A novel chiral Nickel (II) complex of N-(2-pyridylmethyl)-L-alanine (Hpyala) <b>1</b> has been prepared and structurally characterized by elemental analysis, FT-IR, UV-visible, TGA and single crystal X-ray...A novel chiral Nickel (II) complex of N-(2-pyridylmethyl)-L-alanine (Hpyala) <b>1</b> has been prepared and structurally characterized by elemental analysis, FT-IR, UV-visible, TGA and single crystal X-ray diffraction techniques. Complex <b>1</b> crystallizes in an orthorhombic P2<sub>1</sub>2<sub>1</sub>2<sub>1</sub> space group. The nickel (II) centre in the complex adopts a distorted octahedral geometry. This compound has been seen to exhibit structural diversity resulting from the number of lattice water molecules. The photoluminescent properties of this compound which have also been investigated, indicates the potential application in luminescence.展开更多
文摘A novel chiral Nickel (II) complex of N-(2-pyridylmethyl)-L-alanine (Hpyala) <b>1</b> has been prepared and structurally characterized by elemental analysis, FT-IR, UV-visible, TGA and single crystal X-ray diffraction techniques. Complex <b>1</b> crystallizes in an orthorhombic P2<sub>1</sub>2<sub>1</sub>2<sub>1</sub> space group. The nickel (II) centre in the complex adopts a distorted octahedral geometry. This compound has been seen to exhibit structural diversity resulting from the number of lattice water molecules. The photoluminescent properties of this compound which have also been investigated, indicates the potential application in luminescence.
