Cobalt（Ⅲ） complex [CoL3], where L=（5-bromo-2-hydroxybenzyl-2-furylmethyl）imine, has been synthesized by reacting cobalt（Ⅱ） nitrate with L. The complex has been characterized by elemental analysis and FT-IR spe...Cobalt（Ⅲ） complex [CoL3], where L=（5-bromo-2-hydroxybenzyl-2-furylmethyl）imine, has been synthesized by reacting cobalt（Ⅱ） nitrate with L. The complex has been characterized by elemental analysis and FT-IR spectroscopy. The crystal structure of [CoL3]_was determined by X-ray crystallography from single crystal data. It crys- tallizes in the triclinic space group P1 with unit cell parameters： a=9.6644（10）A, b--11.5657（11）A, c= 16.5809（17）A, a= 102.833（4）°,β= 102.999（3）°, γ= 105.480（3）°, V= 1659.9（3）A3 and Z=2. Thermal decomposition of [COL3] was studied by thermogravimetry in order to evaluate its thermal stability and thermal decomposition pathways.展开更多
文摘Cobalt（Ⅲ） complex [CoL3], where L=（5-bromo-2-hydroxybenzyl-2-furylmethyl）imine, has been synthesized by reacting cobalt（Ⅱ） nitrate with L. The complex has been characterized by elemental analysis and FT-IR spectroscopy. The crystal structure of [CoL3]_was determined by X-ray crystallography from single crystal data. It crys- tallizes in the triclinic space group P1 with unit cell parameters： a=9.6644（10）A, b--11.5657（11）A, c= 16.5809（17）A, a= 102.833（4）°,β= 102.999（3）°, γ= 105.480（3）°, V= 1659.9（3）A3 and Z=2. Thermal decomposition of [COL3] was studied by thermogravimetry in order to evaluate its thermal stability and thermal decomposition pathways.
