Metal porphyrin intercalated reduced graphene oxide nanocomposite utilized for electrocatalytic oxygen reduction

In this paper, we report a simple and facile self-assembly method to successfully fabricate cationic metal porphyrin-MtTMPyP(Mt= Cobalt(Ⅱ), Manganese(Ⅲ), or Iron(Ⅲ); TMPyP = 5, 10, 15, 20-tetrakis(N-methylpyridinium-4-yl) porphyrin) intercalated into the layer of graphene oxide(GO) by the cooperative effects of electrostatic and π-π stacking interaction between positively charged metal porphyrin and negatively charged GO sheets. Followed by reduction with hydrazine vapor, a series of novel 2 D MtTMPyP/rGO_n were fabricated. The as-prepared 2 D hybrids were fully characterized and tested as non-noble metal catalysts for oxygen reduction reaction(ORR) in an alkaline medium. The MtTMPyP/rGO_n hybrids, especially CoTMPyP/rGO_5, demonstrated an improved electrocatalytic activity for ORR and a number of exchanged electrons close to 4-electron reaction, increased stability and excellent tolerance to methanol, showing a potential alternative catalyst for ORR in fuel cells and air batteries.

Research on Compensation Mechanism of Land Acquisition in Rural Areas Based on the Practice of Anhui Province

With the continuous development of Chinese economy and rapid progress it has made,land demand for urban construction becomes larger and larger. Rural urbanization has a great relation to common prosperity and plays a key role in realizing the 21 st century great dream of Chinese people of all ethnic groups. Because of the complicated situation of land acquisition and compensation mechanism,we will conduct a systematic analysis on the compensation mechanism of land acquisition in Anhui Province and put forward the compensation methods to perfect the compensation mechanism according to the present compensation mechanism and the existing shortages of land acquisition in Anhui Province.

Metasurface-enabled augmented reality display: a review

Augmented reality(AR)display,which superimposes virtual images on ambient scene,can visually blend the physical world and the digital world and thus opens a new vista for human–machine interaction.AR display is considered as one of the next-generation display technologies and has been drawing huge attention from both academia and industry.Current AR display systems operate based on a combination of various refractive,reflective,and diffractive optical elements,such as lenses,prisms,mirrors,and gratings.Constrained by the underlying physical mechanisms,these conventional elements only provide limited light-field modulation capability and suffer from issues such as bulky volume and considerable dispersion,resulting in large size,severe chromatic aberration,and narrow field of view of the composed AR display system.Recent years have witnessed the emerging of a new type of optical elements—metasurfaces,which are planar arrays of subwavelength electromagnetic structures that feature an ultracompact footprint and flexible light-field modulation capability,and are widely believed to be an enabling tool for overcoming the limitations faced by current AR displays.Here,we aim to provide a comprehensive review on the recent development of metasurface-enabled AR display technology.We first familiarize readers with the fundamentals of AR display,covering its basic working principle,existing conventional-optics-based solutions,as well as the associated pros and cons.We then introduce the concept of optical metasurfaces,emphasizing typical operating mechanisms,and representative phase modulation methods.We elaborate on three kinds of metasurface devices,namely,metalenses,metacouplers,and metaholograms,which have empowered different forms of AR displays.Their physical principles,device designs,and the performance improvement of the associated AR displays are explained in details.In the end,we discuss the existing challenges of metasurface optics for AR display applications and provide our perspective on future research endeavors.

Real-time reconfigurable metasurfaces enabling agile terahertz wave front manipulation

Real-time controlled programmable metasurfaces,having an array-of-subarrays architecture under the control of one-bit digital coding sequence,are demonstrated for rapid and precise multifunctional Terahertz wave front engineering.