The dielectric permittivities(ε′ & ε″) and dielectric loss tangent(tan) are studied for the prepared samples CuFe2O4 and Cu1-xZnxGa0.1Fe1.9O4 spinel ferrites with(0.0 ≤ x ≤ 0.5) from room temperature up to 7...The dielectric permittivities(ε′ & ε″) and dielectric loss tangent(tan) are studied for the prepared samples CuFe2O4 and Cu1-xZnxGa0.1Fe1.9O4 spinel ferrites with(0.0 ≤ x ≤ 0.5) from room temperature up to 700K in the frequency range(102~105Hz).Dielectric anomaly at the transition temperature Tc is pronounced in the relations of dielectric permittivitties with temperature where,the obtained Tc is found to decrease linearly with increasing Zn concentration.The relation of tan with frequency at different temperatures shows relaxation spectra where the relaxation time and the maximum frequency of the hopping conduction mechanism are determined.The variation of(ε′,ε″ and tanδ) with frequency and temperature displays a strong dependence on both gallium and zinc concentrations.The results are explained in light of the cation-anion-cation and cation-cation interactions over the octahedral sites in the spinel structure.展开更多
文摘The dielectric permittivities(ε′ & ε″) and dielectric loss tangent(tan) are studied for the prepared samples CuFe2O4 and Cu1-xZnxGa0.1Fe1.9O4 spinel ferrites with(0.0 ≤ x ≤ 0.5) from room temperature up to 700K in the frequency range(102~105Hz).Dielectric anomaly at the transition temperature Tc is pronounced in the relations of dielectric permittivitties with temperature where,the obtained Tc is found to decrease linearly with increasing Zn concentration.The relation of tan with frequency at different temperatures shows relaxation spectra where the relaxation time and the maximum frequency of the hopping conduction mechanism are determined.The variation of(ε′,ε″ and tanδ) with frequency and temperature displays a strong dependence on both gallium and zinc concentrations.The results are explained in light of the cation-anion-cation and cation-cation interactions over the octahedral sites in the spinel structure.
