The interaction of TbC13 and lanthanide(Ⅲ) β-diketonate complexes with poly(N-vinylpyrrolidone) (PVP) polymer was studied using fluorescence spectroscopy. In the presence of PVP the emission of Tb3+ in cthano...The interaction of TbC13 and lanthanide(Ⅲ) β-diketonate complexes with poly(N-vinylpyrrolidone) (PVP) polymer was studied using fluorescence spectroscopy. In the presence of PVP the emission of Tb3+ in cthanolic solution of TbCl3 significantly in- creased owing to the excitation energy transfer from PVP to Tb3+ ions, which was more efficient as compared to a direct excitation of the Tb3+ 4f75d1 levels. In contrast, emission of NEt4Tb(hfa)4 and NEt4Eu(hfa)4 complexes was almost completely quenched in solu- tion containing PVP. The PVP bound both Ln3+ ions and hfa ligands which caused decomposition of Ln-hfa complexes and switched off the excitation energy transfer from the ligand to the emitting Ln3+ ion. The important role of hydrogen bonds in stabilization of in- teraction ofhfa ligands with PVP was indicated.展开更多
Tb3+-doped ZnSe and ZnSe/ZnS nanocrystals were synthesized using modified hot-injection method. The observation of the characteristic quantum dots absorption features in a time-gated excitation spectrum was recorded ...Tb3+-doped ZnSe and ZnSe/ZnS nanocrystals were synthesized using modified hot-injection method. The observation of the characteristic quantum dots absorption features in a time-gated excitation spectrum was recorded while monitoring Tb3+ emission at 545 nm provided direct evidence for successful incorporation of dopant ions into semiconductor host. Relatively long decay time (-1.5 ms) of Tb3+ emission indicated that dopant ions were well protected from interaction with surface ligands. Emission properties of core ZnSe:Tb3+ nanocrystals were only slightly modified upon growth of ZnS shell.展开更多
文摘The interaction of TbC13 and lanthanide(Ⅲ) β-diketonate complexes with poly(N-vinylpyrrolidone) (PVP) polymer was studied using fluorescence spectroscopy. In the presence of PVP the emission of Tb3+ in cthanolic solution of TbCl3 significantly in- creased owing to the excitation energy transfer from PVP to Tb3+ ions, which was more efficient as compared to a direct excitation of the Tb3+ 4f75d1 levels. In contrast, emission of NEt4Tb(hfa)4 and NEt4Eu(hfa)4 complexes was almost completely quenched in solu- tion containing PVP. The PVP bound both Ln3+ ions and hfa ligands which caused decomposition of Ln-hfa complexes and switched off the excitation energy transfer from the ligand to the emitting Ln3+ ion. The important role of hydrogen bonds in stabilization of in- teraction ofhfa ligands with PVP was indicated.
基金Project supported by Wroclaw Research Centre EIT+within the project"The Application of Nanotechnology in Advanced Materials”-Nano Mat(POIG.01.01.02-02-002/08) co-financed by the European Regional Development Fund(Operational Programme Innovative Economy,1.1.2)
文摘Tb3+-doped ZnSe and ZnSe/ZnS nanocrystals were synthesized using modified hot-injection method. The observation of the characteristic quantum dots absorption features in a time-gated excitation spectrum was recorded while monitoring Tb3+ emission at 545 nm provided direct evidence for successful incorporation of dopant ions into semiconductor host. Relatively long decay time (-1.5 ms) of Tb3+ emission indicated that dopant ions were well protected from interaction with surface ligands. Emission properties of core ZnSe:Tb3+ nanocrystals were only slightly modified upon growth of ZnS shell.