Highly porous Mg-Ca-Zn-Co alloy scaffolds for tissue engineering applications were produced by powder metallurgy based space holder-water leaching method.Mg-Ca-Zn-Co alloy foam can be used as a scaffold material in ti...Highly porous Mg-Ca-Zn-Co alloy scaffolds for tissue engineering applications were produced by powder metallurgy based space holder-water leaching method.Mg-Ca-Zn-Co alloy foam can be used as a scaffold material in tissue engineering.Carbamide was used as a space holder material.Fluoride conversion coating was synthesized on the alloy by immersion treatment in hydrofluoric acid(HF).Increasing Zn content of the alloy increased the elastic modulus.Ca addition prevented the oxidation of the specimens during sintering.Electrochemical corrosion behaviour of the specimens was examined in simulated body fluid.Corrosion rate decreased with Zn addition from1.0%up to3.0%(mass fraction)and then increased.Mass loss of the specimens initially decreased with Zn addition up to about3%and then increased.Fluoride conversion coating increased the corrosion resistance of the specimens.展开更多
Highly porous Ti-Co alloy specimens for biomedical applications were synthesized by powder metallurgy based space holder technique. Ti alloys have high melting temperature and affinity for oxygen, which makes Ti alloy...Highly porous Ti-Co alloy specimens for biomedical applications were synthesized by powder metallurgy based space holder technique. Ti alloys have high melting temperature and affinity for oxygen, which makes Ti alloys difficult to be processed. The Co addition reduces the melting temperature and Ti-Co alloy was sintered at lower temperatures. The electrochemical corrosion behaviour of the specimens was examined in the artificial saliva solution. The effects of Co content of the alloy, the p H value and fluoride concentration of the artificial saliva solution on the electrochemical corrosion properties of the specimens were investigated. The microstructure and mechanical properties of the specimens were examined. The electrochemical impedance spectroscopy results indicate that the corrosion resistance of the specimens decreases at high fluoride concentrations and low p H value. The defect density increases with increasing the fluoride concentration and decreasing the p H value of artificial saliva according to Mott-Schottky analysis.展开更多
Highly porous 17-4 PH stainless steel foam for implant applications was produced by space holder technique. Metal release and weight loss from 17-4 PH stainless steel foams were investigated in fluoride added artifici...Highly porous 17-4 PH stainless steel foam for implant applications was produced by space holder technique. Metal release and weight loss from 17-4 PH stainless steel foams were investigated in fluoride added artificial saliva environment by static immersion test. An inductively coupled plasma-mass spectrometer was employed to measure the concentrations of various metal ions. Effects of fluoride content of artificial saliva on metal release and weight loss from the steel foams were investigated. Effects of immersion time, pH value and process parameters on the weight loss and metal release were determined. Pore morphology, pore size and mechanical properties of the 17-4 PH stainless steel foams were also characterized.展开更多
基金Project(214M438)supported by the Scientific and Technological Research Council of Turkey(TUBITAK)Projects(20795,42796)supported partially by Scientific Research Projects Coordination Unit of Istanbul University,Turkey
文摘Highly porous Mg-Ca-Zn-Co alloy scaffolds for tissue engineering applications were produced by powder metallurgy based space holder-water leaching method.Mg-Ca-Zn-Co alloy foam can be used as a scaffold material in tissue engineering.Carbamide was used as a space holder material.Fluoride conversion coating was synthesized on the alloy by immersion treatment in hydrofluoric acid(HF).Increasing Zn content of the alloy increased the elastic modulus.Ca addition prevented the oxidation of the specimens during sintering.Electrochemical corrosion behaviour of the specimens was examined in simulated body fluid.Corrosion rate decreased with Zn addition from1.0%up to3.0%(mass fraction)and then increased.Mass loss of the specimens initially decreased with Zn addition up to about3%and then increased.Fluoride conversion coating increased the corrosion resistance of the specimens.
基金supported partially by Scientific Research Projects Coordination Unit of Istanbul University, Project numbers 42796 and 42922
文摘Highly porous Ti-Co alloy specimens for biomedical applications were synthesized by powder metallurgy based space holder technique. Ti alloys have high melting temperature and affinity for oxygen, which makes Ti alloys difficult to be processed. The Co addition reduces the melting temperature and Ti-Co alloy was sintered at lower temperatures. The electrochemical corrosion behaviour of the specimens was examined in the artificial saliva solution. The effects of Co content of the alloy, the p H value and fluoride concentration of the artificial saliva solution on the electrochemical corrosion properties of the specimens were investigated. The microstructure and mechanical properties of the specimens were examined. The electrochemical impedance spectroscopy results indicate that the corrosion resistance of the specimens decreases at high fluoride concentrations and low p H value. The defect density increases with increasing the fluoride concentration and decreasing the p H value of artificial saliva according to Mott-Schottky analysis.
文摘Highly porous 17-4 PH stainless steel foam for implant applications was produced by space holder technique. Metal release and weight loss from 17-4 PH stainless steel foams were investigated in fluoride added artificial saliva environment by static immersion test. An inductively coupled plasma-mass spectrometer was employed to measure the concentrations of various metal ions. Effects of fluoride content of artificial saliva on metal release and weight loss from the steel foams were investigated. Effects of immersion time, pH value and process parameters on the weight loss and metal release were determined. Pore morphology, pore size and mechanical properties of the 17-4 PH stainless steel foams were also characterized.
