Due to native character of thermal expansion coefficient(CTE)mismatch between C_(f)/SiC and GH3536,achieving high strength joint was a huge challenge for C_(f)/SiC-GH3536 joints.Herein,a composite filler metal of Ag-C...Due to native character of thermal expansion coefficient(CTE)mismatch between C_(f)/SiC and GH3536,achieving high strength joint was a huge challenge for C_(f)/SiC-GH3536 joints.Herein,a composite filler metal of Ag-Cu-Ti+Sc_(2)(WO_(4))_(3) was developed to join C_(f)/SiC and GH3536.This work introduced Sc_(2)(WO_(4))_(3) to Ag-Cu-Ti system as a negative thermal expansion(NTE)reinforcing phase to release joint residual stress.Sc_(2)(WO_(4))_(3) was evenly distributed in the brazing seam and reacted with Ti to form Ti_(3)O_(5) reaction layer.The results of finite element analysis showed that the residual stress of the joints was effectively released by introducing Sc_(2)(WO_(4))_(3) reinforcing phase,and the mises stress was decreased from447 to 401 MPa.The maximum shear strength of the C_(f)/SiC-GH3536 joint brazed with Ag-Cu-Ti+6 vol%Sc_(2)(WO_(4))_(3) filler alloys was 64 MPa,which was about 2.6 times higher than that of Ag-Cu-Ti alloys.The results of this study provide a promising strategy for the introduction of new Sc_(2)(WO_(4))_(3) reinforcing phase in Ag-Cu-Ti system,and improve the reliability and feasibility of composite brazing alloy in brazing filed.展开更多
基金the National Natural Science Foundation of China(Grant Nos.51575135 and 51622503)Natural Science Foundation of Heilongjiang Province of China(YQ2019E023)。
文摘Due to native character of thermal expansion coefficient(CTE)mismatch between C_(f)/SiC and GH3536,achieving high strength joint was a huge challenge for C_(f)/SiC-GH3536 joints.Herein,a composite filler metal of Ag-Cu-Ti+Sc_(2)(WO_(4))_(3) was developed to join C_(f)/SiC and GH3536.This work introduced Sc_(2)(WO_(4))_(3) to Ag-Cu-Ti system as a negative thermal expansion(NTE)reinforcing phase to release joint residual stress.Sc_(2)(WO_(4))_(3) was evenly distributed in the brazing seam and reacted with Ti to form Ti_(3)O_(5) reaction layer.The results of finite element analysis showed that the residual stress of the joints was effectively released by introducing Sc_(2)(WO_(4))_(3) reinforcing phase,and the mises stress was decreased from447 to 401 MPa.The maximum shear strength of the C_(f)/SiC-GH3536 joint brazed with Ag-Cu-Ti+6 vol%Sc_(2)(WO_(4))_(3) filler alloys was 64 MPa,which was about 2.6 times higher than that of Ag-Cu-Ti alloys.The results of this study provide a promising strategy for the introduction of new Sc_(2)(WO_(4))_(3) reinforcing phase in Ag-Cu-Ti system,and improve the reliability and feasibility of composite brazing alloy in brazing filed.
