年第1期158-165,共8页
Origami has recently emerged as a promising building block of mechanical metamaterials because it offers a purely geometric design approach independent of scale and constituent material.The folding mechanics of origam... Origami has recently emerged as a promising building block of mechanical metamaterials because it offers a purely geometric design approach independent of scale and constituent material.The folding mechanics of origami-inspired metamaterials,i.e.,whether the deformation involves only rotation of crease lines(rigid origami)or both crease rotation and facet distortion(nonrigid origami),is critical for fine-tuning their mechanical properties yet very difficult to determine for origami patterns with complex behaviors.Here,we characterize the folding of tubular waterbomb using a combined kinematic and structural analysis.We for the first time uncover that a waterbomb tube can undergo a mixed mode involving both rigid origami motion and nonrigid structural deformation,and the transition between them can lead to a substantial change in the stiffness.Furthermore,we derive theoretically the range of geometric parameters for the transition to occur,which paves the road to program the mechanical properties of the waterbomb pattern.We expect that such analysis and design approach will be applicable to more general origami patterns to create innovative programmable metamaterials,serving for a wide range of applications including aerospace systems,soft robotics,morphing structures,and medical devices. 展开更多
关键词 DEFORMATION ROTATION RIGID
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